Abstract: Herein discussed is a method of producing hydrogen comprising: providing a tubular reactor having an open end and a closed end, wherein the reactor comprises an anode on the inside and a cathode on the outside separated by and in contact with a mixed conducting electrolyte, wherein the electrolyte comprises an electronically conducting phase and an ionically conducting phase, wherein the reactor comprises no current collector or interconnect; introducing a hydrocarbon and an oxidant into a feed tube, wherein the feed tube contains a catalyst that promotes catalytic partial oxidation (CPOX) reactions, wherein the feed tube extends into the open end of the reactor and toward the closed end of the reactor; introducing steam to the outside of the tubular reactor; and converting steam to hydrogen electrochemically without electricity input.

Abstract: Herein discussed is a method of making an electrochemical device comprising (a) infiltrating an anode precursor, a cathode precursor, and an electrolyte precursor with a dispersion to produce an infiltrated anode precursor, an infiltrated cathode precursor, and an infiltrated electrolyte precursor, wherein the dispersion comprises metal ions and nanoparticles selected from the group consisting of metallic nanoparticles, metal-oxide nanoparticles, ceramic nanoparticles, and combinations thereof; wherein the metal ions percolate each precursor, wherein the anode precursor, the cathode precursor, and the electrolyte precursor are porous, the electrolyte precursor having an average pore size that is 50% or less of an average pore size of the anode precursor and that is 50% or less of an average pore size of the cathode precursor; and (b) co-sintering the infiltrated anode precursor, the infiltrated cathode precursor, and the infiltrated electrolyte precursor such that the infiltrated anode precursor becomes a por

Abstract: Herein discussed is a hydrogen production system comprising: a catalytic partial oxidation (CPOX) reactor; a steam generator; and an electrochemical (EC) reactor; wherein the CPOX reactor product stream is introduced into the EC reactor and the steam generator provides steam to the EC reactor; and wherein the product stream and the steam do not come in contact with each other in the EC reactor. In an embodiment, the EC reactor generates a first product stream comprising CO and CO2 and a second product stream comprising H2 and H2O, wherein the two product streams do not come in contact with each other.

Abstract: Herein discussed is a method of producing hydrogen or carbon monoxide comprising introducing a waste gas having a total combustible species (TCS) content of no greater than 60 vol % into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase. Also disclosed herein is an integrated hydrogen production system comprising a waste gas source and an electrochemical (EC) reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the waste gas source is configured to send its exhaust to the EC reactor, wherein the exhaust has a total combustible species (TCS) content of no greater than 60 vol %.

Abstract: Herein discussed is a method of producing hydrogen comprising introducing a first stream comprising a fuel to an electrochemical (EC) reactor having a mixed-conducting membrane, introducing a second stream comprising water to the reactor, reducing the water in the second stream to produce hydrogen, and recycling at least portion of the produced hydrogen to the first stream, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase; and wherein the first stream and the second stream do not come in contact with each other in the reactor.

Abstract: Herein discussed is a method of using an oxide ion conducting membrane comprising exposing the oxide ion conducting membrane to a reducing environment on both sides of the membrane. In an embodiment, the oxide ion conducting membrane also conducts electrons. In various embodiments, the membrane is impermeable to fluid flow (e.g., having a permeability of less than 1 micro darcy). In an embodiment, the oxide ion conducting membrane comprises lanthanum chromite and a material selected from the group consisting of doped ceria, yttria-stabilized zirconia (YSZ), lanthanum strontium gallate magnesite (LSGM), scandia-stabilized zirconia (SSZ), Sc and Ce doped zirconia, and combinations thereof. In an embodiment, the lanthanum chromite comprises undoped lanthanum chromite, strontium doped lanthanum chromite, iron doped lanthanum chromite, strontium and iron doped lanthanum chromite, lanthanum calcium chromite, or combinations thereof. In an embodiment, the membrane is mixed conducting.

Abstract: A hydrogen production system comprising: a fuel source; a water source; and a hydrogen producer; where the fuel source and the water source are in fluid communication with the hydrogen producer; and where fuel enters the hydrogen producer from the fuel source and water enters the hydrogen producer from the water source and the fuel and the water do not come in contact with each other in the hydrogen producer.

Abstract: A method of producing hydrogen includes providing a device, introducing a first stream including a fuel to the device, introducing a second stream comprising water to the device, reducing the water in the second stream to hydrogen, and extracting hydrogen from the device. The first stream and the second stream do not come in contact with each other in the device.

Abstract: A device includes a first electrode, a second electrode, and an electrolyte between the electrodes. The first electrode and the second electrode may comprise a metallic phase that does not contain a platinum group metal when the device is in use, and where the electrolyte is solid state and is oxide ion conducting.

Abstract: Herein disclosed is a method of manufacturing comprises depositing a composition on a substrate slice by slice to form an object; heating in situ the object using electromagnetic radiation (EMR); wherein said composition comprises a first material and a second material, wherein the second material has a higher absorption of the radiation than the first material. In an embodiment, the EMR has a wavelength ranging from 10 to 1500 nm and the EMR has a minimum energy density of 0.1 Joule/cm2. In an embodiment, the EMR comprises UV light, near ultraviolet light, near infrared light, infrared light, visible light, laser, electron beam. In an embodiment, said object comprises a catalyst, a catalyst support, a catalyst composite, an anode, a cathode, an electrolyte, an electrode, an interconnect, a seal, a fuel cell, an electrochemical gas producer, an electrolyser, an electrochemical compressor, a reactor, a heat exchanger, a vessel, or combinations thereof.

Abstract: Herein discussed is a method of heating a material having a surface comprising exposing the surface to an electromagnetic radiation source emitting a first wavelength spectrum; receiving a second wavelength spectrum from the surface using a detector at a sampling frequency; wherein the first wavelength spectrum and the second wavelength spectrum have no greater than 10% of overlap, wherein the overlap is the integral of intensity with respect to wavelength. In an embodiment, the first wavelength spectrum and the second wavelength spectrum have no greater than 5% of overlap or no greater than 3% of overlap or no greater than 1% of overlap or no greater than 0.5% of overlap. In an embodiment, exposing the surface to the radiation source causes the material to sinter at least partially.

Abstract: Herein discussed is an electrochemical reactor comprising a first electrode, wherein the first electrode is liquid when the reactor is in operation; a second electrode having a metallic phase and a ceramic phase, wherein the metallic phase is electronically conductive and wherein the ceramic phase is ionically conductive; and a membrane, wherein the membrane is positioned between the first and second electrodes and is in contact with the first and second electrodes, wherein the membrane is mixed conducting. Also discussed herein is a method of producing hydrogen or carbon monoxide comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode, wherein the anode is liquid when the reactor is in operation and wherein the membrane is mixed conducting; (b) introducing a feedstock to the anode; (c) introducing a stream to the cathode, wherein the stream comprises water or carbon dioxide.

Abstract: Herein discussed is a method of producing carbon monoxide comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a mixed-conducting membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises a fuel; (c) introducing a second stream to the cathode, wherein the second stream comprises carbon dioxide, wherein carbon monoxide is generated from carbon dioxide electrochemically; wherein the reactor generates no electricity and receives no electricity. In an embodiment, the anode and the cathode are separated by the membrane and are both exposed to reducing environments during the entire time of operation.

Abstract: Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a product from ammonia cracking; (c) introducing a second stream to the cathode, wherein the second stream comprises water; and wherein hydrogen is generated from water electrochemically without electricity input. Systems for producing hydrogen from ammonia are also discussed.

Abstract: Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a product from ammonia cracking; (c) introducing a second stream to the cathode, wherein the second stream comprises water; and wherein hydrogen is generated from water electrochemically without electricity input. Systems for producing hydrogen from ammonia are also discussed.

Abstract: Herein discussed is a method of making a copper-containing electrode comprising: (a) forming a copper solution; (b) forming a ceramic substrate; (c) infiltrating the ceramic substrate with the copper solution; and (d) calcining the infiltrated substrate using electromagnetic radiation, wherein the substrate is no thicker than 50 microns. In an embodiment, the method comprises repeating (c) and (d) until copper percolates the ceramic substrate.

Abstract: Herein disclosed is a method of making an electrochemical reactor comprising a) depositing a composition on a substrate to form a slice; b) drying the slice using a non-contact dryer; c) sintering the slice using electromagnetic radiation (EMR), wherein the electrochemical reactor comprises an anode, a cathode, and an electrolyte between the anode and the cathode. In an embodiment, the electrochemical reactor comprises at least one unit, wherein the unit comprises the anode, the cathode, the electrolyte and an interconnect and wherein the unit has a thickness of no greater than 1 mm. In an embodiment, the anode is no greater than 50 microns in thickness, the cathode is no greater than 50 microns in thickness, and the electrolyte is no greater than 10 microns in thickness.

Abstract: There is disclosed a method of making an electrode for an electrochemical reactor including the steps of providing a template and depositing electrode material such that the electrode material is in contact with the template. This template is provided in a form that produces channels in the electrode material. There is also disclosed an electrode for an electrochemical reactor which includes electrode material and a template, with the template occupying channels in the electrode material.

Abstract: Herein disclosed is a method of making a fuel cell including forming an anode, a cathode, and an electrolyte using an additive manufacturing machine. The electrolyte is between the anode and the cathode. Preferably, electrical current flow is perpendicular to the electrolyte in the lateral direction when the fuel cell is in use. Preferably, the method comprises making an interconnect, a barrier layer, and a catalyst layer using the additive manufacturing machine.

Abstract: Herein discussed is a hydrogen production system comprising a first reactor zone and a second reactor zone, wherein both reactor zones comprise an ionically conducting membrane, wherein the first zone is capable of reforming a hydrocarbon electrochemically and the second zone is capable of performing water gas shift reactions electrochemically, wherein the electrochemical reforming reactions involve the exchange of an ion through the membrane to oxidize the hydrocarbon and wherein electrochemical water gas shift reactions involve the exchange of an ion through the membrane and include forward water gas shift reactions, or reverse water gas shift reactions, or both. In an embodiment, the membrane is mixed conducting. In an embodiment, the membrane comprises an electronically conducting phase and an ionically conducting phase.