Patents by Inventor Jin Mizuguchi
Jin Mizuguchi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8268250Abstract: The present invention provides a low-cost hydrogen gas sensor, which exhibits high sensory selectivity for protons and operates at room temperature, and can also provide a highly sensitive sensor capable of fulfilling the important functions of detecting hydrogen gas and preventing leakage accidents in production plants that use hydrogen gas as a carrier, in hydrogen gas storage facilities, and in so-called fuel cells that use hydrogen gas as an energy source. In addition, the sensor is also effective as an acid sensor for hydrofluoric acid and the like.Type: GrantFiled: September 21, 2009Date of Patent: September 18, 2012Assignee: Murata Manufacturing Co., Ltd.Inventor: Jin Mizuguchi
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Publication number: 20120093696Abstract: There is provided a system for decomposing and removing a toxic substance by introducing a gas containing the toxic substance into a reaction apparatus and causing the gas to contact with a heated oxide semiconductor, in which a porous material carrying, as the oxide semiconductor, chromium oxide or nickel oxide is placed in the reaction apparatus, chromium oxide or nickel oxide is thermally excited, and the gas is contacted with the chromium oxide or nickel oxide which is thermally excited. Thus, it is possible to provide a practically useful technique for decomposing and removing a toxic substance with high decomposition/removal efficiency.Type: ApplicationFiled: November 25, 2009Publication date: April 19, 2012Inventors: Jin Mizuguchi, Shigeru Suzuki, Ryo Iwamoto, Yoshiyuki Sato
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Publication number: 20100187109Abstract: The present invention provides a low-cost hydrogen gas sensor, which exhibits high sensory selectivity for protons and operates at room temperature, and can also provide a highly sensitive sensor capable of fulfilling the important functions of detecting hydrogen gas and preventing leakage accidents in production plants that use hydrogen gas as a carrier, in hydrogen gas storage facilities, and in so-called fuel cells that use hydrogen gas as an energy source. In addition, the sensor is also effective as an acid sensor for hydrofluoric acid and the like. The present invention relates to an acid and hydrogen gas sensor, wherein protons are brought into contact with an organic compound containing an introduced pyridine ring (such as pyridine-DPP), and the change in electrical resistivity, photoconductivity, or optical absorption band for the organic compound that accompanies proton addition is detected.Type: ApplicationFiled: September 21, 2009Publication date: July 29, 2010Applicant: Murata Manufacturing Co., Ltd.Inventor: Jin MIZUGUCHI
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Publication number: 20090120793Abstract: A method of protonating a hydrogen molecule includes bringing hydrogen gas into contact with a surface of a solid having a relative dielectric constant of more than 78.Type: ApplicationFiled: March 10, 2008Publication date: May 14, 2009Applicant: MURATA MANUFACTURING CO., LTD.Inventors: Jin MIZUGUCHI, Hiroo Takahashi, Tomomitsu Yamanishi, Junichi Suzuki, Hiroshi Takagi, Noboru Tanida
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Patent number: 7416601Abstract: Black perylene pigments which comprise one of the isomers of the formula Ia or Ib in which R1, R2 are each independently phenylene, naphthylene or pyridylene, each of which may be mono- or polysubstituted by C1-C12-alkyl, C1-C6-alkoxy, hydroxyl, nitro, and/or halogen; X is halogen; n Is from 0 to 4, or comprises a mixture of both isomers and has a blackness value ?210 in an alkyd/melamine baking varnish.Type: GrantFiled: February 4, 2005Date of Patent: August 26, 2008Assignee: BASF AktiengesellschaftInventors: Peter Erk, Andreas Stohr, Arno Boehm, Walter Kurtz, Jin Mizuguchi, Benno Sens
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Publication number: 20070151478Abstract: Black perylene pigments which comprise one of the isomers of the formula Ia or Ib in which R1, R2 are each independently phenylene, naphthylene or pyridylene, each of which may be mono- or polysubstituted by C1-C12-alkyl, C1-C6-alkoxy, hydroxyl, nitro, and/or halogen; X is halogen; n Is from 0 to 4, or comprises a mixture of both isomers and has a blackness value ?210 in an alkyd/melamine baking varnish.Type: ApplicationFiled: February 4, 2005Publication date: July 5, 2007Applicant: BASF AktiengesellschaftInventors: Peter Erk, Andreas Stohr, Arno Bohm, Walter Kurtz, Jin Mizuguchi, Benno Sens
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Publication number: 20070140908Abstract: The present invention provides a low-cost hydrogen gas sensor, which exhibits high sensory selectivity for protons and operates at room temperature, and can also provide a highly sensitive sensor capable of fulfilling the important functions of detecting hydrogen gas and preventing leakage accidents in production plants that use hydrogen gas as a carrier, in hydrogen gas storage facilities, and in so-called fuel cells that use hydrogen gas as an energy source. In addition, the sensor is also effective as an acid sensor for hydrofluoric acid and the like. The present invention relates to an acid and hydrogen gas sensor, wherein protons are brought into contact with an organic compound containing an introduced pyridine ring (such as pyridine-DPP), and the change in electrical resistivity, photoconductivity, or optical absorption band for the organic compound that accompanies proton addition is detected.Type: ApplicationFiled: September 27, 2004Publication date: June 21, 2007Applicants: Toyo Ink Mfg., Ltd. of Tokyo, Japan, Jin MIZUGUCHI of Kanagawa, JapanInventor: Jin Mizuguchi
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Patent number: 7105046Abstract: A black perylene-based pigment produced by calcining at least one compound selected from the group consisting of diimide derivatives of perylene tetracarboxylic acid and diimide derivatives of perylene diiminodicarboxylic acid, at a temperature of 200 to 600° C. in vacuum or in an inert gas atmosphere, exhibits an excellent blackness, an excellent heat resistance and an excellent weather fastness as well as a high resistance and a high safety.Type: GrantFiled: July 26, 2002Date of Patent: September 12, 2006Assignee: BASF AktiengesellschaftInventors: Jin Mizuguchi, Nobuya Shimo
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Patent number: 7083675Abstract: A black perylene-based pigment comprising a solid solution obtained by calcining a mixture of at least two compounds selected from the group consisting of anhydrides of perylene tetracarboxylic acid, diimide derivatives of perylene tetracarboxylic acid and diimide derivatives of perylene diiminodicarboxylic acid, exhibits an excellent blackness, an excellent heat resistance and an excellent weather fastness as well as a high resistance and a high safety.Type: GrantFiled: January 23, 2004Date of Patent: August 1, 2006Assignee: BASF AktiengesellschaftInventors: Jin Mizuguchi, Nobuya Shimo
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Publication number: 20050016420Abstract: A black perylene-based pigment produced by calcining at least one compound selected from the group consisting of diimide derivatives of perylene tetracarboxylic acid and diimide derivatives of perylene diiminodicarboxylic acid, at a temperature of 200 to 600° C. in vacuum or in an inert gas atmosphere, exhibits an excellent blackness, an excellent heat resistance and an excellent weather fastness as well as a high resistance and a high safety.Type: ApplicationFiled: July 26, 2002Publication date: January 27, 2005Inventors: Jin Mizuguchi, Nobuya Shimo
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Publication number: 20040255821Abstract: A black perylene-based pigment comprising a solid solution obtained by calcining a mixture of at least two compounds selected from the group consisting of anhydrides of perylene tetracarboxylic acid, diimide derivatives of perylene tetracarboxylic acid and diimide derivatives of perylene diiminodicarboxylic acid, exhibits an excellent blackness, an excellent heat resistance and an excellent weather fastness as well as a high resistance and a high safety.Type: ApplicationFiled: January 23, 2004Publication date: December 23, 2004Applicants: Toda Kogyo Corporation, Yokohama TLO Company, Ltd.Inventors: Jin Mizuguchi, Nobuya Shimo
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Patent number: 6245403Abstract: The invention relates to an optical storage medium comprising a substrate and a storage layer, wherein the storage layer comprises a compound of the formula (I) or (II) in which A and A′, independently of one another, are unsubstituted or mono- or di-halo-, -hydroxy-, —C1-C6alkyl-, —C1-C6alkoxy-, -cyano- or -nitro-substituted phenyl, pyridyl, pyrrolyl, imidazolyl, furyl or thienyl, which can, if desired, be fused to a benzene ring, are halide, tetrafluoroborate or unsubstituted or with one or more halogen substituted C1-C6alkane-sulfonate, benzenesulfonate, C1-C6alkylbenzenesulfonate, C1-C6alkylsulfate or di-C1-C6alkyl-phosphonate of N—C1-C6alkyl-pyridiniumyl, or are unsubstituted or mono- or di-hydroxy-substituted C2-C6alkyl or C2-C6alkenyl, whose chain may be uninterrupted or interrupted by one or two oxygen atoms, B and B′, independently of one another, are 2 H, S, S2 or SO2, and n and n′, independently of one another, are each a number from 1 to 4.Type: GrantFiled: April 29, 1998Date of Patent: June 12, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Heinz Spahni, Jin Mizuguchi, Beat Schmidhalter, Annemarie Wolleb, Jean-Luc Budry, Gérald Giller
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Patent number: 5973146Abstract: A process for the preparation of compounds of formula I ##STR1## by reacting a pyrrolopyrrole of formula ##STR2## wherein X.sub.1 is a group selected from ##STR3## X.sub.2 is a group selected from ##STR4## or has the same meaning as X.sub.1, with a secondary amine of formula ##STR5## in the molar ratio 1:2, in the presence of an anhydrous dipolar aprotic solvent and of an amount 0.1 to 15 times in excess of stoichiometric proportion, based on the amine of formula III, of an anhydrous organic base, in the temperature range from 50.degree. to 230.degree. C. and under a pressure from 0 to 10 bar.The substituents R.sub.1 to R.sub.8, Y and Hal are as defined in claim 1.The compounds of formula I are especially suitable for use as photoconductive substances.Type: GrantFiled: September 29, 1993Date of Patent: October 26, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Alain Claude Rochat, Olof Wallquist, Abul Iqbal, Jin Mizuguchi
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Patent number: 5808094Abstract: A process for the preparation of mixed crystals of 1,4-diketopyrrolo?3,4-c!pyrroles, consisting of 1 mol each of two different compounds of formula ##STR1## by heating a corresponding mixture in solid form to the temperature range from 220.degree. to 380.degree. C.A and B are, for example, each a group of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently hydrogen, chloro, bromo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, phenyl or --CN,G is --O--, --NR.sub.7 --, --N.dbd.N-- or --SO.sub.2 --,R.sub.3 and R.sub.4 are hydrogen, and R.sub.7 is hydrogen, methyl or ethyl.The mixed crystals and solid solutions obtained are excellently suited for pigmenting high molecular weight material.Type: GrantFiled: July 22, 1997Date of Patent: September 15, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Jin Mizuguchi, Zhimin Hao, Olof Wallquist, Abul Iqbal
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Patent number: 5725651Abstract: Mono-N-alkyl-quinacridone pigments are disclosed. They exhibit high light fastness, high temperature stability and high migration fastness. Moreover, they show hypsochromic shifts, fluorescence and high photoconductivity. These pigments are suited for coloring high molecular weight organic materials, for use as light emitting materials of organic electroluminescent elements as well as photoreceptors of electrophotography.Type: GrantFiled: March 10, 1997Date of Patent: March 10, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: John Zambounis, Jin Mizuguchi
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Patent number: 5693824Abstract: A process for the preparation of mixed crystals of 1,4-diketopyrrolo?3,4-c!pyrroles, consisting of 1 mol each of two different compounds of formula ##STR1## by heating a corresponding mixture in solid form to the temperature range from 220.degree. to 380.degree. C.A and B are, for example, each a group of formula ##STR2## wherein R.sub.1 and R.sub.2 are each independently hydrogen, chloro, bromo, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylamino, phenyl or --CN, G is --O--, --NR.sub.7 --, --N.dbd.N-- or --SO.sub.2 --, R.sub.3 and R.sub.4 are hydrogen, and R.sub.7 is hydrogen, methyl or ethyl.The mixed crystals and solid solutions obtained are excellently suited for pigmenting high molecular weight material.Type: GrantFiled: September 12, 1996Date of Patent: December 2, 1997Assignee: Ciba Specialty Chemicals CorporationInventors: Jin Mizuguchi, Zhimin Hao, Olof Wallquist, Abul Iqbal
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Patent number: 5500314Abstract: A process for the optical recording and storage of information in the form of bits by irradiating a recording material comprising a substrate coated with at least one layer of a pigment selected from the group of the dithiopyrrolopyrroles, dithioquinacridones, phthalocyanines or mixtures of several of these pigments as recording layer dotwise or linearly with laser light in the near infrared range (NIR range), which pigment (a) has a crystal modification having an absorption band in the NIR range, and (b) is in contact with a solid organic compound that changes the crystal modification of the pigment upon irradiation with laser light, so that (c) after irradiation the absorption in the NIR range is reduced, while the organic compound exhibits no absorption in the NIR range before and after irradiation.Type: GrantFiled: October 6, 1994Date of Patent: March 19, 1996Assignee: Ciba-Geigy CorporationInventors: Jin Mizuguchi, Gerald Giller
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Patent number: 5472815Abstract: A coated material comprising a substrate which is coated with a layer of a pyrrolopyrrole of formula I ##STR1## wherein R.sub.1 and R.sub.2 may be 4-pyridyl and X.sub.1 and X.sub.2 are O, said compound of formula I being at least partially in the form of a salt of a strong acid, is suitable for use as an optical recording material and, owing to its electrical conductivity and photoconductivity, as antistatically treated material, as sensor, photoreceptor and solar battery.Type: GrantFiled: January 25, 1994Date of Patent: December 5, 1995Assignee: Ciba-Geigy CorporationInventors: Jin Mizuguchi, Gerald Giller, Alain C. Rochat
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Patent number: 5382485Abstract: A process for the optical recording and storage of information in the form of bits by irradiating a recording material comprising a substrate coated with at least one layer of a pigment selected from the group of the dithiopyrrolopyrroles, dithioquinacridones, phthalocyanines or mixtures of several of these pigments as recording layer dotwise or linearly with laser light in the near infrared range (NIR range), which pigment (a) has a crystal modification having an absorption band in the NIR range, and (b) is in contact with a solid organic compound that changes the crystal modification of the pigment upon irradiation with laser light, so that (c) after irradiation the absorption in the NIR range is reduced, while the organic compound exhibits no absorption in the NIR range before and after irradiation.Type: GrantFiled: March 5, 1993Date of Patent: January 17, 1995Assignee: Ciba-Geigy CorporationInventors: Jin Mizuguchi, Gerald Giller
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Patent number: 5352551Abstract: A process for storing information in an organic recording layer which, when treated locally with an organic solvent in accordance with the input of information, is able to change its absorption spectrum and/or its photoconductivity such that information can be produced or stored at the treated areas of said layer, wherein the organic solvent is solid at room temperature and is present in the recording layer, or by decomposition of a solid organic precursor which is present in the recording layer, and said solvent is vaporized or melts by the action of laser beams in accordance with the input of information, or said precursor is decomposed by the action of laser beams in accordance with the input of information.The stored information can be read out with a photodetector in the visible or near NIR range or with a built-in electrode system.Type: GrantFiled: April 30, 1993Date of Patent: October 4, 1994Assignee: Ciba-Geigy CorporationInventors: Jin Mizuguchi, Alain C. Rochat, Gerald Giller