Abstract: The present disclosure relates generally to insecticide formulations. The present disclosure relates more particularly to aqueous pymetrozine formulations that can be provided in concentrate form and methods for making them. In one aspect, the disclosure provides a composition including pymetrozine in particulate form; a first polymeric dispersing agent, the first polymeric dispersing agent being a copolymer of (a) a maleic acid monomer and (b) a hydrophobic monomer; and a second polymeric dispersing agent, the second polymeric dispersing agent being a copolymer of (a) a (meth)acrylic acid monomer, an ethylenically unsaturated dicarboxylic acid monomer or a combination thereof, (b) a (meth)acrylamido alkyl or aryl sulfonate monomer; and (c) a third monomer selected from one or more of vinylic compounds, (meth)acrylic esters, vinyl acetate, and substituted (meth)acrylamides.

Abstract: The present invention provides compositions containing a wetting agent, a polycarboxylate type surfactant, and a sulfonate type surfactant. The composition can be used as an additive package composition in a pesticide suspension concentrate formulation to enhance thermal stability.

Abstract: The application discloses a method for acquiring parameters of a dynamic signal, including: selecting a dynamic sample signal sequence of a power grid to constitute an autocorrelation matrix; determining an effective rank of the autocorrelation matrix and the number of frequency components of the dynamic sample signal sequence; establishing an AR model, and solving a model parameter of the AR model; determining an expression and a complex sequence of the dynamic sample signal sequence by using a Prony algorithm, wherein the dynamic sample signal sequence is represented by the complex sequence with a minimum square error; and substituting a root of a characteristic polynomial corresponding to the model parameter into the complex sequence and solving various parameters of the dynamic sample signal sequence. In the application, with the idea of AR parameter model, a current signal is considered to be a linear combination of signals at previous time points.

Abstract: An apparatus (1600) and method (200) determine an instance quality set of an access system while the access system is used by an application package of a radio device. The access system comprises a radio system (110, 115) and an access network (140, 145). The application package has communicated information using a networked service (150) of the access network. The apparatus and method determine additional information that comprises at least one of a location of the device and an acquisition time, the instance quality set, and a radio system identifier of the radio system used. The apparatus and method perform at least one of storing within the radio device and transmitting from the radio device an application identifier of the application package in association with the additional information. The apparatus and method selects at least one of a preferred radio system and a preferred application package based on the instance quality set.

Abstract: Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3??(I) to at least one compound of Formula (II) CF3CF?CHZ??(II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments. Preferably Z is H.

Abstract: A disclosed method of operation includes generating a first resolution geographic descriptor that identifies a first size geographic grid area. The first size geographic grid area includes a specific location identified by mobile device location data but does not identify the specific location. The method proceeds with adjusting the first resolution geographic descriptor to a second resolution geographic descriptor, by increasing or decreasing the resolution to correspondingly decrease or increase, respectively, the corresponding geographic grid area to a second size geographic grid area that includes the specific location. An information update is then sent to a server. The information update includes the second resolution geographic descriptor but does not provide the mobile device location data, in order to preserve the mobile device user's anonymity.

Abstract: In embodiments of wireless communication handover profiles, a profile manager is implemented on a communication-enabled device to detect that a signal strength of a wireless connection decreases to a signal-level threshold or lower. The profile manager then monitors the decreasing signal strength of the wireless connection, and compares the signal strength to a handover profile to determine when a handover of the wireless connection from one access point to another will likely occur. The profile manager can then transfer handover parameters to the next access point before the handover to maintain the wireless connection during the handover between the access points.

Abstract: An apparatus (1600) and method (200) determine an instance quality set of an access system while the access system is used by an application package of a radio device. The access system comprises a radio system (110, 115) and an access network (140, 145). The application package has communicated information using a networked service (150) of the access network. The apparatus and method determine additional information that comprises at least one of a location of the device and an acquisition time, the instance quality set, and a radio system identifier of the radio system used. The apparatus and method perform at least one of storing within the radio device and transmitting from the radio device an application identifier of the application package in association with the additional information. The apparatus and method selects at least one of a preferred radio system and a preferred application package based on the instance quality set.

Abstract: The present application provides a power line communications system and method. The system comprises a power line network, a sending apparatus, and a receiving apparatus. The receiving apparatus comprises at least two PLC modems connected through a power line link. The sending apparatus sends a signal to a target PLC modem in the receiving apparatus through a power line network. The target PLC modem is at least one PLC modem in the receiving apparatus. The PLC modems in the receiving apparatus simultaneously receive a signal, the PLC modems except the target PLC modem respectively send the received signal to the target PLC modem through a wireless link, and the target PLC modem restores the signal sent by the sending apparatus according to the signal received through the power line network and the signal received through the wireless link.

Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF?CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2?CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl?CH2, preferably in a 80-96% selectivity. The CF3CCl?CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl?CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3.

Abstract: Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3??(I) to at least one compound of Formula (II) CF3CF?CHZ??(II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments. Preferably Z is H.

Abstract: The present application provides a power line communications system and method. The system comprises a power line network, a sending apparatus, and a receiving apparatus. The receiving apparatus comprises at least two PLC modems connected through a power line link. The sending apparatus sends a signal to a target PLC modem in the receiving apparatus through a power line network. The target PLC modem is at least one PLC modem in the receiving apparatus. The PLC modems in the receiving apparatus simultaneously receive a signal, the PLC modems except the target PLC modem respectively send the received signal to the target PLC modem through a wireless link, and the target PLC modem restores the signal sent by the sending apparatus according to the signal received through the power line network and the signal received through the wireless link.

Abstract: A biocidal composition comprising tributyl tetradecyl phosphonium chloride and tetrakis(hydroxymethyl)phosphonium sulfate at a weight ratio of 2:1 to 1:10, and its use for the control of microorganisms in aqueous and water-containing systems.

Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF?CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2?CClCH2Cl is fluorinated to synthesize a compound such as CF3CCl?CH2. The CF3CCl?CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl?CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

Abstract: Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X??(I) to at least one compound of formula (II) CF3CZCHZ??(II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.

Abstract: Provided is a continuous process for preparing 1,1,2,3-tetrachloro-1-propene having the steps of catalytically dehydrochlorinating CH2ClCCl2CH2Cl in the gas phase to produce CHCl?CClCH2Cl; chlorinating the CHCl?CClCH2Cl to form CHCl2CCl2CH2Cl; and catalytically dehydrochlorinating the CHCl2CCl2CH2Cl in the gas phase to form CCl2?CClCH2Cl.

Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF?CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2?CClCH2Cl is fluorinated to synthesize a compound such as CF3CCl?CH2. The CF3CCl?CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl?CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.

Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF?CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2?CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl?CH2, preferably in a 80-96% selectivity. The CF3CCl?CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl?CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3.

Abstract: A method for preparing 2,3,3,3-tetrafluoropropene comprising contacting a reactant comprising CCl2?CFCH2Cl with a fluorinating agent, such as HF, under conditions effective to produce a reaction product comprising CF3CF?CH2.

Abstract: Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X ??(I) to at least one compound of formula (II) CF3CZCHZ ??(II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.