Abstract: A method of calibration transfer for a testing instrument includes: collecting a first sample; generating a standard response of a first instrument based, at least in part, on the first sample; and performing instrument standardization of a second instrument based, at least in part, on the standard response of the first instrument. Data corresponding to a second sample is then obtained using the second instrument and a component of the second sample is identified based, at least in part, on a calibration model.

Abstract: A method of using spectroscopic envelopes for determining components in a sample may include selecting spectroscopic envelopes and passing input light through a sample comprising at least one absorbing component is provided. The method includes measuring throughput light with a photo-detector and determining the concentration of the at least one absorbing component in the sample using the measured throughput, wherein at least one of the plurality of spectroscopic envelopes overlaps at least one absorption band of the at least one absorbing component in the sample. An apparatus for determining components in a sample including an input light source having a spectrum and a sample container having a fixed optical path-length is also provided. The apparatus may include a plurality of pre-selected spectroscopic envelopes to select spectral portions of the throughput light from the sample; and at least one photo-detector to measure the throughput light selected by the spectroscopic envelopes.

Abstract: Methods and systems for the use of a thin-layer spectroelectrochemical cell to detect porphyrins in a wellbore environment are provided. In one embodiment, methods for the use of a thin-layer spectroelectrochemical cell to detect porphyrins in a wellbore environment comprises: positioning a spectroelectrochemical cell in a wellbore penetrating at least a portion of a subterranean formation comprising a downhole fluid; allowing at least a portion of the downhole fluid to flow into the spectroelectrochemical cell; and detecting at least one compound in at least a portion of the downhole fluid, wherein the at least one compound is selected from the group consisting of: a porphyrin, a metalloporphyrin, a porphyrin derivative, a porphyrin-like macrocycle, and any combination thereof.

Abstract: A method may include collecting measurement data using a first operational sensor and a second operational sensor of a downhole tool, standardizing optical responses of each operational sensor to a master sensor in a tool parameter space to obtain a standardized master sensor response, transforming the standardized master sensor response to a synthetic parameter space response of the master sensor, applying a fluid model with the synthetic parameter space response of the master sensor to predict a fluid characteristic, comparing a first prediction obtained with the fluid model from the first operational sensor with a second prediction obtained with the fluid model from the second operational sensor, determining a fluid characteristic from the first prediction and the second prediction, and optimizing a well testing and sampling operation according to the fluid characteristic.

Abstract: Apparatus, systems, and methods may operate to select a subset of sensor responses as inputs to each of a plurality of pre-calibrated models in predicting each of a plurality of formation fluid properties. The sensor responses are obtained and pre-processed from a downhole measurement tool. Each of the plurality of predicted formation fluid properties are evaluated by applying constraints in hydrocarbon concentrations, geo-physics, and/or petro-physics. The selection of sensor responses and the associated models from a pre-constructed model base or a candidate pool are adjusted and reprocessed to validate model selection.

Abstract: Apparatus, methods, and systems related to a spectroelectrochemical cell apparatus including a cell body that has a first volume, a transparent sample window defined in the cell body, the transparent sample window defining an optical path through the cell body and having a second volume, a working electrode extending through the cell body and into the transparent sample window in the optical path, a counter electrode extending through the cell body, a reference electrode extending through the cell body, a sample inlet extending through the cell body, a solvent inlet extending through the cell body, an electrolyte inlet extending through the cell body, an ionic fluid inlet extending through the cell body, a detection species inlet extending through the cell body, a fluid outlet extending through the cell body, and a fluid mixer located within the cell body.

Abstract: An example method includes performing validation testing on a tool using a plurality of reference fluids, the tool having a calibrated optical sensor installed therein that includes one or more optical elements. One or more tool sensor responses from the calibrated optical sensor may be obtained and pre-processed, and the one or more tool sensor responses may be compared with calibrated optical sensor responses derived from the calibrated optical sensor during calibration and thereby detecting one or more optical sensor anomalies. The one or more optical sensor anomalies may be evaluated through performance analysis with one or more candidate models, and an alternative candidate model may be selected to mitigate the one or more optical sensor anomalies. One or more remedial options may be pursued when the alternative candidate model fails to mitigate the one or more optical sensor anomalies.

Abstract: A downhole formation fluid identification sensing module for measuring averaged gas molecular weight of wellbore formation fluid acquires simultaneous temperature, pressure, and density measurements. The sensing module includes two venturi-type gas sensors that both contain vibrating tubes. During operation, formation fluid flows through the vibrating tubes whereby resonant frequency measurements are acquired simultaneously with temperature and pressure measurements. Each measurement is then utilized to determine the gas molecular weight of the dry, wet or saturated formation fluid.

Abstract: The disclosed embodiments include a method, apparatus, and computer program product for determining a synthetic gas-oil-ratio for a gas dominant fluid. For example, one disclosed embodiment includes a system that includes at least one processor, and at least one memory coupled to the at least one processor and storing instructions that when executed by the at least one processor performs operations that include optimizing a gas-oil-ratio database using a genetic algorithm and a multivariate regression simulator and generating a synthetic gas-oil-ratio for a gas dominant fluid.

Abstract: Apparatus, methods, and systems related to a spectroelectrochemical cell apparatus including a cell body that has a first volume, a transparent sample window defined in the cell body, the transparent sample window defining an optical path through the cell body and having a second volume, a working electrode extending through the cell body and into the transparent sample window in the optical path, a counter electrode extending through the cell body, a reference electrode extending through the cell body, a sample inlet extending through the cell body, a solvent inlet extending through the cell body, an electrolyte inlet extending through the cell body, an ionic fluid inlet extending through the cell body, a detection species inlet extending through the cell body, a fluid outlet extending through the cell body, and a fluid mixer located within the cell body.

Abstract: An example method includes performing validation testing on a tool using a plurality of reference fluids, the tool having a calibrated optical sensor installed therein that includes one or more optical elements. One or more tool sensor responses from the calibrated optical sensor may be obtained and pre-processed, and the one or more tool sensor responses may be compared with calibrated optical sensor responses derived from the calibrated optical sensor during calibration and thereby detecting one or more optical sensor anomalies. The one or more optical sensor anomalies may be evaluated through performance analysis with one or more candidate models, and an alternative candidate model may be selected to mitigate the one or more optical sensor anomalies. One or more remedial options may be pursued when the alternative candidate model fails to mitigate the one or more optical sensor anomalies.

Abstract: The disclosed embodiments include a method, apparatus, and computer program product for determining a synthetic gas-oil-ratio for a gas dominant fluid. For example, one disclosed embodiment includes a system that includes at least one processor, and at least one memory coupled to the at least one processor and storing instructions that when executed by the at least one processor performs operations that include optimizing a gas-oil-ratio database using a genetic algorithm and a multivariate regression simulator and generating a synthetic gas-oil-ratio for a gas dominant fluid.

Abstract: Apparatus, systems, and methods may operate to select a subset of sensor responses as inputs to each of a plurality of pre-calibrated models in predicting each of a plurality of formation fluid properties. The sensor responses are obtained and pre-processed from a downhole measurement tool. Each of the plurality of predicted formation fluid properties are evaluated by applying constraints in hydrocarbon concentrations, geo-physics, and/or petro-physics. The selection of sensor responses and the associated models from a pre-constructed model base or a candidate pool are adjusted and reprocessed to validate model selection.

Abstract: A photometric system design methodology employs genetic algorithms to optimize the selection of optical elements for inclusion in the photometric system in order to improve system performance with respect to environmental conditions (i.e., to “ruggedize” the photometric system). The genetic algorithms utilize a multi-objective fitness function to evolve simulated optical element selection, which may be a combination of optical filters and integrated computational elements.

Abstract: This disclosure includes methods for designing a simplified Integrated Computational Element (ICE) and for optimizing a selection of a combination of ICE designs. A method for fabricating a simplified ICE having one or more film layers includes predicting an optimal thickness of each of the one or more film layers of the simplified ICE using a neural network. A method for re-calibrating the fabricated ICE elements for system implementation is also disclosed. The disclosure also includes the simplified ICE designed by and the ICE combination selected by the disclosed methods. The disclosure also includes an information handling system with machine-readable instructions to perform the methods disclosed herein.

Abstract: Disclosed are systems and methods that use discriminant analysis techniques and processing in order to reduce the time required to determine chemical and/or physical properties of a substance. One method includes optically interacting a plurality of optical elements with one or more known substances, each optical element being configured to detect a particular characteristic of the one or more known substances, generating an optical response from each optical element corresponding to each known substance, wherein each known substance corresponds to a known spectrum stored in an optical database, and training a neural network to provide a discriminant analysis classification model for an unknown substance, the neural network using each optical response as inputs and one or more fluid types as outputs, and the outputs corresponding to the one or more known substances.

Abstract: Nanoparticle catalyst compositions and methods for preparation of same are described. The nanoparticle catalysts are platinum-free and are useful in effecting selective ring-opening reactions, for example in upgrading heavy oil. The catalyst may be of monometallic composition, or may comprise an alloyed or core-shell bimetallic composition. The nanoparticles are of controlled size and shape.

Abstract: The present invention relates to a method for measuring the characteristics of a downhole fluid. The method for measuring the characteristics of a downhole fluid includes passing a downhole fluid sample through an analyzer, analyzing the downhole fluid sample by illuminating the downhole fluid sample with light from a light source and detecting light that interacts with the fluid sample. The method is applicable to detecting carbon dioxide and/or hydrogen sulfide directly in a downhole environment.

Abstract: A cleaner is provided for a filter of a dishwashing appliance. The filter cleaner rotates within the filter and uses nozzles to remove particulates on the filter surface. Energy from fluid flow caused by a pump is used to rotate the filter cleaner. The particulates removed from the filter are pumped away for disposal.

Abstract: The present invention provides a smart mobile device having a dual-window displaying function. This smart mobile device comprises a first displaying region, a second displaying region, a separation bar, at least one status bar and at least one operation bar.