Publication number: 20240079579
Abstract: A positive active material, a secondary battery, a battery module, a battery pack, and an electrical device are disclosed. The positive active material includes a spinel-type lithium-manganese-containing composite oxide with a molecular formula of Li1+xAaMbXcMn2?a?b?c?xO4?t. In the molecular formula: A is a doping element for a manganese site of the spinel-type lithium-manganese-containing composite oxide; M is used for combining with O to form a second phase containing a polyoxyanion, and M includes one or more of B, C, N, Si, P, S, or Cl; X includes one or more of Mg, Al, Si, Ca, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, or Zr; and the molecular formula satisfies: ?0.1?x?0.3, 0<a?0.2, 0<b?0.2, 0<c?0.7, and 0?t?0.2.
Type:
Application
Filed:
November 14, 2023
Publication date:
March 7, 2024
Applicant:
CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
Inventors:
Zhenguo ZHANG, Xingkai HU, Xiang YIN, Jingpeng FAN, Sihui WANG, Zhijie YAO, Na LIU
Publication number: 20230395793
Abstract: Provided is a positive electrode material for a lithium ion battery, having the following general formula I: Li1+aNixCoyMnzMcM?dO2?bAb general formula I, wherein ?0.05?a?0.3, 0.8?x?1, 0?y?0.2, 0?z?0.2, 0?c?0.01, 0?d?0.01, x+y+z+c+d=1, and 0?b?0.05; M and M? are different from each other and each independently selected from at least one of La, Cr, Mo, Ca, Fe, Ti, Zn, Y. Zr, W, Nb, V, Mg, B, Al, Sr, Ba and Ta, A is selected from at least one of F, Cl, Br, I and S, and the number of crystallite boundaries N in primary particles of the positive electrode material is from 10.5 to 14.5, wherein N is calculated according to Equation I: N=DS/DX Equation I, wherein DS is an average size of the primary particles, as measured from scanning electron microscope (SEM) image of cross section of the positive electrode material, and DX is an average size of crystallites in the primary particles of the positive electrode material, as measured by an XRD test and calculated by the Scherrer equation.
Type:
Application
Filed:
August 17, 2023
Publication date:
December 7, 2023
Inventors:
Hang ZHANG, Yafei LIU, Jingpeng WANG, Xuequan ZHANG, Yanbin CHEN