Patent number: 11045794
Abstract: A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.
Type:
Grant
Filed:
August 24, 2016
Date of Patent:
June 29, 2021
Inventors:
Shujie Ren, Congying Zhang, Xin Li, Zhenguo Liu, Xiaolong Wang, Lei Tang, Zhipeng Liu, Zhanyu Gao, Jian Wu, Cong Wang, Yuan Li, Qingmei Jiang, Jinhong Song, Weiqi Hua, Hao Ding
Publication number: 20190201878
Abstract: A supported catalyst used for synthesizing a polyether amine, and a manufacturing method of the catalyst. The catalyst comprises: a porous oxide as a support; Ni, Cu, Pd, and Rh as active components; and one or more of any of Zr, Cr, Mo, Fe, Zn, Sn, Bi, Ce, La, Hf, Sr, Sb, Mg, Be, Re, Ta, Ti, Sc, Ge and related metals as an auxiliary agent. The catalyst can be used in an amination reaction for a large molecular weight polyether polyol, and is particularly active and selective for an amination reaction of a low molecular weight polyether polyol. The catalyst has a simple and economic manufacturing technique and good potential for future applications.
Type:
Application
Filed:
August 24, 2016
Publication date:
July 4, 2019
Applicant:
Wanhua Chemical Group Co., Ltd.
Inventors:
Shujie Ren, Congying Zhang, Xin Li, Zhenguo Liu, Xiaolong Wang, Lei Tang, Zhipeng Liu, Zhanyu Gao, Jian Wu, Cong Wang, Yuan Li, Qingmei Jiang, Jinhong Song, Weiqi Hua, Hao Ding
Patent number: 9580380
Abstract: Disclosed is a method for preparing diamino-dicyclohexyl methane (H12MDA) by hydrogenation of diamino-diphenyl methane (MDA). In the process, 4,4?-MDA used as the starting material is firstly hydrogenated to prepare 4,4?-H12MDA. When the activity of the catalyst is reduced, the feed is switched from 4,4?-MDA to the mixture of 2,4?-MDA and 4,4?-MDA, and then when the conversion is stabilized, the feed is switched to 4,4?-MDA again. The deactivated catalyst is activated on line by switching the feed to the mixture of 2,4?-MDA and 4,4?-MDA. 4,4?-H12MDA having the trans-trans isomer content of 16˜24 wt % is produced, and the mixture of 2,4?-H12MDA and 4,4?-H12MDA is also produced, wherein the content of 2,4?-H12MDA in the mixture is 4˜15 wt %.
Type:
Grant
Filed:
November 22, 2013
Date of Patent:
February 28, 2017
Assignee:
Wanhua Chemical Group Co., Ltd.
Inventors:
Xin Li, Hao Chen, Congying Zhang, Shan Gao, Zhenguo Liu, Weijia Wang, Lei Tang, Zhipeng Liu, Yuan Li, Qingmei Jiang, Jinhong Song, Weiqi Hua, Hao Ding
Publication number: 20160068472
Abstract: Disclosed is a method for preparing diamino-dicyclohexyl methane (H12MDA) by hydrogenation of diamino-diphenyl methane (MDA). In the process, 4,4?-MDA used as the starting material is firstly hydrogenated to prepare 4,4?-H12MDA. When the activity of the catalyst is reduced, the feed is switched from 4,4?-MDA to the mixture of 2,4?-MDA and 4,4?-MDA, and then when the conversion is stabilized, the feed is switched to 4,4?-MDA again. The deactivated catalyst is activated on line by switching the feed to the mixture of 2,4?-MDA and 4,4?-MDA. 4,4?-H12MDA having the trans-trans isomer content of 16˜24 wt % is produced, and the mixture of 2,4?-H12MDA and 4,4?-H12MDA is also produced, wherein the content of 2,4?-H12MDA in the mixture is 4˜15 wt %.
Type:
Application
Filed:
November 22, 2013
Publication date:
March 10, 2016
Applicants:
WANHUA CHEMICAL (NINGBO) CO., LTD., WANHUA CHEMICAL GROUP CO., LTD.
Inventors:
Xin LI, Hao CHEN, Congying ZHANG, Shan GAO, Zhenguo LIU, Weijia WANG, Lei TANG, Zhipeng LIU, Yuan LI, Qingmei JIANG, Jinhong SONG, Weiqi HUA, Hao DING