Abstract: Disclosed in the present invention are nano-meter sheet ferric phosphate, a preparation method therefor and the use thereof. The preparation method includes the following steps: dissolving a phosphorus source and an iron source in an acidic solution, adding an oxidant, and mixing same to obtain a solution containing phosphorus and iron; adding a precipitation auxiliary agent into part of the solution containing phosphorus and iron, heating same until boiling, and then diluting same for a reaction to obtain a primary ferric phosphate slurry; and dropwise adding the remaining solution containing phosphorus and iron into the primary ferric phosphate slurry, and then heating same for a reaction to obtain ferric phosphate. In the present invention, a primary ferric phosphate is prepared by means of a dilution precipitation reaction, and the precipitation auxiliary agent is then added for two-step precipitation to regulate the growth of the ferric phosphate.

Abstract: The present disclosure belongs to the technical field of battery recycling, and discloses a recycling method and use of lithium iron phosphate (LFP) waste. The method includes the following steps: mixing the LFP waste with water to prepare a slurry; adjusting a pH of the slurry to higher than 7.0 with an alkali, and heating to react; filtering a resulting mixture to obtain a filter residue; dissolving the filter residue in an acid, and filtering to obtain a filtrate; adding an oxalate-containing solution to react, and aging and filtering a resulting mixture to obtain a filter cake and a precipitation mother liquor; and subjecting the filter cake to slurrying, washing, and free water removal to obtain ferrous oxalate.

Abstract: The present disclosure discloses a method for recycling lithium iron phosphate waste and its application. The method comprises the following steps: disassembling, crushing, and sieving the lithium iron phosphate waste to obtain a lithium iron phosphate powder; Diluting a ionic membrane liquid alkali, adding the lithium iron phosphate powder to the alkali, stirring under an oxidizing atmosphere in water bath to perform a reaction; filtering a resulting product to obtain a leachate and a lithium phosphate slag; drying the lithium phosphate slag, adding an ammonia aqueous solution to the slag to perform a reaction, filtering to obtain an ammonia aqueous solution containing lithium phosphate and a filter residue; the ammonia aqueous solution containing lithium phosphate is evaporated to obtain lithium phosphate. By adopting the present method of removing aluminum by alkaline leaching under an oxidizing atmosphere, the aluminum content in the obtained lithium iron phosphate slag is 0.08%.

Abstract: The present disclosure discloses a recycling method for a mixed waste material of lithium nickel manganese cobalt oxide (LNMCO) and lithium iron phosphate (LFP), including: conducting acid-leaching to obtain an acid-leaching liquor with nickel, cobalt, manganese, phosphorus, iron, and lithium; conducting adsorption separation with a resin, washing the resin with sulfuric acid to obtain a mixed solution of nickel sulfate, cobalt sulfate, and manganese sulfate, and subjecting the mixed solution to precipitation to obtain an LNMCO cathode material precursor; and subjecting an obtained solution with phosphorus, iron, and lithium to lithium precipitation to obtain a lithium salt precipitate, and subjecting a post-precipitation solution to concentration and electrospinning to obtain a ferric phosphate/carbon material. The process of the present disclosure can achieve comprehensive recycling of a mixed waste material of LNMCO and LFP and the directed circulation of waste LNMCO and LFP materials.