Abstract: The disclosure provides a polyurethane-acrylate water repellant prepared by double bonds in the side chain, and belongs to the technical field of environment-friendly polymers. The disclosure introduces the carbon-carbon double bonds into the polyurethane side chain through a carbon-carbon double bond-containing dihydroxy micromolecular chain extender having a carbon chain structure to adjust the number of double bonds on a waterborne polyurethane chain segment participating in a free radical polymerization with acrylate monomers, thereby generating a branched structure, and improving the compatibility of polyurethane and acrylate; the fastness of a fabric is increased by combining an oxime blocking structure with the fabric. The polyurethane-acrylate water repellant prepared by the disclosure is non-toxic and low in VOC, and the finished fabric has significantly improved physical and chemical properties, and good application prospects.

Abstract: The disclosure relates to a method for improving the alkali resistance and oxidation resistance of a benzisothiazole disperse dye, and belongs to the technical field of textiles. In the disclosure, azo alkali-resistant disperse dyes with benzisothiazole as a diazo component are synthesized based on structural design of the dyes, the alkali resistance and oxygen bleaching resistance of the heterocyclic azo disperse dyes are improved by introducing different groups to a coupling component, a series of benzisothiazole disperse dyes having gradient differences in alkali resistance and oxidation resistance are obtained, disperse dyes capable of meeting requirements of a one-bath process for cotton bleaching and disperse dyeing of a polyester-cotton blended fabric or a one-bath process for alkali deweighting and disperse dyeing of polyester fabrics are determined, and a reference can be provided for structural design of disperse dyes with alkali resistance and oxidation resistance.

Abstract: The disclosure relates to a method for improving the alkali resistance and oxidation resistance of a benzothiazole disperse dye, and belongs to the field of disperse dyes. In the disclosure, 4 kinds of diazo components and 8 kinds of coupling components are used in designing and synthesizing 28 thiazole heterocyclic azo disperse dyes, and the alkali resistance and oxidation resistance of the disperse dyes are improved. Structure confirmation is performed on the synthetic disperse dyes, and the alkali resistance, oxidation resistance and other dyeing properties of the disperse dyes are tested.

Abstract: The disclosure provides a polyurethane-acrylate water repellant prepared by double bonds in the side chain, and belongs to the technical field of environment-friendly polymers. The disclosure introduces the carbon-carbon double bonds into the polyurethane side chain through a carbon-carbon double bond-containing dihydroxy micromolecular chain extender having a carbon chain structure to adjust the number of double bonds on a waterborne polyurethane chain segment participating in a free radical polymerization with acrylate monomers, thereby generating a branched structure, and improving the compatibility of polyurethane and acrylate; the fastness of a fabric is increased by combining an oxime blocking structure with the fabric. The polyurethane-acrylate water repellant prepared by the disclosure is non-toxic and low in VOC, and the finished fabric has significantly improved physical and chemical properties, and good application prospects.

Abstract: The present disclosure discloses a pad-steam bleaching method based on a TBLC-activated hydrogen peroxide system, and belongs to the field of pretreatment processing of textiles. According to the pad-steam bleaching method based on the TBLC-activated hydrogen peroxide system, TBCC and H2O2 are compounded with a weak base to prepare a TBCC/H2O2/weak base system for performing near-neutral bleaching on cotton fabrics; the fabrics are padded and then steamed to be bleached. By the method disclosed by the present disclosure, the whiteness of fabric treated for 2 minutes by a TBCC/H2O2/sodium citrate padding and steaming system is significantly superior to that of fabric treated for 60 minutes by an H2O2/NaOH dip bleaching system. The CIE whiteness of the fabric reaches 77 and above, the fabric wettability after treatment is also improved, the damage of the fabric is smaller, and the amount of water used by the method is small.

Abstract: The present disclosure discloses a pad-steam bleaching method based on a TBLC-activated hydrogen peroxide system, and belongs to the field of pretreatment processing of textiles. According to the pad-steam bleaching method based on the TBLC-activated hydrogen peroxide system, TBCC and H2O2 are compounded with a weak base to prepare a TBCC/H2O2/weak base system for performing near-neutral bleaching on cotton fabrics; the fabrics are padded and then steamed to be bleached. By the method disclosed by the present disclosure, the whiteness of fabric treated for 2 minutes by a TBCC/H2O2/sodium citrate padding and steaming system is significantly superior to that of fabric treated for 60 minutes by an H2O2/NaOH dip bleaching system. The CIE whiteness of the fabric reaches 77 and above, the fabric wettability after treatment is also improved, the damage of the fabric is smaller, and the amount of water used by the method is small.

Abstract: The present invention provides a method for synthesizing cationic bleach activators via a single-bath reaction, comprising steps of: separately dissolving 4-chloromethylbenoyl chloride and lactam in its respective solvent, adding an acid-binding agent to the lactam solution, next adding dropwisely 4-chloromethylbenoyl chloride solution into the lactam/acid binding-agent solution, and finally adding tertiary amine to the solution above to make a reaction solution, which is further treated with mixing and refluxing. The washed and dried final product is TBLC cationic bleach activator. The method of the present invention greatly simplifies the synthesizing process and lowers the stringency of reaction conditions for preparing cationic bleach activators (TBLC). At the same time, the present method produces TBLC cationic bleach activators with high yields, making it a suitable option for industrial production of these bleach activators.

Abstract: The present invention provides a method for synthesizing cationic bleach activators via a single-bath reaction, comprising steps of: separately dissolving 4-chloromethylbenoyl chloride and lactam in its respective solvent, adding an acid-binding agent to the lactam solution, next adding dropwisely 4-chloromethylbenoyl chloride solution into the lactam/acid binding-agent solution, and finally adding tertiary amine to the solution above to make a reaction solution, which is further treated with mixing and refluxing. The washed and dried final product is TBLC cationic bleach activator. The method of the present invention greatly simplifies the synthesizing process and lowers the stringency of reaction conditions for preparing cationic bleach activators (TBLC). At the same time, the present method produces TBLC cationic bleach activators with high yields, making it a suitable option for industrial production of these bleach activators.

Abstract: The present invention provides a novel, non-toxic and eco-friendly hydrogen peroxide activator, a method for its production and its application. The activator can effectively activate H2O2 under mild conditions, such as low temperature and nearly neutral aqueous solution, making it a more advantageous alternative to traditional activators. The novel activator can further expand the application of H2O2 in the fields, such as textile, paper making and health care.

Abstract: The present invention provides a novel, non-toxic and eco-friendly hydrogen peroxide activator, a method for its production and its application. The activator can effectively activate H2O2 under mild conditions, such as low temperature and nearly neutral aqueous solution, making it a more advantageous alternative to traditional activators. The novel activator can further expand the application of H2O2 in the fields, such as textile, paper making and health care.