Abstract: Embodiments of the present disclosure are directed to thermoplastic elastomer articles comprising a crosslinked reaction product of styrene block copolymer and silane. The styrene block copolymer comprises at least one terminal polymer block A. The at least one terminal polymer block A comprises a vinyl compound having para-alkylstyrene. The styrene block copolymer is silane grafted and silane crosslinked.

Abstract: Embodiments of the present disclosure are directed to thermoplastic elastomer articles comprising a crosslinked reaction product of styrene block copolymer, rubber, and silane. The styrene block copolymer comprises at least one terminal polymer block A. The at least one terminal polymer block A comprises a vinyl compound having para-alkyl styrene. The rubber comprises at least one of ethylene propylene diene rubber, silicone rubber, and nitrile butadiene rubber. The styrene block copolymer and the rubber are silane grafted and silane crosslinked. The silane crosslinking is at least one of intramolecular silane crosslinking and intermolecular silane crosslinking.

Abstract: Thermoplastic articles are molded from thermoplastic polyurethane compounds including blends of aliphatic polycaprolactone thermoplastic polyurethane and aromatic thermoplastic polyurethane selected from aromatic polyester thermoplastic polyurethane, aromatic polyether thermoplastic polyurethane, and combinations thereof. The thermoplastic articles exhibit enhanced stain resistance, as represented by achieving a rating of 2 or better according to Blue Jean Abrasion Test, relative to thermoplastic articles molded from thermoplastic polyurethane compounds including either aromatic polyester thermoplastic polyurethane or aromatic polyether thermoplastic only, while also having good clarity (i.e., low haze) and other desirable properties. The thermoplastic articles can be especially useful as protective cases for handheld electronic devices.

Abstract: Embodiments of the present disclosure are directed to thermoset articles including a crosslinked reaction product of thermoplastic polyolefin, at least one of ethylene alpha-olefin polyolefin elastomer and ethylene propylene diene rubber, nitrile butadiene rubber, and silane. At least one of the thermoplastic polyolefin, the at least one of the ethylene alpha-olefin polyolefin elastomer and the ethylene propylene diene rubber, and the nitrile butadiene rubber is silane grafted and silane crosslinked. The silane crosslinking is at least one of intramolecular silane crosslinking and intermolecular silane crosslinking.

Abstract: Embodiments of the present disclosure are directed to thermoset articles including a crosslinked reaction product of thermoplastic polyolefin, at least one of ethylene alpha-olefin polyolefin elastomer and ethylene propylene diene rubber, silicone rubber, and silane. The silicone rubber has at least one vinyl functional group. At least one of the thermoplastic polyolefin, the at least one of the ethylene alpha-olefin polyolefin elastomer and the ethylene propylene diene rubber, and the silicone rubber is silane grafted and silane crosslinked. The silane crosslinking is at least one of intramolecular silane crosslinking and intermolecular silane crosslinking.

Abstract: Embodiments of the present disclosure are directed to thermoplastic elastomer articles including a crosslinked reaction product of polar elastomer, rubber, and silane. The rubber comprises at least one of nitrile butadiene rubber, silicone rubber, ethylene alpha-olefin polyolefin elastomer, and ethylene propylene diene rubber. The rubber is silane grafted and silane crosslinked. The silane crosslinking is at least one of intramolecular silane crosslinking and intermolecular silane crosslinking.

Abstract: Embodiments of the present disclosure are directed to electronic devices comprising a housing comprising a polymer blend. The polymer blend comprises at least one of an aromatic polyether thermoplastic polyurethane and a copolyester elastomer, and a dielectric constant modifier comprising at least one of a polyolefin and a block copolymer comprising at least one polyolefin block. The electronic devices receive signals greater than or equal to 2.5 Gigahertz.

Abstract: Embodiments of the present disclosure are directed to thermoplastic elastomer blends comprising at least one non-hydrogenated styrene isoprene block copolymer (SIS) having a Weight Average Molecular Weight (Mw) greater than or equal to 50,000 g/mol and a Tan Delta Peak Temperature greater than or equal to 15° C. and less than or equal to 25° C. at least one of: at least one hydrogenated SIS having an Mw greater than or equal to 75,000 g/mol and a Tan Delta Peak Temperature less than or equal to 20° C.; and a styrene-ethylene/butylene-styrene block copolymer (SEBS) having a Mw greater than or equal to 75,000 g/mol and a Tan Delta Peak Temperature less than or equal to 20° C.; and a tackifier having a softening point greater than or equal to 80° C.

Abstract: Thermoplastic articles are molded from thermoplastic polyurethane compounds including blends of aromatic polycaprolactone thermoplastic polyurethane and aliphatic polycaprolactone thermoplastic polyurethane. The thermoplastic articles can have enhanced stability against exposure to ultraviolet (UV) light relative to thermoplastic articles molded from thermoplastic polyurethane compounds including only aromatic polycaprolactone thermoplastic polyurethane as the thermoplastic polyurethane component. Additionally, the thermoplastic articles can have good stain resistance, good clarity (i.e., low haze), and other desirable properties.

Abstract: A thermoplastic elastomer compound includes polyester-type thermoplastic polyurethane and no greater than about 30 weight percent of styrene-isobutylene-styrene block copolymer. The compound has good clarity, as exhibited by a haze of no greater than about 60%, or 50%, or 30%, according to ASTM D 1003. Additionally, the compound has good damping properties, as exhibited by a resilience or vertical rebound of less than about 25% according to ASTM D2632.

Abstract: A thermoplastic elastomer compound includes polyolefin elastomer, high softening point tackifier, and, optionally, styrenic block copolymer. When styrenic block copolymer is present, the weight ratio of polyolefin elastomer to styrenic block copolymer is no less than about 1:1. The polyolefin elastomer has a POE Tan Delta Peak Temperature, the styrenic block copolymer has a SBC Tan Delta Peak Temperature, and the thermoplastic elastomer compound has a Compound Tan Delta Peak Temperature. The Compound Tan Delta Peak Temperature is greater than the POE Tan Delta Peak Temperature. When styrenic block copolymer is present, Compound Tan Delta Peak Temperature is also greater than the SBC Tan Delta Peak Temperature. The thermoplastic elastomer compound exhibits useful damping properties at or above room temperature and can be formed into plastic articles, including foamed plastic articles and/or crosslinked plastic articles, which can be useful for a variety of damping applications.

Abstract: An overmolded thermoplastic article includes a substrate portion molded from a thermoplastic resin compound and an overmold portion molded from a thermoplastic elastomer compound. The thermoplastic resin compound includes thermoplastic polymer resin. The thermoplastic elastomer compound includes thermoplastic elastomer and polysiloxane as a mold release agent, and is free of wax. The overmold portion is bonded onto the substrate portion with a peel strength at least comparable to that of an overmolded thermoplastic elastomer compound containing wax as a mold release agent instead of the polysiloxane. Undesirable effects observed with the use of wax as a mold release agent in overmolded thermoplastic elastomer compounds such as blooming and ease of scratching/marring can be reduced, while desirable properties such as silky feel of the surface of the overmold portion and good bonding of the overmold portion onto the substrate portion can be at least maintained.

Abstract: A tackifier to modify the Tan Delta of midblock segments of a hydrogenated styrenic block copolymer in a thermoplastic elastomer compounds aids in rendering the HSBC TPE more effective as an overmolding compound having a low percentage compression set value when measured at the high temperature compression set standard. The HSBC TPE can overmold effectively upon polar polymeric substrates depending on the bonding agent chosen.

Abstract: Thermoplastic articles are molded from thermoplastic polyurethane compounds including aromatic polycaprolactone thermoplastic polyurethane. The thermoplastic articles exhibit enhanced stain resistance, as represented by achieving a rating of 1 according to Blue Jean Abrasion Test, relative to thermoplastic articles molded from thermoplastic polyurethane compounds including other types of thermoplastic polyurethanes, while also having good clarity (i.e., low haze) and other desirable properties. The thermoplastic articles can be especially useful as protective cases for handheld electronic devices.

Abstract: Thermoplastic articles are molded from thermoplastic polyurethane compounds including blends of aromatic polycaprolactone thermoplastic polyurethane and other aromatic thermoplastic polyurethane selected from aromatic polyester thermoplastic polyurethane, aromatic polyether thermoplastic, and combinations thereof. The thermoplastic articles exhibit enhanced stain resistance, as represented by achieving a rating of 2 or better according to Blue Jean Abrasion Test, relative to thermoplastic articles molded from thermoplastic polyurethane compounds including either aromatic polyester thermoplastic polyurethane or aromatic polyether thermoplastic only, while also having good clarity (i.e., low haze) and other desirable properties. The thermoplastic articles can be especially useful as protective cases for handheld electronic devices.

Abstract: Thermoplastic articles are molded from thermoplastic polyurethane compounds including blends of aliphatic poly-caprolactone thermoplastic polyurethane and aromatic thermoplastic polyurethane selected from aromatic polyester thermoplastic polyurethane, aromatic polyether thermoplastic polyurethane, and combinations thereof. The thermoplastic articles exhibit enhanced stain resistance, as represented by achieving a rating of 2 or better according to Blue Jean Abrasion Test, relative to thermoplastic articles molded from thermoplastic polyurethane compounds including either aromatic polyester thermoplastic polyurethane or aromatic polyether thermoplastic only, while also having good clarity (i.e., low haze) and other desirable properties. The thermoplastic articles can be especially useful as protective cases for handheld electronic devices.

Abstract: Thermoplastic elastomer compounds include (a) at least about 40 weight percent of thermoplastic polyurethane selected from polycaprolactone-type thermoplastic polyurethane, polyether-type thermoplastic polyurethane, and combinations thereof, and (b) at most about 5 weight percent of polysiloxane. The thermoplastic elastomer compounds can be molded into thermoplastic articles which exhibit substantially no blooming after weathering, while also exhibiting good processability, useful functionality, and desirable aesthetics. The thermoplastic compounds can be especially useful for making overmolded thermoplastic articles.

Abstract: A tackifier to modify the Tan Delta of midblock segments of a hydrogenated styrenic block copolymer in a thermoplastic elastomer compounds aids in rendering the HSBC TPE more effective as an overmolding compound having a low percentage compression set value when measured at the high temperature compression set standard. The HSBC TPE can overmold effectively upon polar polymeric substrates depending on the bonding agent chosen.

Abstract: An overmolded thermoplastic article includes a substrate portion molded from a thermoplastic resin compound and an overmold portion molded from a thermoplastic elastomer compound. The thermoplastic resin compound includes thermoplastic polymer resin. The thermoplastic elastomer compound includes thermoplastic elastomer and polysiloxane as a mold release agent, and is free of wax. The overmold portion is bonded onto the substrate portion with a peel strength at least comparable to that of an overmolded thermoplastic elastomer compound containing wax as a mold release agent instead of the polysiloxane. Undesirable effects observed with the use of wax as a mold release agent in overmolded thermoplastic elastomer compounds such as blooming and ease of scratching/marring can be reduced, while desirable properties such as silky feel of the surface of the overmold portion and good bonding of the overmold portion onto the substrate portion can be at least maintained.

Abstract: A thermoplastic elastomer compound includes hydrogenated styrenic block copolymer having a polyisoprene soft block, styrene-isobutylene-styrene block copolymer, tackifier having a softening point of at least about 80° C. according to ASTM 6493, and, optionally, one or more additional thermoplastic elastomers. The compound has a Compound Tan Delta Peak Temperature (at 10 Hz) of at least 10° C. and a Compound Tan Delta Peak Height (at 10 Hz) of at least 0.85 if no thermoplastic polyurethane is present and at least 0.60 if additional thermoplastic elastomer is present and includes thermoplastic polyurethane. The thermoplastic elastomer compound exhibits superior damping properties across a broad range of temperatures, including at or above room temperature, and across a broad range of vibrational frequencies. The compound in sheet form can be used as a layer in an article of a structure susceptible to forceful impact of any item.