Abstract: The disclosure is directed to an article including a first layer, second layer, and third layer. The first layer includes a fluoropolymer having a first major surface and a second major surface. The second layer overlies the first major surface of the first layer and includes an adhesive layer. The third layer overlies the second layer and includes a polymeric material. The article has a burst performance greater than 200 N as measured by ASTM D751 and a chemical permeation breakthrough detection time greater than about one hour as measured by ASTM F739. The disclosure is further directed to a method of forming the aforementioned multi-layer article.

Abstract: The disclosure is directed to a barrier structure including a fluoropolymer layer and a polymeric layer. The barrier structure has a chemical permeation breakthrough detection time greater than about one hour for hazardous chemicals as measured by ASTM F739. The disclosure is further directed to a method of forming the aforementioned barrier structure. The barrier material is designed to be suitable for construction of shelters, clothing, containers and other articles requiring barrier properties.

Abstract: The disclosure is directed to a barrier structure including a fluoropolymer layer and a polymeric layer. The barrier structure has a chemical permeation breakthrough detection time greater than about one hour for hazardous chemicals as measured by ASTM F739. The disclosure is further directed to a method of forming the aforementioned barrier structure. The barrier material is designed to be suitable for construction of shelters, clothing, containers and other articles requiring barrier properties.

Abstract: The disclosure is directed to an article including a first layer, second layer, and third layer. The first layer includes a fluoropolymer having a first major surface and a second major surface. The second layer overlies the first major surface of the first layer and includes an adhesive layer. The third layer overlies the second layer and includes a polymeric material. The article has a burst performance greater than 200 N as measured by ASTM D751 and a chemical permeation breakthrough detection time greater than about one hour as measured by ASTM F739. The disclosure is further directed to a method of forming the aforementioned multi-layer article.

Abstract: A method of forming a seal for a subterranean drilling tool employs irradiation. The seal is formed of a single homogeneous elastomeric material. The seal has an exterior surface with at least one portion that is in sliding engagement with part of a seal gland of the drilling tool. A property gradient is formed in the elastomeric material on at least this portion. The property gradient is formed by exposing the seal to an environment to define a property that changes from a first level to a second level without essentially changing the composition of the elastomeric material. The step of exposing is done by irradiating the seal with an electron beam.