Abstract: This invention relates to a process for the electrochemical synthesis of green urea, and the urea produced thereby. The electrochemical synthesis of urea involves the reduction of dual purging gases N2 and CO2 via six electron transfer process (N2+CO2+6H++6e??CO (NH2)2+H2O) & reduction of the NO3? ions and CO2 via sixteen electron transfer process (2NO3?+CO2+18H++16e??CO(NH2)2+7H2O) under ambient condition using copper phthalocyanine (CuPc) catalyst. The binding of two intermediate products during dual reduction simultaneously, leads to the production of urea in water medium under ambient conditions.