Abstract: The invention relates to a water-in-oil coating composition comprising a water phase emulsified in a non-aqueous liquid phase, wherein the non-aqueous phase comprises an autoxidizable binder and wherein an inorganic first salt and an organic second salt are dissolved in the water phase, wherein the inorganic first salt has a solubility in water of at least 100 grams per liter as determined at 20° C., and a solubility in the non-aqueous phase of less than 1.0 grams per liter as determined at 20° C., and wherein the second salt is an organic salt of an alkali or alkaline earth metal, and wherein the coating composition comprises a primary drier. The invention further relates to a substrate coated with a coating deposited from such water-in-oil coating composition.

Abstract: A water-in-oil coating composition comprising a water phase emulsified in a non-aqueous liquid phase, wherein the non-aqueous phase comprises an autoxidizable binder and wherein a salt is dissolved in the water phase, wherein the salt is a carbonate or an organic salt of an alkali or alkaline earth metal, and wherein the coating composition comprises a primary drier. A substrate coated with a coating deposited from such water-in-oil coating composition, and a process to improve the aged drying of a water-in-oil coating composition comprising dissolving such salt in the water phase of a water-in-oil coating composition.

Abstract: The invention relates to a coating composition comprising an autoxidizable alkyd-based resin and a drier composition, the drier composition comprising: a) an iron-ligand complex comprising iron and at least one bispidine ligand; and b) a vanadium compound; wherein the amount of the vanadium compound is such that the coating composition comprises vanadium in a concentration in the range of from 0.01 wt % to 1.0 wt %, based on the solid weight of alkyd-based resin and wherein the amount of iron-ligand complex is such that the coating composition comprises iron in a concentration in the range of from 0.5·10?4 wt % to 5·10?3 wt %, based on the solid weight of alkyd-based resin.

Abstract: A drier for air-drying an auto-oxidizable resin composition, said drier comprising: 1,4,7-trialkyl-1,4,7-triazacyclononane (L); a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, Cl?, Br?, I?, NO3, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20) aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of Mn:L is at least 1.25:1 and preferably at least 1.5:1.

Abstract: A mixture for use as a drier for air-drying an auto-oxidizable resin composition, said mixture comprising : 1,4,7-trialkyl-1,4,7-triazacyclononane (L); and, a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, CI?, Br?, I?, NO3?, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of L:Mn is at least 1.25:1 and more preferably at least 1.5:1.

Abstract: The invention relates to a drier for an air drying auto-oxidisable resin composition comprising a polymer comprising unsaturated fatty acid residues, the drier comprising a manganese triaza complex comprising the following structure: wherein R1=C1-C20alkyl optionally substituted with heteroatoms, or C6-C20aryl optionally substituted with heteroatoms; X and Y are independently selected from O and OC(R2)O, in which a=4 when X=O, and a=3 when X=OC(R2)O, and in which b=4 when Y=O, and b=3 when Y=OC(R2)O; Wherein R2=C1-C20alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue, and one or more anions, being chosen PF6-, SbF6—, AsF6-, BF4—, B(C6F5)4—, Cl—, Br—, I—, NO3—, or R3COO— or SO42?, and wherein R3 is C1-C20alkyl optionally substituted with heteroatoms, C6-C20aryl 1optionally substituted with heteroatoms, or a polymeric residue, and wherein the drier comprises an additional amount of, 4,7-trialkyl-1,4,7-triazacyclononane; wherein the 1,4,7-tr

Abstract: A drier for air-drying an auto-oxidizable resin composition, said drier comprising: 1,4,7-trialkyl-1,4,7-triazacyclononane (L); a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, CI?, Br?, I?, NO3, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20) aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of Mn:L is at least 1.25:1 and preferably at least 1.5:1.

Abstract: A mixture for use as a drier for air-drying an auto-oxidizable resin composition, said mixture comprising : 1,4,7-trialkyl-1,4,7-triazacyclononane (L); and, a manganese salt having the general formula Mn2+[X]n, wherein anion X is selected from PF6?, SbF6?, AsF6?, BF4?, B(C6F5)4?, Cl?, Br?, I?, NO3?, or R2COO? in which case n=2, or the anion X is SO42? in which case n=1, and wherein R2 is C1-C20 alkyl optionally substituted with heteroatoms, C6-C20 aryl optionally substituted with heteroatoms, or a polymeric residue; wherein the 1,4,7-trialkyl-1,4,7-triazacyclononane (L) is present in the mixture in an amount such that the molar ratio of L:Mn is at least 1.25:1 and more preferably at least 1.5:1.