Abstract: A method for manufacturing a play-of-color article includes the steps of: (a) providing a first mixture that contains a solvent and a plurality of functionalized colloidal particles; (b) replacing the solvent of the first mixture with a polymer solution that contains polymers, thereby obtaining a second mixture; (c) adding an initiator to the second mixture to obtain a third mixture, followed by injecting the third mixture into a mold and disturbing the third mixture, so that the third mixture is formed with a pattern; (d) leaving the third mixture to stand, so as to allow the functionalized colloidal particles therein to self-assemble to form a crystalline arrangement, thereby obtaining a fourth mixture; and (e) subjecting the polymers in the fourth mixture to a cross-linking reaction, thereby obtaining the play-of-color article. A play-of-color article manufactured by the method, and a play-of-color product including the play-of-color article are also provided.