Patents by Inventor Jixing Ma
Jixing Ma has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11325994Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high activity and a long term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.Type: GrantFiled: September 22, 2017Date of Patent: May 10, 2022Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Jun Wang, Mingzhi Gao, Haitao Liu, Jing Ma, Jixing Ma, Xiaoxia Cai, Jianhua Chen, Jianjun Hu, Changxiu Li, Zhihui Zhang, Ruilin Duan, Changyou Ma
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Patent number: 10662268Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high long-term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.Type: GrantFiled: September 22, 2017Date of Patent: May 26, 2020Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Jun Wang, Mingzhi Gao, Jing Ma, Haitao Liu, Jianhua Chen, Xiaoxia Cai, Jixing Ma, Jianjun Hu, Changxiu Li, Zhihui Zhang, Changyou Ma
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Publication number: 20190256623Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high long-term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.Type: ApplicationFiled: September 22, 2017Publication date: August 22, 2019Inventors: Jun WANG, Mingzhi GAO, Jing MA, Haitao LIU, Jianhua CHEN, Xiaoxia CAI, Jixing MA, Jianjun HU, Changxiu LI, Zhihui ZHANG, Changyou MA
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Publication number: 20190211119Abstract: Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high activity and a long term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.Type: ApplicationFiled: September 22, 2017Publication date: July 11, 2019Inventors: Jun WANG, Mingzhi GAO, Haitao LIU, Jing MA, Jixing MA, Xiaoxia CAI, Jianhua CHEN, Jianjun HU, Changxiu LI, Zhihui ZHANG, Ruilin DUAN, Changyou MA
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Patent number: 10208145Abstract: The present invention provides a catalyst component for olefin polymerization, obtained by a reaction of magnesium, titanium, halogen and an internal electron donor, the internal electron donor comprising an imine compound as shown in Formula Z. The present invention also provides a preparation method of the catalyst component, and a catalyst for olefin polymerization containing the same. When the catalyst of the present invention is used for olefin polymerization reaction, the catalyst has a high activity, and a slow rate of activity decay, and the obtained polymer has a high isotacticity index, and a wide molecular weight distribution.Type: GrantFiled: April 24, 2015Date of Patent: February 19, 2019Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroteum & Chemical CorporationInventors: Mingzhi Gao, Jun Wang, Haitao Liu, Jing Ma, Jianhua Chen, Jixing Ma, Xiaoxia Cai, Changxiu Li, Jianjun Hu, Xiaofan Zhang, Xianzhong Li, Zhihui Zhang, Ruilin Duan, Linna Yang, Changyou Ma
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Patent number: 10184017Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.Type: GrantFiled: April 24, 2015Date of Patent: January 22, 2019Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical CorporationInventors: Jun Wang, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xiaoxia Cai, Jixing Ma, Changxiu Li, Jianjun Hu, Xiaofan Zhang, Xianzhong Li, Zhihui Zhang, Ruilin Duan, Linna Yang, Changyou Ma
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Patent number: 9822196Abstract: The present disclosure discloses a catalyst composition for olefin polymerization, comprising the following components: a): a solid catalyst component containing magnesium, titanium, halogens, and at least one internal electron donor having a lone pair of electrons; b): an aluminum alkyl compound; and c): an external electron donor containing a first external electron donor C1, which is a malonate compound. In the present disclosure, a catalyst composition having an external electron donor that contains a malonate compound is used in olefin polymerization, in particular propene polymerization, and can significantly improve catalytic activity and hydrogen response of the catalyst and expand molecular weight distribution of polymers, which facilitates development of different polymers.Type: GrantFiled: September 28, 2014Date of Patent: November 21, 2017Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xianzhong Li, Xiaoxia Cai, Jixing Ma, Jun Wang, Jianjun Hu
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Patent number: 9751960Abstract: The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved.Type: GrantFiled: May 21, 2014Date of Patent: September 5, 2017Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical CorporationInventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jianhua Chen, Jing Ma, Jixing Ma, Xiaoxia Cai, Jun Wang, Xiaofan Zhang, Jianjun Hu
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Publication number: 20170073441Abstract: The present invention provides a catalyst component for olefin polymerization, obtained by a reaction of magnesium, titanium, halogen and an internal electron donor, the internal electron donor comprising an imine compound as shown in Formula Z. The present invention also provides a preparation method of the catalyst component, and a catalyst for olefin polymerization containing the same. When the catalyst of the present invention is used for olefin polymerization reaction, the catalyst has a high activity, and a slow rate of activity decay, and the obtained polymer has a high isotacticity index, and a wide molecular weight distribution.Type: ApplicationFiled: April 24, 2015Publication date: March 16, 2017Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroteum & Chemical CorporationInventors: Mingzhi GAO, Jun WANG, Haitao LIU, Jing MA, Jianhua CHEN, Jixing MA, Xiaoxia CAI, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA
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Publication number: 20170044280Abstract: The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity.Type: ApplicationFiled: April 24, 2015Publication date: February 16, 2017Applicants: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry China Petroleum & Chemical CorporationInventors: Jun WANG, Mingzhi GAO, Haitao LIU, Jing MA, Jianhua CHEN, Xiaoxia CAI, Jixing MA, Changxiu LI, Jianjun HU, Xiaofan ZHANG, Xianzhong LI, Zhihui ZHANG, Ruilin DUAN, Linna YANG, Changyou MA
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Publication number: 20160244538Abstract: The present disclosure discloses a catalyst composition for olefin polymerization, comprising the following components: a): a solid catalyst component containing magnesium, titanium, halogens, and at least one internal electron donor having a lone pair of electrons; b): an aluminum alkyl compound; and c): an external electron donor containing a first external electron donor C1, which is a malonate compound. In the present disclosure, a catalyst composition having an external electron donor that contains a malonate compound is used in olefin polymerization, in particular propene polymerization, and can significantly improve catalytic activity and hydrogen response of the catalyst and expand molecular weight distribution of polymers, which facilitates development of different polymers.Type: ApplicationFiled: September 28, 2014Publication date: August 25, 2016Inventors: Changxiu Liu, Mingzhi Gao, Haitao Liu, Jing Ma, Jianhua Chen, Xianzhong Li, Xiaoxia Cai, Jixing Ma, Jun Wang, Jianjun Hu
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Publication number: 20160115257Abstract: The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved.Type: ApplicationFiled: May 21, 2014Publication date: April 28, 2016Inventors: Changxiu Li, Mingzhi Gao, Haitao Liu, Jianhua Chen, Jing Ma, Jixing Ma, Xiaoxia Cai, Jun Wang, Xiaofan Zhang, Jianjun Hu
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Patent number: 9156927Abstract: A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.Type: GrantFiled: April 22, 2011Date of Patent: October 13, 2015Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Mingzhi Gao, Changxiu Li, Haitao Liu, Xiaofan Zhang, Jianhua Chen, Jing Ma, Xiaoxia Cai, Xianzhong Li, Jixing Ma
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Publication number: 20130225773Abstract: A catalyst component for olefin polymerization which contains magnesium, titanium, halogen and electron donors is provided in the present invention. The electron donors are selected from at least one succinate compounds of following general formula (I), and the content of said succinate compounds with the structure as shown in Formula (II) in said succinate compounds (I) is less than 100%, but not less than 51.0 wt %. Compared with the mesomer whose content with the structure as shown in Formula (II) is 100%, the catalyst component provided by the present invention not only greatly decreases the manufacturing cost, but also improves certain properties of the catalyst, for example the molecular weight distribution of polymer obtained by catalytic reaction using said catalyst is wider, which is beneficial for improving processing properties of polymers. The corresponding catalyst is also provided.Type: ApplicationFiled: August 12, 2011Publication date: August 29, 2013Applicants: Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation, China Petroleum & Chemical CorporationInventors: Mingzhi Gao, Changxiu Li, Haitao Liu, Xianzhong Li, Xiaofan Zhang, Xiaoxia Cai, Jianhua Chen, Jing Ma, Jixing Ma
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Publication number: 20130041120Abstract: A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.Type: ApplicationFiled: April 22, 2011Publication date: February 14, 2013Applicant: China Petroleum & Chemical CorporationInventors: Mingzhi Gao, Changxiu Li, Haitao Liu, Xiaofan Zhang, Jianhua Chen, Jing Ma, Xiaoxia Cai, Xianzhong Li, Jixing Ma