Abstract: A catalyst for treating an exhaust gas stream comprising a NOx occluding catalyst structure having an outer layer comprising an alkaline earth component and a rare earth component.

Abstract: A gas treatment system and method for using the same is disclosed. The gas treatment system, comprises: a non-thermal plasma reactor; and a catalyst composition disposed within said non-thermal plasma reactor, said catalyst composition comprising a MZr4(PO4)6, wherein M is a metal selected from the group consisting of platinum, palladium, ruthenium, silver, rhodium, osmium, iridium, and combinations comprising at least one of said foregoing metals. The process comprises exposing said gas to a plasma field and to the catalyst composition.

Abstract: A system and method for treating a combustion exhaust stream includes admitting an exhaust stream into a non-thermal plasma reactor having at least one segmented non-thermal plasma element including a plurality of individually energizable electrode segments defining a plurality of corona volumes. In a preferred embodiment, the electrode segments are progressively smaller in size in the exhaust flow direction to provide optimum plasma volume variation. Individually energizable electrodes are selectively activated to effect variable corona volumes for treating an exhaust stream. Additional reactor segments are activated only as needed, such as during periods of high exhaust flow, for efficient treatment of the exhaust stream so as to maintain optimized high space velocity in the active corona volume. The segmented elements may comprise a variety of shapes. The system and method are particularly suitable for gas pretreatment and downstream diesel particulate filter regeneration.

Abstract: An active system for regenerating a NOx adsorber and a particulate filter, the system comprising a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the reformer, an oxidation catalyst, a NOx adsorber located downstream from the oxidation catalyst, a particulate filter located downstream from the NOx adsorber; and wherein the first valve, the second valve, and the third valve control fluid flow from the reformer to the oxidation catalyst, the NOx adsorber, and the particulate filter.

Abstract: An exhaust system can comprise a NOx adsorber, a reformer disposed upstream of a NOx adsorber and in fluid communication with a fuel source, a first valve for controlling the introduction of the fluid to an exhaust conduit; and a particulate filter disposed upstream and in fluid communication with the NOx adsorber and downstream an in fluid communication with the reformer such that the first valve controls introduction of fluid to the exhaust conduit upstream of the particulate filter. The reformer can be designed to generate a fluid comprising sufficient thermal energy, hydrogen, and carbon monoxide. Optionally, the particulate filter can be designed to be regenerated by the thermal energy and to adsorb a sufficient amount of the thermal energy to reduce the temperature of a gas stream comprising the fluid from a first temperature of about 600° C. to about 1,000° C. to a second temperature of less than or equal to about 500° C.

Abstract: In one embodiment, a method of treating a gas stream comprises: controlling an amount of the NH3 entering a catalytic unit and converting NO2 and the NH3 to N2 in the catalytic unit, wherein greater than or equal to about 60 wt % of NOx initially in the gas stream is converted to N2. In one embodiment, a gas treatment system comprises: a plasma reactor disposed downstream of an engine; a cracking catalyst disposed downstream of the engine; and a catalytic unit capable of converting NO and HC to NH3, and capable of converting NH3 and NO2 to N2.

Abstract: A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned. A method for forming a gas treatment device, comprises applying a slurry to a substrate, wherein the slurry comprises a support and a sufficient amount of SMSI material such that, upon exposure to a gas stream at a gas treatment device operating temperature, greater than or equal to about 50 wt % of hydrocarbons in the gas stream are cracked to a light fraction; applying a catalyst to the substrate; calcining the catalyst; and disposing the calcined substrate into a shell, with a retention material disposed between the shell and the calcined substrate.

Abstract: One embodiment of an ammonia gas sensor includes: a reference electrode, an ammonia selective sensing electrode and an electrolyte disposed therebetween. The sensing electrode comprises the reaction product of a main material selected from the group consisting of vanadium, tungsten, molybdenum, vanadium oxides, tungsten oxides, molybdenum oxides, and combinations comprising at least one of the foregoing main materials, and an electrically conducting material selected from the group consisting of electrically conductive metals, electrically conductive metal oxides, and combinations comprising at least one of the foregoing.

Abstract: An active system for regenerating a NOx adsorber and a particulate filter, the system comprising a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the reformer, an oxidation catalyst, a NOx adsorber located downstream from the oxidation catalyst, a particulate filter located downstream from the NOx adsorber; and wherein the first valve, the second valve, and the third valve control fluid flow from the reformer to the oxidation catalyst, the NOx adsorber, and the particulate filter.

Abstract: A gas treatment device, comprises a substrate disposed within a shell. The substrate comprises a catalyst composition comprising a support, a catalyst, and a sufficient amount of SMSI material such that, upon exposure to a gas stream (at a gas treatment device operating temperature), less than or equal to about 35 wt % of hydrocarbons in the gas stream are burned.

Abstract: In one embodiment, the process for treating a gas stream, comprises: introducing a gas stream to a plasma reactor, maintaining a reactor temperature of the plasma reactor at greater than or equal to about 70° C., and reducing the concentration of a gas stream component in the plasma reactor to produce a treated gas stream.

Abstract: A high-pressure metering pump for providing reductant in a single fluid engine exhaust dosing system, comprising: a solenoid for actuating a piston slidably received within an inner bore of a valve housing of the pump, the inner bore having a pressure chamber with an inlet check valve and an outlet check valve; and wherein movement of the piston causes high pressure reductant to be received at an atomizer of the system, the atomizer being disposed in a location to cause a maximum reduction of undesirable pollutant in the combustion gases of an engine.

Abstract: Disclosed herein are various embodiments of systems (including vehicle systems and fuel cell systems), as well as reformers and methods for operating the systems. In one embodiment, the reformer comprises: a support comprising a reforming catalyst and a hexaaluminate comprising a crystal stabilizer disposed in a hexaaluminate crystal structure. Meanwhile, one embodiment of the system comprises: a device selected from the group consisting of an engine, a fuel cell, and combinations thereof, and the reformer.

Abstract: Gas treatment devices and vehicle exhaust systems are disclosed herein. In one embodiment, the vehicle exhaust system, comprises: an engine, a gas treatment device disposed downstream from the engine, the gas treatment device comprising a housing, a substrate disposed within the housing, the substrate comprising a catalyst and a hexaaluminate comprising a catalyst stabilizer disposed in a hexaaluminate crystal structure.

Abstract: Disclosed herein are methods for depositing catalytic material on a support, methods for making a gas treatment device, and the gas treatment devices formed therefrom. In one embodiment, the method for disposing a catalytic material on a support comprises: contacting the support with a catalytic material and a supercritical fluid, changing the supercritical fluid to a non-supercritical fluid, and depositing at least a portion of the catalytic material in pores of the support, wherein the catalytic material has a first solubility in the supercritical fluid of greater than or equal to about 70% and a second solubility in the non-supercritical fluid of less than or equal to about 20%. In one embodiment, the method for making the gas treatment device comprises disposing the supported catalytic material onto a substrate and disposing the substrate in a housing comprising an inlet for receiving gas and an outlet.

Abstract: A non-thermal plasma (NTP) reactor structural conductor element includes a base conductor support and a high dielectric constant (“high k”) barrier layer supported by and substantially surrounding the base conductor support to form a structural conductor NTP reactor element. The structural conductor element may comprise a variety of shapes such as plates, sheets, half-box, I shapes, C shapes, or comb shapes, among others. In one embodiment, the dielectric barrier layer includes a coating applied to the base conductor support. In another embodiment, the dielectric barrier layer includes a high k film laminated to the base conductor support. In yet another embodiment, the base conductor support integrally forms the dielectric barrier layer via conversion of surfaces of the base conductor using electrochemical, thermal or chemical means to form the dielectric barrier layer.

Abstract: A NOx, catalyst combination for treating a lean exhaust gas stream comprising an alkaline earth-alumina catalyst and an alkaline earth-zeolite catalyst, arranged on a substrate such that the gas stream first contacts the alkaline earth-alumina catalyst prior to contacting the alkaline earth-zeolite catalyst.

Abstract: One embodiment of a non-precious metal catalyst for treating an exhaust gas stream comprises an alkali metal oxide component comprising lithium oxide, in combination with an alkaline earth support component, wherein the alkaline earth support component is an alkaline earth zeolite catalyst, an alkaline earth alumina catalyst, or a mixture thereof. Another embodiment of a non-precious metal catalyst for treating an exhaust gas stream comprises a substrate supporting a coating having more than about 6 weight percent of a lithium oxide component in combination with less than about 49 weight percent of an barium zeolite catalyst component and less than about 42 weight percent of a barium alumina catalyst component and not more than about 7 weight percent of a ceramic oxide binder.

Abstract: A method for controlling exhaust gases produced by an internal combustion engine, a medium encoded with a machine-readable computer program code for controlling exhaust gases produced by an internal combustion engine and a system for controlling exhaust gases produced by an internal combustion engine is provided wherein the system includes a vehicle sensor and an engine control module and wherein the method includes obtaining a vehicle data signal responsive to the engine performance of the internal combustion engine, processing the vehicle data signal so as to formulate an engine operating parameter, wherein the engine operating parameter is responsive to the hydrocarbon content of the exhaust gases and controlling the fuel introduced into the internal combustion engine in a manner responsive to the engine operating parameter.

Abstract: A gas treatment system and method for using the same is disclosed. The gas treatment system, comprises: a non-thermal plasma reactor; and a catalyst composition disposed within said non-thermal plasma reactor, said catalyst composition comprising a MZr4(PO4)6, wherein M is a metal selected from the group consisting of platinum, palladium, ruthenium, silver, rhodium, osmium, iridium, and combinations comprising at least one of said foregoing metals. The process comprises exposing said gas to a plasma field and to the catalyst composition.