Abstract: A method of increasing bubble stability of a needful high molecular weight bimodal high-density polyethylene resin in need thereof, the method comprising subjecting the needful high molecular weight bimodal high-density polyethylene resin to a determined amount of oxygen tailoring of the resin so as to independently increase both the resin's melt storage modulus G? (at G?=3000 pascals) and complex viscosity ratio SH1000, and thereby make an oxygen-tailored high molecular weight bimodal high-density polyethylene resin having a targeted increase in bubble stability. The method uses a tailoring effective amount of molecular oxygen (O2) to achieve the desired oxygen tailoring. The method uses these advanced rheological properties from dynamic mechanical spectroscopy, but analyzes the data in a different way that is more sensitive to changes in resin composition and properties, and yet achieves a resin regime having a targeted increase in bubble stability.

Abstract: A nucleating agent-free and LLDPE-free polyolefin composition for making films with enhanced barrier properties against water vapor and oxygen gas. Related aspects include formulations, manufactured articles, films, and methods.

Abstract: A method of increasing bubble stability of a needful high molecular weight bimodal high-density polyethylene resin in need thereof, the method comprising subjecting the needful high molecular weight bimodal high-density polyethylene resin to a determined amount of oxygen tailoring of the resin so as to independently increase both the resin's melt storage modulus G? (at G?=3000 pascals) and complex viscosity ratio SH1000, and thereby make an oxygen-tailored high molecular weight bimodal high-density polyethylene resin having a targeted increase in bubble stability. The method uses a tailoring effective amount of molecular oxygen (O2) to achieve the desired oxygen tailoring. The method uses these advanced rheological properties from dynamic mechanical spectroscopy, but analyzes the data in a different way that is more sensitive to changes in resin composition and properties, and yet achieves a resin regime having a targeted increase in bubble stability.

Abstract: A bimodal ethylene-co-1-hexene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A blown film consisting essentially of the bimodal ethylene-co-1-hexene copolymer. A method of synthesizing the bimodal ethylene-co-1-hexene copolymer. A method of making the blown film. A manufactured article comprising the bimodal ethylene-co-1-hexene copolymer.

Abstract: Embodiments are directed towards polyolefin compositions including a high molecular weight polyolefin and a low molecular weight polyolefin.

Abstract: In various embodiments, a polyethylene formulation has a density of greater than 0.940 g/cm3 when measured according to ASTM D792, and a high load melt index (I21) of 1.0 g/10 min to 10.0 g/10 min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load. Moreover, the polyethylene formulation has a peak molecular weight (Mp(GPC)) of less than 50,000 g/mol, a number average molecular weight (Mn(GPC)) of less than 30,000 g/mol, and a weight fraction (w1) of molecular weight (MW) less than 10,000 g/mol of less than or equal to 10.5 wt %, as determined by Gel Permeation Chromatography (GPC). Articles made from the polyethylene formulation, such as articles made by blow molding processes are also provided.

Abstract: In various embodiments, a bimodal polyethylene composition may have a density (?) from 0.952 g/cm3 to 0.957 g/cm3, a high load melt index (I21) from 1 to 10 dg/min, and a z-average molecular weight (Mz(GPC)) from 3,200,000 to 5,000,000 g/mol. The bimodal polyethylene composition may also have a peak molecular weight (Mp(GPC)) defined by the equation: Mp(GPC)<?2,805.3 MWD+102,688, wherein MWD is a molecular weight distribution defined by the equation: MWD=Mw(GPC)/Mn(GPC), Mw(GPC) is a weight average molecular weight of the bimodal polyethylene composition, Mn(GPC) is a number average molecular weight of the bimodal polyethylene composition. Additionally, the bimodal polyethylene composition has a ratio of the (Mz(GPC)) to the Mw(GPC) from 8.5 to 10.5. Articles made from the bimodal polyethylene composition, such as articles made by blow molding processes, are also provided.

Abstract: A nucleating agent-free and LLDPE-free polyolefin composition for making films with enhanced barrier properties against water vapor and oxygen gas. Related aspects include formulations, manufactured articles, films, and methods.

Abstract: In various embodiments, a polyethylene formulation has a density of greater than 0.940 g/cm3 when measured according to ASTM D792, and a high load melt index (I21) of 1.0 g/10 min to 10.0 g/10 min when measured according to ASTM D1238 at 190° C. and a 21.6 kg load. Moreover, the polyethylene formulation has a peak molecular weight (Mp(GPC)) of less than 50,000 g/mol, a number average molecular weight (Mn(GPC)) of less than 30,000 g/mol, and a weight fraction (w1) of molecular weight (MW) less than 10,000 g/mol of less than or equal to 10.5 wt %, as determined by Gel Permeation Chromatography (GPC). Articles made from the polyethylene formulation, such as articles made by blow molding processes are also provided.

Abstract: A bimodal ethylene-co-1-hexene copolymer consisting essentially of a higher molecular weight component and a lower molecular weight component and, when in melted form at 190 degrees Celsius, is characterized by a unique melt property space defined by a combination of high-load melt index, melt flow ratio, and melt elasticity properties. A blown film consisting essentially of the bimodal ethylene-co-1-hexene copolymer. A method of synthesizing the bimodal ethylene-co-1-hexene copolymer. A method of making the blown film. A manufactured article comprising the bimodal ethylene-co-1-hexene copolymer.

Abstract: A process for producing a heterophasic copolymer is provided. The process includes introducing an antifoulant to a second polymerization reactor which operates in series with a first polymerization reactor. The antifoulant may be a multicomponent antifoulant and/or a coating agent. Provision of either antifoulant enables the production of a heterophasic copolymer with an Fc value from about 10% to about 50% by inhibiting reactor fouling during polymerization.

Abstract: A process for producing a heterophasic copolymer is provided. The process includes introducing an antifoulant to a second polymerization reactor which operates in series with a first polymerization reactor. The antifoulant may be a multicomponent antifoulant and/or a coating agent. Provision of either antifoulant enables the production of a heterophasic copolymer with an Fc value from about 10% to about 50% by inhibiting reactor fouling during polymerization.