Abstract: A method for depositing a plasma polymer layer in an atmospheric-pressure plasma on a metallic substrate, wherein the plasma is obtained by a discharge between two electrodes. At least one organic coating precursor compound is fed into the region of the relaxing plasma and is deposited on the metallic substrate as a plasma polymer layer. Nitrogen or a forming gas is used as a treatment gas and the at least one organic coating precursor compound is selected from various compounds. Also disclosed is an article, an electrode and a capacitor which utilize the method and include a metallic substrate having a surface and a plasma polymer layer on the surface. Also disclosed is a method for producing the electrode or for producing the capacitor, a battery cell or a lithium-ion accumulator which comprises the electrode.