Abstract: A transparent, non elastomeric, high refractive index, impact resistant poly(thio)urethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic polysulfide prepolymer, and b) at least one aromatic primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function ranging from 0.5 to 2, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and wherein the (?, ?)-diiso(thio)cyanate polysulfide prepolymer is the reaction product of at least one cycloaliphatic or aromatic diiso(thio)cyanate and at least one (?, ?)-diol prepolymer.

Abstract: A method of in-mold coating utilizing an injection molding machine oriented to a horizontal parting line. At the beginning of the cycle the mold opens and a charge of liquid coating solution is deposited onto the lower mold insert. A ophthalmic wafer is deposited on the coating to spread it across the insert surface. The mold is closed and a pre-cure phase elapses before the thermoplastic resin is injected into the mold cavity above the wafer. The process provides coated and functionally enhanced lenses upon ejection from the molding machine.

Abstract: A transparent, non elastomeric, high refractive index, impact resistant poly(thio)urethane/urea material comprising the reaction product of: a) at least one (?, ?)-diiso(thio)cyanate cycloaliphatic or aromatic polysulfide prepolymer, and b) at least one aromatic primary diamine, in an equivalent molar ratio amine function/iso(thio)cyanate function ranging from 0.5 to 2, wherein, said prepolymer and diamine are free from disulfide (—S—S—) linkage and wherein the (?, ?)-diiso(thio)cyanate polysulfide prepolymer is the reaction product of at least one cycloaliphatic or aromatic diiso(thio)cyanate and at least one (?, ?)-diol prepolymer.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The method and equipment includes injection molding a single vision lens, for example, from polycarbonate. The clamp opens vertically and the top insert is exchanged for a bifocal mold having a base curve similar to the single vision lens. The thermoset coating includes compounds from several acrylate classes, and is applied to the single vision lens. The coating may include a photochromic dye. The coating is also formulated to receive a photochromic solution through an imbibition process.

Abstract: A method and coating used to prepare a photochromically-enabled bifocal ophthalmic lens. The method and equipment includes injection molding a single vision lens, for example, from polycarbonate. The clamp opens vertically and the top insert is exchanged for a bifocal mold having a base curve similar to the single vision lens. The thermoset coating includes compounds from several acrylate classes, and is applied to the single vision lens. The coating may include a photochromic dye. The coating is also formulated to receive a photochromic solution through an imbibition process.

Abstract: A method of in-mold coating utilizing an injection molding machine oriented to a horizontal parting line. At the beginning of the cycle the mold opens and a charge of liquid coating solution is deposited onto the lower mold insert. A ophthalmic wafer is deposited on the coating to spread it across the insert surface. The mold is closed and a pre-cure phase elapses before the thermoplastic resin is injected into the mold cavity above the wafer. The process provides coated and functionally enhanced lenses upon ejection from the molding machine.

Abstract: A process for making a stabilized, liquid, diepisulfide based prepolymer having a viscosity at 25 C. ranging from 20 to 330000 centipoises which comprises polymerizing at room temperature a monomer composition comprising at least one diepisulfide monomer in the presence of at least one anionic polymerization initiator and at least one halogenated polymerization inhibitor and compositions made therefrom.