Patents by Inventor Johann-Wilhelm Frey

Johann-Wilhelm Frey has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8937145
    Abstract: An epoxy resin composition prepared from a dihydroxydiphenyl-cycloalkane compound to form a diglycidyl ether of dihydroxydiphenyl cycloalkane compound which may be useful for making various products including, for example, powder coatings, composites and electrical laminates.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: January 20, 2015
    Assignee: Dow Global Technologies LLC
    Inventors: Robert E. Hefner, Jr., Michael J. Mullins, Guillaume Metral, Johann-Wilhelm Frey, Bernd Hoevel
  • Publication number: 20120238709
    Abstract: An epoxy resin composition prepared from a dihydroxydiphenyl-cycloalkane compound to form a diglycidyl ether of dihydroxydiphenyl cycloalkane compound which may be useful for making various products including, for example, powder coatings, composites and electrical laminates.
    Type: Application
    Filed: November 10, 2010
    Publication date: September 20, 2012
    Inventors: Guillaume Metral, Johann-Wilhelm Frey, Bernd Hoevel, Robert E. Hefner, JR., Michael J. Mullins
  • Patent number: 7989514
    Abstract: A strong-acid cation exchange resin comprising a plurality of acid groups which are partially neutralized with a cation of formula (I); wherein R1 at each occurrence independently is hydrogen or a Ci-4-alkyl group, R2 at each occurrence independently is hydrogen, alkyl or aryl, R3 at each occurrence independently is hydrogen or alkyl or two vicinal groups R3 together form an aromatic ring, m is 1, 2, 3, 4, 5 or 6, n is 1, 2, 3 or 4, o is 1 or 2, and p is 1, 2 or 3, is useful in the production of bisphenols.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: August 2, 2011
    Assignee: Dow Global Technologies LLC
    Inventor: Johann-Wilhelm Frey
  • Publication number: 20110152389
    Abstract: A strong-acid cation exchange resin comprising a plurality of acid groups which are partially neutralized with a cation of formula (I); wherein R1 at each occurrence independently is hydrogen or a Ci-4-alkyl group, R2 at each occurrence independently is hydrogen, alkyl or aryl, R3 at each occurrence independently is hydrogen or alkyl or two vicinal groups R3 together form an aromatic ring, m is 1, 2, 3, 4, 5 or 6, n is 1, 2, 3 or 4, o is 1 or 2, and p is 1, 2 or 3, is useful in the production of bisphenols.
    Type: Application
    Filed: July 18, 2007
    Publication date: June 23, 2011
    Inventor: Johann-Wilhelm Frey
  • Patent number: 7586012
    Abstract: A process for recovering a solid adduct of a bis(4-hydroxyaryl)alkane and a phenolic compound from a suspension comprising the addict is disclosed. The process comprises the steps of a) supplying the suspension to a rotary filter, b) filtering the supplied suspension in the rotary filter to retain adduct as an adduct cake, c) pre-drying the adduct cake with an inert gas, d) washing the pre-dried adduct cake, e) optionally drying the washed adduct cake, and f) discharging the washed adduct cake from the rotary filter.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: September 8, 2009
    Inventors: Emil Patrascu, Johann-Wilhelm Frey, Manfred Hagel
  • Publication number: 20060224025
    Abstract: A process for recovering a solid adduct of a bis(4-hydroxyaryl)alkane and a phenolic compound from a suspension comprising the addict is disclosed. The process comprises the steps of a) supplying the suspension to a rotary filter, b) filtering the supplied suspension in the rotary filter to retain adduct as an adduct cake, c) pre-drying the adduct cake with an inert gas, d) washing the pre-dried adduct cake, e) optionally drying the washed adduct cake, and f) discharging the washed adduct cake from the rotary filter.
    Type: Application
    Filed: January 16, 2004
    Publication date: October 5, 2006
    Applicant: DOW GLOBAL TECHNOLOGIES, INC.
    Inventors: Emil Patrascu, Johann-Wilhelm Frey, Manfred Hagel
  • Patent number: 7067704
    Abstract: Bisphenol-A is purified in a process which comprises the following steps: a) cooling a liquid mixture comprising bisphenol-A and water in a bisphenol-A crystallizer to form bisphenol-A crystals in a liquid phase; b) separating the bisphenol-A crystals from the liquid phase; c) dividing at least a portion of the liquid phase into a bisphenol-rich organic phase and a water-rich phase; d) feeding phenol and at least a portion of the bisphenol-rich organic phase into a adduct crystallizer to form a crystalline adduct of phenol and bisphenol-A in a mother liquor, and e) separating the crystalline adduct from the mother liquor. Bisphenol-A of high purity at a high yield is obtained.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: June 27, 2006
    Assignee: Dow Global Technologies Inc.
    Inventors: Thomas C. Young, Damian M. Feord, Johann-Wilhelm Frey
  • Publication number: 20060014986
    Abstract: Bisphenol-A is purified in a process which comprises the following steps: a) cooling a liquid mixture comprising bisphenol-A and water in a bisphenol-A crystallizer to form bisphenol-A crystals in a liquid phase; b) separating the bisphenol-A crystals from the liquid phase; c) dividing at least a portion of the liquid phase into a bisphenol-rich organic phase and a water-rich phase; d) feeding phenol and at least a portion of the bisphenol-rich organic phase into a adduct crystallizer to form a crystalline adduct of phenol and bisphenol-A in a mother liquor, and e) separating the crystalline adduct from the mother liquor. Bisphenol-A of high purity at a high yield is obtained.
    Type: Application
    Filed: November 12, 2003
    Publication date: January 19, 2006
    Inventors: Thomas Young, Damian Feord, Johann-Wilhelm Frey
  • Patent number: 6740684
    Abstract: A strong-acid cation exchange resin in acid form is contacted with an alkylcarhamoyl alkylthioester in the presence of water for producing a strong-acid cation exchange resin comprising a plurality of acid groups being partially neutralized with a mercaptoalkylamine. The produced partially neutralized cation exchange resin is useful as a catalyst in a process of producing a bisphienol by reaction of a phenolic compound with a carhonyl compound.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: May 25, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Mihail Paliuras, Damian M. Feord, Johann-Wilhelm Frey
  • Publication number: 20030212151
    Abstract: A strong-acid cation exchange resin in acid form is contacted with an alkylcarbamoyl alkylthioester in the presence of water for producing a strong-acid cation exchange resin comprising a plurality of acid groups being partially neutralized with a mercaptoalkylamine. The produced partially neutralized cation exchange resin is useful as a catalyst in a process of producing a bisphenol by reaction of a phenolic compound with a carbonyl compound.
    Type: Application
    Filed: February 21, 2003
    Publication date: November 13, 2003
    Inventors: Mihail Paliuras, Damian M. Feord, Johann-Wilhelm Frey
  • Patent number: 5723688
    Abstract: A process for preparing an adduct of a bisphenol with a phenolic compound comprising the following steps:a) reacting a carbonyl compound with a stoichiometric excess of a phenolic compound in the presence of an acidic cation exchange resin as a catalyst, to produce a product mixture containing a bisphenol, unreacted phenolic compound, unreacted carbonyl compound and water, andb) crystallizing an adduct of the bisphenol with the phenolic compound from the product mixture in a crystallization device in the presence of water and acetone.The product mixture obtained in step a) is not subjected to a distillation step before the product mixture enters the crystallization device and prior to the crystallization step b) the content of the carbonyl compound in the product mixture is controlled and, if necessary, carbonyl compound is added such that the total concentration of the carbonyl compound is from about 0.1 to about 8 percent, based on the total weight of the product mixture.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: March 3, 1998
    Assignee: The Dow Chemical Company
    Inventors: Emil Patrascu, Johann Wilhelm Frey, Hartwig Sendner
  • Patent number: 5288926
    Abstract: Bisphenols are prepared bya) reacting a phenolic compound with a carbonyl compound in a reaction mixture, containing the carbonyl compound, a stoichiometric excess of the phenolic compound and a catalyst, to produce a product mixture containing a bisphenol,b) separating bisphenol from the product mixture to leave a mother liquor andc) recycling at least a portion of the mother liquor to the reaction mixture.At least a portion of the phenolic compound is contacted with a strongly acidic cation exchange resin and a strongly basic anion exchange resin before the phenolic compound is used in the reaction step a) and/or at least a portion of the product mixture and/or at least a portion or the mother liquor is contacted with a strongly acidic cation exchange resin and a strongly basic anion exchange resin before mother liquor is recycled to the reaction mixture.
    Type: Grant
    Filed: February 4, 1993
    Date of Patent: February 22, 1994
    Assignee: The Dow Chemical Company
    Inventors: Emil Patrascu, Dieter Tank, Jochen Gressmann, Johann-Wilhelm Frey, Ulrich Wallbaum