Abstract: Described herein are polymer compositions comprising a matrix polymer component comprising a dynamic cross-linked polymer composition; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of making and using these polymer compositions are also described.

Abstract: Described herein are polymer compositions comprising a matrix polymer component comprising a dynamic cross-linked polymer composition; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of making and using these polymer compositions are also described.

Abstract: The disclosure is directed to polymer compositions comprising a matrix polymer component comprising a crystalline or semi-crystalline polymer; and a fibrillated fluoropolymer, a fibrillated fluoropolymer encapsulated by an encapsulating polymer, or a combination thereof. Methods of preparing and using these polymer compositions, as well as articles comprising the polymer compositions, as also described.

Abstract: Methods for preparing pre-dynamic cross-linked polymer compositions are described. Methods of preparing dynamic cross-linked polymer compositions using pre-dynamic cross-linked polymer compositions are also described.

Abstract: A multilayer thermoplastic film having polycarbonate layers is disclosed, in which a first layer comprises a first polycarbonate that comprises repeat units derived from one or more of a monoaryl monomer (II) and/or (III), and a diaryl monomer (IV) as defined herein. A second layer, adjacent to the first layer and coextruded therewith, comprises another polycarbonate that is not the same as a polycarbonate in the first layer. The first layer provides improved properties, for example hardness, impact, and/or scratch resistance.

Abstract: In one embodiment, a multilayer structure comprises: an initial terpolymer layer, a second layer comprising plastic and/or glass, a polycarbonate layer, and an adhesive layer. The initial terpolymer layer comprises a polycarbonate terpolymer derived from a first dihydroxy compound, a second dihydroxy compound, and a third dihydroxy compound, the first dihydroxy compound has Structure (A) wherein Rf is a hydrogen or CH3; the second dihydroxy compound has Structure (A) and is different from the first dihydroxy compound; and the third dihydroxy compound does not have Structure (A), and wherein a sum of mole percent of all of the first dihydroxy compound and the second dihydroxy compound is greater than or equal to 45% relative to a sum of mole percent of all of the first dihydroxy compound, the second dihydroxy compound, and the third dihydroxy compound in the polycarbonate terpolymer.

Abstract: A method of making a thermoplastic composition comprises melt blending a reaction mixture comprising a first polycarbonate comprising repeat units derived from monoaryl monomers (II) and (III) and a diaryl monomer (IV), wherein the sum of the mole percent of the repeat units derived from monomers (II) and (III) is greater than or equal to 30 mole percent, and the mole percent of the repeat units derived from monomer (IV) is 5 to 70 mole percent, each based on the total moles the repeat units derived from monomers (II), (III), and (IV), and the total weight of the repeat units derived from monomers (II), (III), and (IV) is greater than or equal to 90 wt. % of the first polycarbonate; and an additional polycarbonate, comprising 50 to 100 mole percent of repeat units derived from a bisphenol cyclohexane.

Abstract: Disclosed herein is a method of preparing a polycarbonate composition comprising melt blending a first polycarbonate prepared by interfacial polymerization and having hydroxy end groups that are capped with endcapping groups, with a second polycarbonate prepared by melt polymerization and having hydroxy end groups that are capped with endcapping groups, wherein the second polycarbonate has a lower mole percent of endcapping groups than that of the first polycarbonate; wherein an article having a thickness of 3.2 mm and molded from the polycarbonate composition has a haze of less than 3 according to ASTM D1003-00; and wherein a flat article molded from the polycarbonate composition has a surface charge of ?2 to +2 kV. A polycarbonate composition and complex article prepared according to the method are also disclosed.

Abstract: A method of making a thermoplastic composition comprises melt blending a reaction mixture comprising a first polycarbonate comprising repeat units derived from monoaryl monomers (II) and (III) and a diaryl monomer (IV), wherein the sum of the mole percent of the repeat units derived from monomers (II) and (III) is greater than or equal to 30 mole percent, and the mole percent of the repeat units derived from monomer (IV) is 5 to 70 mole percent, each based on the total moles the repeat units derived from monomers (II), (III), and (IV), and the total weight of the repeat units derived from monomers (II), (III), and (IV) is greater than or equal to 90 wt. % of the first polycarbonate; and an additional polycarbonate, comprising 50 to 100 mole percent of repeat units derived from a bisphenol cyclohexane.

Abstract: A multilayer thermoplastic film having polycarbonate layers is disclosed, in which a first layer comprises a first polycarbonate that comprises repeat units derived from one or more of a monoaryl monomer (II) and/or (III), and a diaryl monomer (IV) as defined herein. A second layer, adjacent to the first layer and coextruded therewith, comprises another polycarbonate that is not the same as a polycarbonate in the first layer. The first layer provides improved properties, for example hardness, impact, and/or scratch resistance.

Abstract: Disclosed herein is a method of preparing a polycarbonate composition comprising melt blending a first polycarbonate prepared by interfacial polymerization and having hydroxy end groups that are capped with endcapping groups, with a second polycarbonate prepared by melt polymerization and having hydroxy end groups that are capped with endcapping groups, wherein the second polycarbonate has a lower mole percent of endcapping groups than that of the first polycarbonate; wherein an article having a thickness of 3.2 mm and molded from the polycarbonate composition has a haze of less than 3 according to ASTM D1003-00; and wherein a flat article molded from the polycarbonate composition has a surface charge of ?2 to +2 kV. A polycarbonate composition and complex article prepared according to the method are also disclosed.

Abstract: In one embodiment, a multilayer structure comprises: an initial terpolymer layer, a second layer comprising plastic and/or glass, a polycarbonate layer, and an adhesive layer. The initial terpolymer layer comprises a polycarbonate terpolymer comprising structures derived from a dihydroxy compound having Structure (I) wherein Rf is a hydrogen or CH3; a second dihydroxy compound of Structure (A) which is derived from Structure (I) and is different from Structure (I); and a third dihydroxy compound of Structure (B) which is not derived from Structure (I), wherein a sum of mole percent of all of Structures (I) and Structure (A) is greater than or equal to 45% relative to a sum of mole percent of all of Structure (I), Structure (A), and Structure (B) in the polycarbonate terpolymer.

Abstract: In one embodiment, a multilayer structure comprises: an initial terpolymer layer, a second layer comprising plastic and/or glass, a polycarbonate layer, and an adhesive layer. The initial terpolymer layer comprises a polycarbonate terpolymer derived from a first dihydroxy compound, a second dihydroxy compound, and a third dihydroxy compound, the first dihydroxy compound has Structure (A) wherein Rf is a hydrogen or CH3; the second dihydroxy compound has Structure (A) and is different from the first dihydroxy compound; and the third dihydroxy compound does not have Structure (A), and wherein a sum of mole percent of all of the first dihydroxy compound and the second dihydroxy compound is greater than or equal to 45% relative to a sum of mole percent of all of the first dihydroxy compound, the second dihydroxy compound, and the third dihydroxy compound in the polycarbonate terpolymer.

Abstract: A method for making a polycarbonate article is described wherein the article is made by rotation molding a melt polycarbonate having a weight average molecular weight from 25,000 to about 36,000. The melt polycarbonate is produced by transesterifying a diaryl carbonate and a dihydroxy compound in the presence of a catalyst system to form an intermediate aromatic polycarbonate, wherein the catalyst system comprises a first catalyst selected from the group consisting of alkali metal salts and alkaline earth metal salts; and a second catalyst selected from the group consisting of quaternary ammonium compounds and quaternary phosphonium compounds; adding to said intermediate aromatic polycarbonate a catalyst quencher, and rotation molding the aromatic polycarbonate at a temperature from about 305° C. to about 360° C. Also disclosed are polycarbonate light diffusive articles produced by rotation molding.

Abstract: A method to reduce haze in the production of fire resistant polycarbonate compositions comprising flame retardant salts, wherein the salt is blended with a first polycarbonate to form a concentrate, and the concentrate is then added to a second polycarbonate resin.

Abstract: A transparent, flame retardant polycarbonate composition consisting essentially of an aromatic polycarbonate resin and a flame-retarding amount of a guanidine salt or derivatives thereof, wherein the amount of guanidine salt or derivatives thereof is about 1 wt. % or less.

Abstract: A water resistant permanent antistatic thermoplastic composition contains about 100 parts by weight of a thermoplastic polymer, such as polycarbonate or a blend thereof, about 0.1 to about 10 parts by weight of an antistatic agent, and about 0.1 to about 10 parts by weight of a polysiloxane-polyether copolymer.

Abstract: A method for producing a thermoplastic sheet includes extruding a composition including a melt polycarbonate resin having a Fries content of about 10 ppm to about 2000 ppm. The composition enables the sheet to be extruded with excellent uniformity.

Abstract: Disclosed herein is a light diffusing substrate in the form of film or sheet including multi-wall sheet and a process for making such light diffusing article, wherein the article comprises a light transmitting thermoplastic resin and about 0.001 to 10 wt. parts of a polyalkyl silsesquioxane, wherein the alkyl group is selected from a methyl, a C12-C18 alkyl, hydride, phenyl, vinyl, and cyclohexyl. The light diffusing substrate is characterized as having a surface roughness expressed as a centerline average height Ra of about or less than 0.1 &mgr;m, a ten-point surface roughness Rz of about or less than 1.0 &mgr;m, and a maximum height surface roughness Rmax of about or less than 1.0 &mgr;m.

Abstract: A method to reduce haze in the production of fire resistant polycarbonate compositions comprising flame retardant salts, wherein the salt is blended with a first polycarbonate to form a concentrate, and the concentrate is then added to a second polycarbonate resin.