Patents by Inventor John A. Ewen
John A. Ewen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7874081Abstract: A method of filling a drying system 24 with product comprises providing a washing unit 22, and a drier or driers 26a, 26b arranged such that one at a time the driers 26a, 26b receive product 48 discharged from the output of the washing unit 22. The washing unit 22 is configured to receive product 48 which is continuously weighed 104 as it is delivered to the washing unit. The product is washed in the washing unit 22 by being passed through the washing unit at a substantially constant speed, allowing the arrival time at the drier 26a, 26b to be predicted. The weight of product loaded into the drier is regulated by controlling the flow of product into the drier.Type: GrantFiled: October 20, 2006Date of Patent: January 25, 2011Assignee: Key Technology, Inc.Inventor: Philip John Ewen
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Patent number: 7851644Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.Type: GrantFiled: June 28, 2007Date of Patent: December 14, 2010Assignee: Basell Polyolefine GmbHInventors: John A. Ewen, Michael J. Elder, Robert L. Jones, Jr., Yuri A. Dubitsky
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Patent number: 7723450Abstract: The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm??(I) where Z1 is a coordinating group which comprises a six-?-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six ? electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.Type: GrantFiled: June 2, 2005Date of Patent: May 25, 2010Assignee: Basell Polyolefine GmbHInventors: Robert L. Jones, Michael J. Elder, Jennifer Kipke, Alexander Koeppl, Markus Schopf, John Ewen
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Publication number: 20090286945Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.Type: ApplicationFiled: June 28, 2007Publication date: November 19, 2009Inventors: John Ewen, Michael Elder, Robert Jones
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Patent number: 7544749Abstract: A catalyst system obtained by reacting at least one chiral transition metal compound and at least one cocatalyst, where the chiral transition metal compound is a transition metal compound of formula (Ia) or one of its enantiomers of the formula (Ia*), where M is an element of Group 4, Z are each halogen, hydrogen, C1-C10-alkyl, C6-C14-aryl, alkylaryl or arylalkyl having from 1 to 4 carbon atoms in the alkyl part and from 6 to 10 carbon atoms in the aryl part, n1 and n2 are each 0 or 1, R1 and R2 are each a C1-C40 radical, or R1 and R2 together with the atoms connecting them form a cyclic or polycyclic ring system, R5 and R6 are each hydrogen or a C1-C40 radical, R10, R11 are each hydrogen, t-butyl or phenyl, R12 are each t-butyl or phenyl, and R13 are each hydrogen or a C1-C40 radical.Type: GrantFiled: February 5, 2004Date of Patent: June 9, 2009Assignee: Basell Polyolefine GmbHInventors: Robert L. Jones, Naka Seidel, Michael J. Elder, John A. Ewen
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Patent number: 7504354Abstract: The present invention relates to organometallic transition metal compounds of the formula (I), a catalyst composition comprising at least one of the organometallic transition metal compound and an olefin polymerization process in the presence of one of the catalyst composition.Type: GrantFiled: November 2, 2004Date of Patent: March 17, 2009Assignee: Basell Polyolefine GmbHInventors: Michael J. Elder, Robert L. Jones, John A. Ewen
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Publication number: 20080090978Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.Type: ApplicationFiled: June 28, 2007Publication date: April 17, 2008Inventors: John Ewen, Michael Elder, Robert Jones
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Patent number: 7332456Abstract: The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R?(C5R?m)2MeQ. The catalysts include a bridge structure between the (C5R?m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R?m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled.Type: GrantFiled: March 21, 2005Date of Patent: February 19, 2008Assignee: Fina Technology, Inc.Inventor: John A. Ewen
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Publication number: 20070260023Abstract: The present invention relates to organometallic transition metal compounds of the formula (I) Z1AnZ2MXm??(I) where Z1 is a coordinating group which comprises a six-?-electron central group which coordinates directly to M, A is a divalent bridge between the groups Z1 and Z2, Z2 is a coordinating group having the same meaning as Z1 or is a group comprising an open pentadienyl, a cyclopentadienyl-containing group or a heterocyclic, 5- or 6-membered group containing six ? electrons, n=zero or 1, M is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements, the radicals X are identical or different and are each an organic or inorganic radical, m is 0, 1 or 2, and at least one of the three molecule fragments Z1, Z2 and A bears a monovalent organic radical.Type: ApplicationFiled: June 2, 2005Publication date: November 8, 2007Applicant: Basell Polyolefine GmbHInventors: Robert Jones, Michael Elder, Jennifer Kipke, Alexander Koeppl, Markus Schopf, John Ewen
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Publication number: 20070260025Abstract: The present invention relates to organometallic transition metal compounds of the formula (I) M1 is a metal of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanicles, X are identical or different and are each an organic or inorganic radical, where two radicals X can also be joined to one another, n is a natural number from 1 to 4, T1, T2 are identical or different and are each a divalent group selected from the group consisting of —O—, —S—, —Se—, —Te—, —N(R13)_?—P(R13)—, —As(R13)—, Sb(R13)—, —Si(R13)2-, —C(R13 R14)—C(R13 R15)— and —C(R14)?C(R15)—, where R13, R14 and R15 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R1, R7 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R2 R8 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R3 R9 are identical or different and are each halogen or an organic radical having from 1 to 40 cType: ApplicationFiled: November 2, 2004Publication date: November 8, 2007Applicant: Basell Polyolefine GmbHInventors: Michael Elder, Robert Jones, John Ewen
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Patent number: 7238818Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using said catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1–3; jj is 0–2; k is 1–3; and l is 0–2.Type: GrantFiled: March 24, 2003Date of Patent: July 3, 2007Assignee: Basell Polyolefine GmbHInventors: John A. Ewen, Michael J. Elder, Robert L. Jones, Jr., Yuri A. Dubitsky
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Publication number: 20060100092Abstract: The present invention relates to catalyst systems for preparing isotactic polyolefins obtainable by reacting at least one chiral transition metal compound and at least one cocatalyst which is able to convert the chiral transition metal compound into a cation, where the chiral transition metal compound contains two bidentate chelating ligands connected to one another via a bridge and, if desired, one or two further monodentate ligands, with the four coordinating atoms of the two chelating ligands being in an approximately planar arrangement around the transition metal ion and up to two further ligands being located above and below this approximately planar coordination sphere formed by the four coordinating atoms of the two chelating ligands and, in the case of two such further ligands, these being in the trans position relative to one another, to the use of the catalyst systems of the present invention for preparing polyolefins, to a process for preparing polyolefins by polymerization or copolymerization of aType: ApplicationFiled: February 5, 2004Publication date: May 11, 2006Applicant: Basell Polyolefine GmbHInventors: Robert Jones, Naka Seidel, Michael Elder, John Ewen
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Publication number: 20050192418Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using said catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinatng Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i os 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.Type: ApplicationFiled: March 24, 2003Publication date: September 1, 2005Inventors: John Ewen, Michael Elder, Robert Jones, Yuri Bubitsky
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Publication number: 20050165184Abstract: The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R?(C5R?m)2MeQ. The catalysts include a bridge structure between the (C5R?m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R?m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled.Type: ApplicationFiled: March 21, 2005Publication date: July 28, 2005Inventor: John Ewen
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Patent number: 6872790Abstract: The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R?(C5R?m)2MeQ. The catalysts include a bridge structure between the (C5R?m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R?m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled.Type: GrantFiled: November 7, 2001Date of Patent: March 29, 2005Assignee: Fina Technology, Inc.Inventor: John A. Ewen
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Patent number: 6649712Abstract: The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R″(C5R″m)2MeQ. The catalysts include a bridge structure between the (C5R′m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R′m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled.Type: GrantFiled: November 7, 2001Date of Patent: November 18, 2003Assignee: Fina Technology, Inc.Inventor: John A. Ewen
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Patent number: 6635779Abstract: A class of metallocene compounds is disclosed having general formula (I) wherein Y is a moiety of formula (II) wherein A, B, and D, same or different from each other, are selected from an element of the groups 14 to 16 of the Periodic Table of the Elements (new IUPAC version), with the exclusion of nitrogen and oxygen; R1, R2, R3, R4 and R5 are hydrogen or hydrocarbon groups, Z is selected from a moiety of formula (II) as described above and from a moiety of formula (III) wherein R6, R7, R8 and R9, are hydrogen or hydrocarbon groups; L is a divalent bridging group; M is an atom of a transition metal selected from those belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups in the Periodic Table of the Elements (new IUPAC version), X, same or different, is hydrogen, a halogen, a R10, OR10, OSO2CF3, OCOR10, SR10, NR102 or PR102 group, wherein the substituents R10 are hydrogen or alkyl groups; p is an integer of from 1 to 3, being equal to the oxidation state of the metal M minus 2.Type: GrantFiled: November 20, 2001Date of Patent: October 21, 2003Assignee: Basell Technology Company bvInventors: John A. Ewen, Michael J. Elder, Robert L. Jones
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Patent number: 6600441Abstract: A radar detector for exploration of subsurface embedded objects comprising an antenna array (1) for high-frequency electromagnetic waves, which is connected and individually switchable with at least one transmit/receive unit, a time-controlled signal processor, an evaluation device for SAR and a display device. The antenna array (1) exhibiting at least three antennas (sx, rx, sy, ry) scanning an area by their positioning.Type: GrantFiled: October 9, 2001Date of Patent: July 29, 2003Assignee: Hilti AktiengesellschaftInventors: Stefan Liedtke, Harald Schmitzer, John Ewen, Klaus Dass
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Publication number: 20020193537Abstract: The present invention provides a method for varying the melting points and molecular weights of polyolefins by changing the structure of the catalyst used in the polymerization. The catalysts that are useful in the present invention are chiral, stereorigid metallocene catalyst of the formula R″(C5R″m)2MeQ. The catalysts include a bridge structure between the (C5R′m) groups and may contain substituents on the groups. It has been discovered that the melting points and molecular weights of the polymers produced by such catalysts are influenced by the bridge and substituents added to the (C5R′m) groups. Thus, the present invention provides a method for varying the melting points of the polymer product and a method of varying the molecular weights of the product by changing the components and structure of the metallocene catalysts. The present invention also provides a process for polymerizing olefins in which the melting points and/or molecular weights of the product may be controlled.Type: ApplicationFiled: November 7, 2001Publication date: December 19, 2002Inventor: John A. Ewen
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Patent number: 6444833Abstract: A class of metallocene compounds is disclosed having the general formula (I): wherein Y is a moiety of formula (II) wherein A, B and D, same or different from each other, are selected from an element of the groups 14 to 16 of the Periodic Table of the Elements (new IUPAC version), with the exclusion of nitrogen and oxygen; R1, R2, R3, R4 and R5 are hydrogen or hydrocarbon groups, Z is selected from a moiety of formula (II) as described above and from a moiety of formula (III): wherein R6, R7, R8 and R9, are hydrogen or hydrocarbon groups; L is a divalent bridging group; M is an atom of a transition metal selected from those belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups in the Periodic Table of the Elements (new IUPAC version), X, same or different, is hydrogen, a halogen, a R10, OR10, OSO2CF3, OCOR10, SR10, NR102 or PR102 group, wherein the substituents R10 are hydrogen or alkyl groups; p is an integer of from 0 to 3, being equal toType: GrantFiled: December 15, 1999Date of Patent: September 3, 2002Assignee: Basell Technology Company BVInventors: John A. Ewen, Michael J. Elder, Robert L. Jones