Abstract: Compositions for reduction of NOx emissions generated during catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise (i) an acidic metal oxide containing substantially no zeolite, (ii) an alkali metal, alkaline earth metal, and mixtures thereof, (iii) an oxygen storage component, (iv) palladium and (v) a noble metal component, preferably platinum, rhodium or iridium, and mixtures thereof. Preferably, the compositions are used as separate additives particles circulated along with the circulating FCC catalyst inventory. Reduced content of NOx in an effluent off gas of a full or complete combustion FCC regenerator are accomplished while simultaneously promoting the combustion of CO.

Abstract: Compositions for reduction of NOx emissions generated during catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise (i) an acidic metal oxide containing substantially no zeolite, (ii) an alkali metal, alkaline earth metal, and mixtures thereof, (iii) an oxygen storage component, (iv) palladium and (v) a noble metal component, preferably platinum, rhodium or iridium, and mixtures thereof. Preferably, the compositions are used as separate additives particles circulated along with the circulating FCC catalyst inventory. Reduced content of NOx in an effluent off gas of a full or complete combustion FCC regenerator are accomplished while simultaneously promoting the combustion of CO.

Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen and to oxidize CO under catalytic cracking conditions. The oxidative catalyst/additive composition is used in an amount less than the amount necessary to prevent afterburn. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.

Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOxCO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Compositions for reduction of gas phase reduced nitrogen species and NOx generated during a partial or incomplete combustion catalytic cracking process, preferably, a fluid catalytic cracking process, are disclosed. The compositions comprise (i) an acidic metal oxide containing substantially no zeolite, (ii) an alkali metal, alkaline earth metal, and mixtures thereof, (iii) an oxygen storage component, and (iv) a noble metal component, preferably rhodium or iridium, and mixtures thereof, are disclosed. Preferably, the compositions are used as separate additives particles circulated along with the circulating FCC catalyst inventory. Reduced emissions of gas phase reduced nitrogen species and NOx in an effluent off gas of a partial or incomplete combustion FCC regenerator provide for an overall NOx reduction as the effluent gas stream is passed from the FCC regenerator to a CO boiler, whereby as CO is oxidized to CO2 a lesser amount of the reduced nitrogen species is oxidized to NOx.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NO.sub.x control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NO.sub.x control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.

Abstract: Catalytic cracking catalysts and catalyst additives which contain silica modified bayerite and/or eta alumina.

Abstract: A silica-containing bayerite alumina is prepared by reacting aluminum sulfate, sodium aluminate and sodium silicate at a pH of about 10.5 to 11.5, preferably in the presence of finely divided magnesium hydroxide "seeds". The silica-containing bayerite is heated to obtain a hydrothermally stable silica "stabilized" eta alumina which may be used in the preparation of catalytic compositions.

Abstract: Superior homogeneity in ceramic materials is achieved by reacting certain soluble metal salts with quaternary ammonium carbonates to form co-precipitated metal carbonates. The precipitate can be recovered and processed to make superconductors. For example, a solution of nitrates of yttrium, barium, and copper are treated with a solution of tetraethyl ammonium carbonate to form co-precipitated carbonates of Y, Ba, Cu. The precipitate is recovered and calcined to form a superconducting material.

Abstract: Catalytic cracking catalysts and catalyst additives which contain silica modified bayerite and/or eta alumina.

Abstract: An extremely pure oxide containing two or more metals, homogeneous at the atomic level, is prepared by (1) reacting in water, soluble salts of two or more metals with quaternary ammonium carbonate; the metals being those that form water-insoluble carbonates, thereby to precipitate mixed carbonates of the metals; (2) recovering and drying the precipitate; (3) calcining the precipitate to provide an oxide of mixed metals homogeneous at the atomic level and substantially free from extraneous contaminants. The calcined oxide can be shaped and compressed as greenware and sintered to form useful ceramic products.

Abstract: Catalysts and catalyst supports are prepared by forming and drying, preferably spray-drying, an aqueous slurry of inorganic solids such as zeolites, clay, silica, alumina, and silica-alumina gel, and aluminum chlorhydrol to obtain particulate composites. The particulate composites are then reacted with ammonia in the absence of free liquid water to convert the aluminum chlorhydrol into a cohesive binder. The ammonia-reacted composites may then be washed, ion exchanged and thermally activated to obtain active attrition resistant catalysts and catalyst components.

Abstract: Catalytic compositions comprising up to about 50 weight percent ZSM-5 zeolite dispersed in an attrition resistant, porous inorganic oxide matrix selected from silica-alumina cogels, silica, alumina and silica alumina sol bound clay. The compositions are combined with zeolitic containing catalytic cracking catalysts and used to convert residual and/or gas oil hydrocarbon feedstocks into lower molecular weight products that include high octane gasoline fractions.