Patents by Inventor John A. Schield

John A. Schield has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7284610
    Abstract: A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with a polyamine salt of an imide of polymaleic anhydride. The salt may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions of this invention are more environmentally friendly than some current technology.
    Type: Grant
    Filed: December 13, 2004
    Date of Patent: October 23, 2007
    Assignee: Baker Hughes Incorporated
    Inventors: David J. Poelker, Joann McMahon, John A. Schield
  • Publication number: 20070142244
    Abstract: Disclosed is composition useful for reducing the concentration of mercaptans in hydrocarbons comprising: (A) a first diazo component and (B) a second component comprising a nucleophilic acceptor. The composition can be added to hydrocarbons such as fuel oil to reduce mercaptans without increasing turbidity or color. Triethylene diamine and 1,2-epoxyhexadecane are disclosed to be exemplary diazo and nucleophilic acceptor components.
    Type: Application
    Filed: February 11, 2004
    Publication date: June 21, 2007
    Inventor: John Schield
  • Publication number: 20060254772
    Abstract: A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with relatively high molecular weight acid ammonium salts of an imide of polymaleic anhydride. The salts may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions herein are made in the presence of a reactive solvent, such as a polyalkylene glycol, e.g. polyethylene glycol. The compositions of this invention are more environmentally friendly than some current technology.
    Type: Application
    Filed: July 18, 2006
    Publication date: November 16, 2006
    Inventors: David Poelker, Joann McMahon, John Schield
  • Publication number: 20050126782
    Abstract: A clayish subterranean formation, such as may be encountered in rock surrounding a well bore during hydrocarbon recovery operations may be stabilized with acid ammonium salt of an imide of polymaleic anhydride. The salt may be unneutralized or partially neutralized. The invention is particularly relevant to hydraulic fracturing fluids used in enhanced oil recovery. The compositions of this invention are more environmentally friendly than some current technology.
    Type: Application
    Filed: December 13, 2004
    Publication date: June 16, 2005
    Inventors: David Poelker, Joann McMahon, John Schield
  • Patent number: 6887447
    Abstract: The present invention provides a method for inhibiting the evolution of H2S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: May 3, 2005
    Assignee: Baker Hughes Incorporated
    Inventors: John A. Schield, Weldon J. Cappel, Jerry J. Weers, Glenn L. Roof
  • Publication number: 20040086443
    Abstract: The present invention provides a method for inhibiting the evolution of H2S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.
    Type: Application
    Filed: October 17, 2003
    Publication date: May 6, 2004
    Inventors: John A. Schield, Weldon J. Cappel, Jerry J. Weers, Glenn L. Roof
  • Patent number: 6656445
    Abstract: The present invention provides a method for inhibiting the evolution of H2S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: December 2, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: John A. Schield, Weldon J. Cappel, Jerry J. Weers, Glenn L. Roof
  • Publication number: 20020068034
    Abstract: The present invention provides a method for inhibiting the evolution of H2S from sulfhydryl compounds in molten sulfur by using scavenging agents such as anhydrides and polymers thereof, conjugated ketones, carbonates, epoxides, monoesters and diesters of unsaturated dicarboxylic acids and polymers of these esters, and the like and mixtures thereof. In one embodiment, it is preferred that the scavenging agent is in liquid form at contact temperature with the molten sulfur. In another embodiment, the scavenging agent may be atomized into the vapor space over the molten sulfur to contact the sulfur with the agent.
    Type: Application
    Filed: October 9, 2001
    Publication date: June 6, 2002
    Inventors: John A. Schield, Weldon J. Cappel, Jerry J. Weers, Glenn L. Roof
  • Patent number: 6391070
    Abstract: It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: May 21, 2002
    Assignee: Baker Hughes Incorporated
    Inventor: John A. Schield
  • Publication number: 20010048099
    Abstract: It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.
    Type: Application
    Filed: April 16, 2001
    Publication date: December 6, 2001
    Inventor: John A. Schield
  • Patent number: 5857287
    Abstract: Adding to a fuel oil a composition of from about 1 to about 40 parts by weight ethylene/vinyl acetate copolymer having a vinyl acetate content of from about 10% by weight to about 50% by weight and a weight average molecular weight of from about 2,000 to about 10,000, and 1 part by weight esterified copolymer of at least one generally linear .alpha.-olefin of from about 18 to about 50 carbon atoms and maleic anhydride in an .alpha.-olefin to maleic anhydride molar ratio of from about 4:1 to about 1:2, the copolymer having a weight average molecular weight of from about 2,000 to about 20,000, the esterified copolymer having been esterified with a plurality of aliphatic alcohols having from about four to about forty carbon atoms, imparts to the fuel oil surprisingly improved low temperature fluidity, provided that the alcohols include an eight carbon alcohol making up from about 50 to about 85 molar percent of the alcohols.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: January 12, 1999
    Assignee: Baker Hughes Incorporated
    Inventors: John A. Schield, Jerry J. Weers
  • Patent number: 5772706
    Abstract: Adding to a fuel oil a composition of from about 1 to about 40 parts by weight ethylene/vinyl acetate copolymer having a vinyl acetate content of from about 10% by weight to about 50% by weight and a weight average molecular weight of from about 2,000 to about 10,000, and 1 part by weight esterified copolymer of at least one generally linear .alpha.-olefin of from about 18 to about 50 carbon atoms and maleic anhydride in an .alpha.-olefin to maleic anhydride molar ratio of from about 4:1 to about 1:2, the copolymer having a weight average molecular weight of from about 2,000 to about 20,000, the esterified copolymer having been esterified with a plurality of aliphatic alcohols having from about four to about forty carbon atoms, imparts to the fuel oil surprisingly improved low temperature fluidity, provided that the alcohols include an eight carbon alcohol making up from about 50 to about 85 molar percent of the alcohols.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: June 30, 1998
    Assignee: Baker Hughes Incorporated
    Inventors: John A. Schield, Jerry J. Weers
  • Patent number: 5672183
    Abstract: A composition having increased electrical conductivity, comprising a liquid hydrocarbon and an anti-static amount of a hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer. The copolymer has an alkylvinyl monomer unit to cationic vinyl monomer unit ratio of from about 1:1 to about 10:1, and has an average molecular weight of from about 800 to about 1,000,000. Other related compositions and methods for measuring electrical conductivity of liquids are also disclosed.
    Type: Grant
    Filed: July 1, 1996
    Date of Patent: September 30, 1997
    Assignee: Petrolite Corporation
    Inventor: John A. Schield
  • Patent number: 5160642
    Abstract: A clayish formation, such as encountered in rock surrounding an oil well bore, is stabilized with a quaternary ammonium salt of an imide of polymaleic anhydride. The invention is particularly relevant to hydraulic fracturing fluids used for enhanced oil recovery.
    Type: Grant
    Filed: May 25, 1990
    Date of Patent: November 3, 1992
    Assignee: Petrolite Corporation
    Inventors: John A. Schield, Michael I. Naiman, Gary A. Scherubel
  • Patent number: 4757862
    Abstract: Water-soluble copolymers which are essentially free of cross-linking are useful as shale stabilizers. These copolymers are random copolymers of a vinyl carboxamide monomer and a hydroxy-containing vinyl carboxylic ester. These shale stabilizers are added to a drilling fluid which is then circulated through a well bore whereby the shale stabilizers come in contact with the shale formation and inhibit hydration of shale to prevent sloughing thereof.
    Type: Grant
    Filed: August 21, 1986
    Date of Patent: July 19, 1988
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield
  • Patent number: 4708993
    Abstract: Oligomers of polymerizable ester-containing halopolyalkylenes are effective as cold flow improvers in middle distillate fuels.
    Type: Grant
    Filed: August 6, 1986
    Date of Patent: November 24, 1987
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield, Lawrence J. Cunningham
  • Patent number: 4617025
    Abstract: This invention relates to polyalkylenes which contain both halogen and ester groups, to the preparation thereof, and to the use thereof as pour depressants for fuel oils. This invention also relates to polyalkylene esters.
    Type: Grant
    Filed: April 22, 1985
    Date of Patent: October 14, 1986
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield
  • Patent number: 4568359
    Abstract: This invention relates to polyalkylenes which contain both halogen and ester groups, to the preparation thereof, and to the use thereof as pour depressants for fuel oils. This invention also relates to polyalkylene esters.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: February 4, 1986
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield
  • Patent number: 4568726
    Abstract: This invention relates to polyalkylenes which contain both halogen and ester groups, to the preparation thereof, and to the use thereof as pour depressants for fuel oils. This invention also relates to polyalkylene esters.
    Type: Grant
    Filed: March 18, 1985
    Date of Patent: February 4, 1986
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield
  • Patent number: 4553980
    Abstract: This invention relates to polyalkylenes which contain both halogen and ester groups, to the preparation thereof, and to the use thereof as pour depressants for fuel oils. This invention also relates to polyalkylene esters.
    Type: Grant
    Filed: April 22, 1985
    Date of Patent: November 19, 1985
    Assignee: Petrolite Corporation
    Inventors: Michael I. Naiman, John A. Schield