Abstract: There is disclosed herein metal nitrate hydrates as phase change materials (PCMs). More particularly, there is disclosed herein metal nitrate hydrate PCMs containing group II metal nitrates as nucleation agents. A further disclosure herein is the combination of multiple chemical species in the PCM formulation which act together to induce nucleation of metal nitrate PCMs. Furthermore, physical mechanisms by which nucleation of metal nitrate hydrate based PCMs and crystallisation rate increased are disclosed.

Abstract: The present invention describes a vapour compression apparatus wherein an intermediary located heat battery is capable of releasing charge (i.e. discharging) and/or charging and thereby controlling the temperature of a heat source or heat sink temperature in a vapour compression cycle. More particularly, the present invention describes vapour compression apparatus wherein an intermediary located heat battery comprising Phase change material (PCM) is capable of releasing charge (i.e. discharging) energy and/or charging and thereby controlling the temperature of a heat source and/or heat sink temperature in a vapour compression cycle in a range of refrigeration and/or heating systems including: air conditioning in both domestic and industrial uses; transportation of food/materials in vehicles, trains, air, etc. The present invention also relates to a methodology for selecting phase change materials (PCMs) and/or refrigerants for a vapour compression apparatus.

Abstract: The present disclosure provides methods to produce 5-(halomethyl)furfural, including 5-(chloromethyl)furfural, by acid-catalyzed conversion of C6 saccharides, including isomers thereof, polymers thereof, and certain derivatives thereof. The methods make use of acids with lower concentrations, and allows for conversion of sugars into 5-(halomethyl)furfural at higher temperatures and faster reaction or residence times.

Abstract: There are herein described energy storage systems. More particularly there are provided thermal energy storage systems comprising battery assemblies containing phase change materials and a monitoring system therefor. In addition there are provided thermal stores comprising battery assemblies having integral control means for management of the thermal energy provided by the battery assembly.

Abstract: The present invention relates to phase-change materials (PCM) which store and release thermal energy by undergoing melt/crystallisation cycles. More particularly, there is described a thermal storage system where sub-cooled phase change material (PCM) is nucleated via a controlled thermal region(s).

Abstract: There is herein described phase change materials (PCMs) comprising at least one or a plurality (e.g. a mixture) of tetrafluoroborate salts that are capable of undergoing a solid to solid phase transition. In particular, there is described phase change materials (PCMs) comprising at least one or a plurality (e.g. a mixture) of tetrafluoroborate salts where there is at least one tetrafluoroborate salt or a plurality of tetrafluoroborate salt which have a solid to solid phase transition. The tetrafluoroborate salt may comprise at least one anion or a plurality of the same or different anions of tetrafluoroborate (e.g. BF4—). The PCM may have a solid to solid phase change in the region of about ?270° C. to about 3,000° C., about ?50° C. to about 1,500° C., about 0° C. to about 1,000° C., or about 0° C. to about 500° C. temperature range.

Abstract: The present disclosure provides methods to produce 5-(halomethyl)furfural, including 5-(chloromethyl)furfural, by acid-catalyzed conversion of C6 saccharides, including isomers thereof, polymers thereof, and certain derivatives thereof. The methods make use of acids with lower concentrations, and allows for conversion of sugars into 5-(halomethyl)furfural at higher temperatures and faster reaction or residence times.

Abstract: There is disclosed herein metal nitrate hydrates as phase change materials (PCMs). More particularly, there is disclosed herein metal nitrate hydrate PCMs containing group II metal nitrates as nucleation agents. A further disclosure herein is the combination of multiple chemical species in the PCM formulation which act together to induce nucleation of metal nitrate PCMs. Furthermore, physical mechanisms by which nucleation of metal nitrate hydrate based PCMs and crystallisation rate increased are disclosed.

Abstract: There is provided a thermal energy storage system suitable for use with systems adapted to transfer heat from at least one heat source to at least one heat sink (heat transfer system), comprising at least one thermal energy storage unit. There is additionally provided a thermal energy storage system for use with a heat pump, or vapour compression refrigeration systems, a method of defrosting evaporators without affecting the energy delivered in the condenser before the defrosting cycle, and system architecture for defrosting evaporators in heat pumps or in vapour compression refrigeration systems.

Abstract: The present invention provides an energy storage system (10) for a use with a boiler (20). The energy storage system (10) comprises a plurality of thermal energy storage banks (101, 102, 103, 104). Each thermal energy storage bank (101, 102, 103, 104) comprises phase changeable material having a predetermined phase transformation temperature. The energy storage system (10) also includes an extraction device (105; 1 15) configured to recover waste energy from the boiler (20). The extraction device (105, 1 15) is operable to extract waste energy from the boiler (20) and feed that energy to at least one (101) of the thermal energy storage banks (101, 102, 103, 104). A controller (106) is arranged, in use, to activate the extraction device (105, 115) in response to operation of the boiler (20).

Abstract: The present disclosure provides methods to produce 5-(halomethyl)furfural, including 5-(chloromethyl)furfural, by acid-catalyzed conversion of C6 saccharides, including isomers thereof, polymers thereof, and certain derivatives thereof. The methods make use of acids with lower concentrations, and allows for conversion of sugars into 5-(halomethyl)furfural at higher temperatures and faster reaction or residence times.

Abstract: The present invention describes a vapour compression apparatus wherein an intermediary located heat battery is capable of releasing charge (i.e. discharging) and/or charging and thereby controlling the temperature of a heat source or heat sink temperature in a vapour compression cycle. More particularly, the present invention describes vapour compression apparatus wherein an intermediary located heat battery comprising Phase change material (PCM) is capable of releasing charge (i.e. discharging) energy and/or charging and thereby controlling the temperature of a heat source and/or heat sink temperature in a vapour compression cycle in a range of refrigeration and/or heating systems including: air conditioning in both domestic and industrial uses; transportation of food/materials in vehicles, trains, air, etc. The present invention also relates to a methodology for selecting phase change materials (PCMs) and/or refrigerants for a vapour compression apparatus.

Abstract: There are herein described phase change materials containing sodium acetate trihydrate having improved homogeneity, a process for the preparation of said materials, and their utility in phase change systems. More particularly, the present invention relates to the use of phase change compositions comprising sodium acetate trihydrate, at least one alkali soluble polymer for inhibition of sodium acetate anhydrous crystal formation in sodium acetatetrihydrate containing phase change materials, and at least one sodium acetate trihydrate nucleation promoter, and, if a lower phase change temperature is required, at least one melting point depressing agent.

Abstract: The present disclosure provides methods to produce 5-(halomethyl)furfural, including 5-(chloromethyl)furfural, by acid-catalyzed conversion of C6 saccharides, including isomers thereof, polymers thereof, and certain derivatives thereof. The methods make use of acids with lower concentrations, and allows for conversion of sugars into 5-(halomethyl)furfural at higher temperatures and faster reaction or residence times.

Abstract: The present invention relates to phase-change materials (PCM) which store and release thermal energy by undergoing melt/crystallisation cycles. More particularly, there is described a thermal storage system where sub-cooled phase change material (PCM) is nucleated via a controlled thermal region(s).

Abstract: Provided herein are methods of producing dialkylfurans, such as 2,5-dimethylfuran, and other alkyl furans, such as 2-methylfuran. For example, 2,5-dimethylfuran may be produced by reducing (5-methylfuran-2-yl)methanol or 2-(chloromethyl)-5-methylfuran.

Abstract: The present disclosure provides methods for purifying a 5-(halomethyl)furfural composition, including 5-(chloromethyl)furfural, at operating conditions that decrease or minimize the decomposition or degradation of 5-(chloromethyl)furfural during the process. The methods may employ certain solvents, operating conditions, and/or techniques (e.g., gas stripping). The gaseous 5-(halomethyl)furfural produced from the process can be condensed or deposited to yield 5-(halomethyl)furfural in liquid or solid form. The solid 5-(halomethyl)furfural may be amorphous or crystalline.

Abstract: There are herein described energy storage systems. More particularly there are provided thermal energy storage systems comprising battery assemblies containing phase change materials and a monitoring system therefor. In addition there are provided thermal stores comprising battery assemblies having integral control means for management of the thermal energy provided by the battery assembly.

Abstract: The present disclosure provides methods to produce substituted furans (e.g., halomethylfurfural, hydroxymethylfurfural, and furfural), by acid-catalyzed conversion of biomass using a gaseous acid in a multiphase reactor, such as a fluidized bed reactor.

Abstract: The present disclosure provides methods to produce para-xylene, toluene, and other compounds from renewable sources (e.g., cellulose, hemicellulose, starch, sugar) and ethylene in the presence of a catalyst. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF), which may be converted into para-xylene by cycloaddition of ethylene to DMF. Para-xylene can then be oxidized to form terephthalic acid.