Abstract: This invention provides perfluoro(alkoxycycloalkane) carbonyl fluoride compounds wherein, pendant from the fluorinated ring, are from 2 to 5 perfluoroalkoxy groups having from 1 to 4, preferably 1 to 2, carbon atoms with the proviso that when one or more of the perfluoroalkoxy groups contain from 3 to 4 carbon atoms, there are no more than 3 pendant groups.In yet another aspect, this invention provides aqueous film-forming foam (AFFF) compositions comprising one or more perfluoro(alkoxycycloalkane) carbonyl group-containing surfactants and one or more water-soluble fluorine-free surfactants selected from the group consisting of nonionic hydrocarbon-containing surfactants with a hydrophilic-lipophilic balance (HLB) value greater than or equal to about 10 and ionic hydrocarbon-containing surfactants having a carbon chain length containing inclusively from about 6 to about 10 carbon atoms.

Abstract: To capacity control a refrigeration system including a compressor, a condenser, and an evaporator all connected in a closed refrigeration circuit, the compressor having a plurality of adjustable inlet guide vanes and driven by an internal combustion engine, signals indicating the condenser pressure; the evaporator pressure; the inlet guide vanes position; the engine speed; the chilled water discharge temperature; and the engine intake manifold pressure are processed by a microprocessor to continuously calculate a surface speed and to equalize engine speed and calculated surface speed utilizing a fuzzy logic algorithm.

Abstract: Perfluoroisobutene-MeOH adduct (2H-octafluororisobutyl methyl ether) is converted to hexafluoropropane by reaction with trialkyl amine (eg. triethyl amine) and H.sub.2 O. 1,1,1,3,3-Pentafluoropropene is also produced in lesser amounts. The electrolysis of the reaction product in anhydrous HF (at 10.degree.-50.degree. C., 0-140 kPa, and 50-300 amps/m.sup.2 anode area) yields C.sub.3 F.sub.8 and some CF.sub.3 CFHCF.sub.3 which is condensed out of a gas stream from the electrolysis cell.

Abstract: A process for preparing perfluoroalkanesulfonyl fluorides, e.g., perfluoromethanesulfonyl fluoride, is described which comprises electrochemically fluorinating in the presence of anhydrous hydrogen fluoride mono-, di- or tri- alkylsulfonyl alkyl esters or amides, or mono-, bis- or tris- alkylsulfonyl alkanes or disulfones. The process can be used to prepare perfluoroalkanesulfonyl fluorides in good yield and can be both more electrically-efficient and more fluorine-efficient than the conventional preparative method involving the electrochemical fluorination of hydrocarbon alkanesulfonyl halides.

Abstract: A method for the preparation of fluoroalkyl fluoroisobutyl ethers is disclosed. Such ethers are prepared by fluorinating, in an electrochemical cell, a solution comprising an adduct of perfluoro-isobutene and an aliphatic alcohol.

Abstract: A process for preparing inert or functional, tertiary carbon-containing perfluorochemicals comprises the step of electrochemically fluorinating, in the presence of anhydrous hydrogen fluoride, a composition comprising at least one starting compound selected from the group consisting of those fluoroalkanes, fluoroalkenes, fluoroalcohols, fluorocarboxylic acids, fluorocarboxylic acid halides, fluorocarboxylic acid esters, and combinations thereof which contain at least one (preferably, only one) --CX.sub.2 --C(R.sub.f).sub.2 -- group, wherein each X is independently selected from the group consisting of hydrogen, fluorine, and CH.sub.2 OH, with the proviso that only one X can be CH.sub.2 OH, and each R.sub.f group is independently perfluoroalkyl. The process enables preservation of the highly-branched structure of the starting compounds resulting in high product yields.

Abstract: A process for preparing perfluoroalkanesulfonyl fluorides, e.g., perfluoromethanesulfonyl fluoride, comprises electrochemically fluorinating in the presence of anhydrous hydrogen fluoride at least one precursor compound selected from the group consisting of .alpha.,.beta.-difluoroalkane-.beta.-sultones, e.g., 1,1,2,2-tetrafluoroethane sultone, and the corresponding .alpha.-halocarbonylfluoroalkanesulfonyl halides, e.g., fluorocarbonyldifluoromethanesulfonyl fluoride. The process can be used to prepare perfluoroalkanesulfonyl fluorides in good yield and can be, for example, both more electrically-efficient and more fluorine-efficient than the conventional preparative method involving the electrochemical fluorination of hydrocarbon alkanesulfonyl halides.

Abstract: A continuous process for preparing in a Simons electrochemical cell charged with anhydrous liquid HF and a S- and H-containing organic precursor fluorochemical compounds having the formula F.sub.5 S--R.sub.f --X where X is COF or SO.sub.2 F; R.sub.f is a saturated fluoroaliphatic radical having at least 3 fully-fluorinated C atoms; and the F.sub.5 S group is bonded via a S--C bond to 1 of the 3 fully-fluorinated C atoms of the R.sub.f radical.

Abstract: Pentafluorosulfanyl fluoroaliphatic carbonyl and sulfonyl fluorides, derivatives of the acid fluorides and the preparation and use of the acid fluorides and derivatives. The fluoroaliphatic moiety of said acid fluorides comprise at least three fully-fluorinated carbon atoms. The derivatives of the acid fluorides are useful as surface-active agents and surface-treating agents.

Abstract: N,N,N',N'-tetrapropyldiaminopropane is fluorinated to produce a liquid predominantly perfluoro-N,N,N',N'-tetrapropyldiaminopropane, having inert properties and a boiling point in the range of 212.degree. C. to 216.degree. C. The inert liquid product is useful as a heat transfer liquid.

Abstract: Perfluoroaminoethers are provided. The perfluoroaminoiethers have two or more tertiary amino nitrogen atoms each of which is connected to the other(s) adjacent thereto by (1) a catenary, ether oxygen-containing, perfluoroalkylene linking group the catenary carbon atoms of which are in the form of segments of vicinal carbon atoms that are 2 to 4 in number, said segments having up to 5 carbon atoms, a catenary ether oxygen-containing perfluorocyclohexylene linking group, or (3) a catenary ether oxygen-containing linking group having perfluoroalkylene and perfluorocyclohexylene moieties, the sum of the catenary ether oxygen atoms being 1 to 6.

Abstract: Perfluoroaminoethers are provided. The perfluoroaminoiethers have two or more tertiary amino nitrogen atoms each of which is connected to the other(s) adjacent thereto by (1) a catenary, ether oxygen-containing, perfluoroalkylene linking group the catenary carbon atoms of which are in the form of segments of vicinal carbon atoms that are 2 to 4 in number, said segments having up to 5 carbon atoms, a catenary ether oxygen-containing perfluorocyclohexylene linking group, or (3) a catenary ether oxygen-containing linking group having perfluoroalkylene and perfluorocyclohexylene moieties, the sum of the catenary ether oxygen atoms being 1 to 6.

Abstract: Perfluoroaminoethers are provided. The perfluoroaminoethers have two or more tertiary amino nitrogen atoms each of which is connected to the other(s) adjacent thereto by (1) a catenary, ether oxygen-containing, perfluoroalkylene linking group the catenary carbon atoms of which are in the form of segments of vicinal carbon atoms that are 2 to 4 in number, said segments having up to 5 carbon atoms, a catenary ether oxygen-containing perfluorocyclohexylene linking group, or (3) a catenary ether oxygen-containing linking group having perfluoroalkylene and perfluorocyclohexylene moieties, the sum of the catenary ether oxygen atoms being 1 to 6.

Abstract: Di- and tri-substituted perfluorocycloalkane compounds which have a cyclohexane or decahydronaphthalene nucleus are provided. These perfluorocycloalkane compounds are carbonyl fluorides and derivatives thereof.

Abstract: When sensors are employed to monitor the evaporator refrigerant pressure and the leaving chilled liquid temperature in an air conditioning system of the type having a liquid chiller, the sensor outputs will normally have a prescribed relationship with respect to each other as long as the sensors are functioning properly and regardless of the operating condition of the air conditioning system. By effectively comparing the output of one sensor relative to that of the other sensor, a faulty condition of either sensor may be detected. This is achieved by calculating the equivalent evaporator temperature, from the evaporator refrigerant pressure, and subtracting the equivalent temperature from the leaving chilled liquid temperature to obtain a difference temperature which is then compared to a predetermined known temperature range representing normal functioning of the two sensors. When one of the sensors is defective the difference temperature will fall outside of the range.

Abstract: When sensors are employed to monitor different operating variables or parameters in a refrigeration system, the sensor outputs will normally have predetermined known relationships with respect to each other as long as the sensors are functioning properly and regardless of the operating condition of the refrigeration system. By comparing the output of one sensor relative to that of another sensor, a faulty condition of either of those two sensors may be detected. For example, during stabilized system operation the output of a condenser pressure sensor should always indicate a higher pressure than that reflected by the output of an evaporator pressure sensor. By effectively subtracting the evaporator pressure from the condenser pressure, a faulty sensor may be discovered. If the result of the subtraction is zero or negative, at least one of the pressure sensors is defective. When a faulty sensor is detected, a warning message is displayed to operating personnel.

Abstract: A rotatable conveyor apparatus for selectively discharging bulk material in any direction from the hopper of a belly-dump trailer is operatively supported in horizontal cantilever fashion by a rotatable material feed joint located beneath the hopper for rotation about a generally vertical axis. The conveyor and feed joint assembly are rigidly attached to and supported by an elongate, vertically oriented rotary shaft which is journaled in widely-spaced bearings which are positionally fixed by a rigid framework within the hopper of the trailer. The rigidly connected shaft, feed joint, and conveyor are operatively carried by the vehicle and may be rotated in unison to discharge the load to either side of the trailer without operatively disconnecting the conveyor from the trailer.

Abstract: To conserve energy in a large capacity refrigeration or air conditioning system, where liquid (usually water) is chilled by the system's evaporator and is then used to cool a building, the temperature setpoint of the chilled liquid leaving the evaporator may be reset upward from its desired level. Normally, if the temperature of the leaving chilled liquid falls below the setpoint by a fixed differential (such as 4.degree. F.) to a cut-out temperature, the system's compressor is shut down as a safety precaution to prevent freeze-ups. A nuisance compressor shutdown may be avoided when the setpoint is reset to a higher level (since the actual temperature of the leaving chilled liquid at that time may be at or below the desired setpoint and may be more than 4.degree. below the reset setpoint) by lowering the cut-out temperature to a fixed level substantially below the desired setpoint, such as down to 36.degree. F.

Abstract: A programmable maintenance timer system suitable for use with industrial equipment such as a centrifugal water chilling system and a telemetry system including a microprocessor-based computer with a programming device for presetting selectively a maintenance time interval representing a number of hours before a maintenance service is to be performed, for counting down the time interval to zero, and for generating an output signal after the time interval has reached zero to the telemetry system so as to alert service personnel that the industrial equipment is due for a scheduled maintenance. The timer system also includes a non-volatile memory device to record permanently the total elapsed operating hours in the preset maintenance time interval so as to avoid loss of such information upon a power failure and/or back-up battery failure.