Abstract: Processes for recovery of carbon dioxide from a gas stream are described. The processes reduce dehydration cost in CO2 capture systems and minimize the formation of COS and H2O and enable water removal with an enhanced solvent-based absorbent operating at a lower temperature. This allows low residual water levels to be achieved in the dried gas. Also, feed streams containing high levels of CO2 and H2S can be treated in an integrated system comprising a cryogenic CO2 fractionation system, an overhead pressure swing adsorption (PSA) unit, and a CO2 temperature swing adsorption (TSA) unit. The processes allow recovery of helium and methane as well as CO2 and H2S.

Abstract: Integrated processes for hydrogen production and carbon dioxide recovery are described. The processes use a chilling stream in a cryogenic carbon dioxide recovery unit. The chilling stream chills a working fluid which chills the hydrogen-depleted tail gas stream from a hydrogen pressure swing adsorption (PSA) unit to form a carbon dioxide product stream.

Abstract: Processes for removing contaminants in CO2 recovery processes are described. The processes incorporate water wash units and/or NO2—SO2 removal section to remove sulfur oxide compounds and heavy nitric oxide compounds such as NO2. Some processes include CO2 PSA units and CO2 fractionation columns, while others only use CO2 PSA units. The CO2 PSA concentrates CO2 along with heavy nitric oxide compounds, SO2 and NH3. Optional quench columns, guard beds, particulate polishing units, and molecular sieves can be used remove HCl, HF, SO2, SO3, NH3, hydrocarbons, mercury, and heavy metals.

Abstract: A process is provided for treating a hydrocarbon gas stream by condensing a portion of the gas stream to produce a liquid stream, then through several steps subcooling a portion of the liquid stream to be introduced into a midpoint into a fractionation column. Unexpectedly, it has been found that the recompression and refrigeration power requirements are substantially reduced and the minimum approach to carbon dioxide freezing are increased when the liquid stream is introduced to a midpoint in the column when compared to introducing the liquid stream to a top position or a lower position in the fractionation column.

Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream containing significant quantities of components more volatile than methane (hydrogen, nitrogen, etc.). The gas stream is partially condensed, then the remaining vapor is expanded to lower pressure and supplied to a fractionation tower at a mid-column feed position. The condensed liquid is cooled and divided into two portions. The first portion is expanded to tower pressure, heated by cooling the liquid, and supplied to the tower at a lower column feed position. The second portion is further cooled, expanded to tower pressure, and supplied to the tower at a top feed position. The tower overhead vapor is heated by cooling the second portion. The quantities and temperatures of the feeds to the tower maintain the overhead temperature of the tower whereby the major portion of the desired components is recovered.

Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream which is divided into first and second streams. The first stream is cooled, expanded to lower pressure, and supplied to a fractionation tower. The second stream is cooled and separated into vapor and liquid streams. The vapor stream is divided into two portions. A first portion is cooled, expanded to tower pressure, and supplied to the tower at an upper mid-column feed position. The second portion and the liquid stream are expanded to tower pressure and supplied to the tower. After heating, compressing, and cooling, a portion of the tower overhead vapor is cooled, expanded, and supplied to the tower at the top feed position. The quantities and temperatures of the feeds to the tower maintain the overhead temperature of the tower whereby the major portion of the desired components is recovered.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. A portion of the outlet vapor from the processing assembly is compressed to higher pressure, cooled and substantially condensed in a heat exchange means inside the processing assembly, then expanded to lower pressure and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. The outlet vapor from the processing assembly is compressed to higher pressure and cooled, then a portion is substantially condensed in a heat exchange means inside the processing assembly, expanded to lower pressure, and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.

Abstract: A process is provided for treating a hydrocarbon gas stream by condensing a portion of the gas stream to produce a liquid stream, then through several steps subcooling a portion of the liquid stream to be introduced into a midpoint into a fractionation column. Unexpectedly, it has been found that the recompression and refrigeration power requirements are substantially reduced and the minimum approach to carbon dioxide freezing are increased when the liquid stream is introduced to a midpoint in the column when compared to introducing the liquid stream to a top position or a lower position in the fractionation column.

Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream containing significant quantities of components more volatile than methane (hydrogen, nitrogen, etc.). The gas stream is partially condensed, then the remaining vapor is expanded to lower pressure and supplied to a fractionation tower at a mid-column feed position. The condensed liquid is cooled and divided into two portions. The first portion is expanded to tower pressure, heated by cooling the liquid, and supplied to the tower at a lower column feed position. The second portion is further cooled, expanded to tower pressure, and supplied to the tower at a top feed position. The tower overhead vapor is heated by cooling the second portion. The quantities and temperatures of the feeds to the tower maintain the overhead temperature of the tower whereby the major portion of the desired components is recovered.

Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream containing significant quantities of components more volatile than methane (hydrogen, nitrogen, etc.). The gas stream is partially condensed, then the remaining vapor is expanded to lower pressure and supplied to a fractionation tower at a mid-column feed position. The condensed liquid is cooled and divided into two portions. The first portion is expanded to tower pressure, heated by cooling the liquid, and supplied to the tower at a lower column feed position. The second portion is expanded to tower pressure and supplied to the tower at an upper mid-column feed position. A distillation vapor stream is withdrawn from the fractionation tower below the mid-column feed position and is heated, compressed to higher pressure, and cooled to substantial condensation before it is expanded and supplied to the tower as its top feed.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to fractionate lighter components from mixed hydrocarbon streams. The hydrocarbon stream is supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a volatile stream and a condensed stream. The condensed stream is supplied to the absorbing means as its top feed. A distillation liquid stream is collected from the lower region of the mass transfer means and heated in a second heat and mass transfer means inside the processing assembly to strip out its volatile components, forming a relatively less volatile stream and a vaporized stream. The vaporized stream is supplied to the mass transfer means as its bottom feed.

Abstract: A process and an apparatus are disclosed for the recovery of components from a hydrocarbon gas stream which is divided into first and second streams. The first stream is cooled, expanded to lower pressure, and supplied to a fractionation tower. The second stream is cooled and separated into vapor and liquid streams. The vapor stream is divided into two portions. A first portion is cooled, expanded to tower pressure, and supplied to the tower at an upper mid-column feed position. The second portion and the liquid stream are expanded to tower pressure and supplied to the tower. After heating, compressing, and cooling, a portion of the tower overhead vapor is cooled, expanded, and supplied to the tower at the top feed position. The quantities and temperatures of the feeds to the tower maintain the overhead temperature of the tower whereby the major portion of the desired components is recovered.

Abstract: A process for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream is disclosed. The stream is cooled and is thereafter expanded to the fractionation tower pressure and supplied to the fractionation tower at a lower mid-column feed position. A distillation stream is withdrawn from the column below the feed point of the stream and is then directed into heat exchange relation with the tower overhead vapor stream to cool the distillation stream and condense at least a part of it, forming a condensed stream. At least a portion of the condensed stream is directed to the fractionation tower at an upper mid-column feed position. A recycle stream is withdrawn from the tower overhead after it has been warmed and compressed. The compressed recycle stream is cooled sufficiently to substantially condense it, and is then expanded to the pressure of the fractionation tower and supplied to the tower at a top column feed position.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. A portion of the outlet vapor from the processing assembly is compressed to higher pressure, cooled and substantially condensed in a heat exchange means inside the processing assembly, then expanded to lower pressure and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. A portion of the outlet vapor from the processing assembly is compressed to higher pressure, cooled and substantially condensed in a heat exchange means inside the processing assembly, then expanded to lower pressure and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. A portion of the outlet vapor from the processing assembly is compressed to higher pressure, cooled and substantially condensed in a heat exchange means inside the processing assembly, then expanded to lower pressure and supplied, to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.

Abstract: A process and an apparatus are disclosed for the recovery of ethane, ethylene, propane, propylene, and heavier hydrocarbon components from a hydrocarbon gas stream. The stream is divided into first and second streams. The first stream is cooled to condense substantially all of it, expanded to lower pressure, and supplied to a fractionation tower at an upper mid-column feed position. The second stream is cooled sufficiently to partially condense it and separated into vapor and liquid streams. The vapor stream is divided into first and second portions. The first portion is cooled to condense substantially all of it, expanded to the tower pressure, and supplied to the tower at the top feed position. The second portion is expanded to the tower pressure and supplied to the fractionation tower at an intermediate mid-column feed position. The liquid stream is expanded to the tower pressure and supplied to the column at a lower mid-column feed position.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to remove C5 and heavier hydrocarbon components from a hydrocarbon gas stream. The hydrocarbon gas stream is expanded to lower pressure and supplied to the processing assembly between an absorbing means and a mass transfer means. A distillation vapor stream is collected from the upper region of the absorbing means and cooled in a first heat and mass transfer means inside the processing assembly to partially condense it, forming a residual vapor stream and a condensed stream. The condensed stream is supplied to the absorbing means at its top feed point. A distillation liquid stream is collected from the lower region of the mass transfer means and directed into a second heat and mass transfer means inside the processing assembly to heat it and strip out its volatile components.

Abstract: A process and an apparatus are disclosed for a compact processing assembly to improve the recovery of C2 (or C3) and heavier hydrocarbon components from a hydrocarbon gas stream. The preferred method of separating a hydrocarbon gas stream generally includes producing at least a substantially condensed first stream and a cooled second stream, expanding both streams to lower pressure, and supplying the streams to a fractionation tower. In the process and apparatus disclosed, the tower overhead vapor is directed to an absorbing means and a heat and mass transfer means inside a processing assembly. The outlet vapor from the processing assembly is compressed to higher pressure and cooled, then a portion is substantially condensed in a heat exchange means inside the processing assembly, expanded to lower pressure, and supplied to the heat and mass transfer means to provide cooling. Condensed liquid from the absorbing means is fed to the tower.