Patents by Inventor John Eugene Palamara
John Eugene Palamara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20220252341Abstract: Integration of a natural gas liquefaction system, a hydrogen production system, and power generation system to increase CO2 capture and improve overall plant efficiency. The predominantly methane endflash is sent to the hydrogen production system which produces hydrogen and CO2. The CO2 may be captured or beneficially used. At least a portion of the hydrogen produced is used to fuel gas turbines in the power generation which, in turn, provides power for the refrigeration compressor of the natural gas liquefaction system—either in the form of mechanical work or electricity.Type: ApplicationFiled: February 5, 2021Publication date: August 11, 2022Applicant: Air Products and Chemicals, Inc.Inventors: Annemarie Ott Weist, Jeremy D. Beard, David Ross Graham, John Eugene Palamara, Mark Julian Roberts, Dejan Veskovic
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Patent number: 11353261Abstract: Light gases such as helium are extracted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.Type: GrantFiled: October 31, 2019Date of Patent: June 7, 2022Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, John Eugene Palamara, Cory E. Sanderson, John H. Petrik
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Publication number: 20210131727Abstract: Light gases such as helium are extacted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.Type: ApplicationFiled: October 31, 2019Publication date: May 6, 2021Applicant: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, John Eugene Palamara, Cory E. Sanderson, John H. Petrik
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Patent number: 10655912Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulfide, are removed from crude carbon dioxide by processes involving distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapor and bottoms liquid enriched with said impurities. Where such processes involve a single heat pump cycle, significant savings in power consumption are realized when the distillation column system is re-boiled by at least partially vaporizing liquid in or taken from an intermediate location in the column system.Type: GrantFiled: October 22, 2014Date of Patent: May 19, 2020Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, John Eugene Palamara, Galip Hakan Guvelioglu
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Patent number: 10267560Abstract: The power required to recover C3+ hydrocarbons from crude carbon dioxide comprising C1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce “lighter” and “heavier” hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.Type: GrantFiled: December 30, 2013Date of Patent: April 23, 2019Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, Liu Yang, John Eugene Palamara, Vincent White
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Patent number: 10254042Abstract: In a process for separating at least one “heavy” impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one “light” impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the “light” impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed “light” impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.Type: GrantFiled: October 25, 2013Date of Patent: April 9, 2019Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
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Patent number: 10215488Abstract: Helium can be recovered from nitrogen-rich natural gas at high pressure with low helium loss by cryogenic distillation of the natural gas after pre-treatment of the gas to remove incompatible impurities and then recovery of natural gas liquid (NGL) from the pre-treated gas by distillation. Overall power consumption may be reduced, particularly if the feed to the helium recovery column system is at least substantially condensed by indirect heat exchange against a first portion of nitrogen-enriched bottoms liquid at first pressure, and a second portion of nitrogen-enriched bottoms liquid at a second pressure that is different from the first pressure.Type: GrantFiled: February 11, 2016Date of Patent: February 26, 2019Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
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Publication number: 20190041128Abstract: Overall power consumption in a cryogenic distillation process for recovering helium from nitrogen-rich gases comprising helium may be reduced if the feed to the distillation column system is at least substantially condensed by indirect heat exchange against a first bottoms liquid at first pressure, and a second bottoms liquid at a second pressure that is different from the first pressure.Type: ApplicationFiled: October 9, 2018Publication date: February 7, 2019Applicant: Air Products and Chemicals, Inc.Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
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Patent number: 10060348Abstract: Carbon dioxide is separated from natural gas using a single stage membrane separation system to produce a retentate gas that typically meets the specification for pipeline distribution of natural gas, and a permeate gas comprising methane that is combusted to generate power and/or heat, e.g. for use in providing the utility requirements of the process itself or for export to an integrated process. Advantages include an overall reduction in power consumption and improvement in process efficiency.Type: GrantFiled: September 25, 2014Date of Patent: August 28, 2018Assignee: Air Products and Chemicals, Inc.Inventors: Jason Michael Ploeger, John Eugene Palamara, Jack Theodore Kindt
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Patent number: 9945608Abstract: The invention provides systems and methods for separating ethane and heavier hydrocarbons from a natural gas stream. In aspects of the invention, an adsorption unit is integrated with a cryogenic gas processing plant in order to overcome methane recovery limitations by sending the tail gas from the adsorption unit to the cryogenic gas processing plant to recover methane that would otherwise be lost.Type: GrantFiled: July 23, 2012Date of Patent: April 17, 2018Assignee: Air Products and Chemicals, Inc.Inventors: Jason Michael Ploeger, Timothy Christopher Golden, Jeffrey Raymond Hufton, John Eugene Palamara
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Patent number: 9791210Abstract: Systems and methods are provided for recovering helium from a feed comprising helium, carbon dioxide, and at least one intermediate component having a volatility between those of helium and carbon dioxide. In particular, processes of the present invention comprise separating the carbon dioxide and the components of intermediate volatility from the helium at a temperature greater than ?82.7° C. to form a helium-rich product stream, wherein the concentration of at least one of the intermediate components in the helium-rich product stream is lower than its concentration in the feed stream, and wherein at least part of the separation is effected by contacting a vapor with a liquid.Type: GrantFiled: August 2, 2012Date of Patent: October 17, 2017Assignee: Air Products and Chemicals, Inc.Inventors: Paul Higginbotham, Vincent White, John Eugene Palamara
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Publication number: 20170234612Abstract: Helium can be recovered from nitrogen-rich natural gas at high pressure with low helium loss by cryogenic distillation of the natural gas after pre-treatment of the gas to remove incompatible impurities and then recovery of natural gas liquid (NGL) from the pre-treated gas by distillation. Overall power consumption may be reduced, particularly if the feed to the helium recovery column system is at least substantially condensed by indirect heat exchange against a first portion of nitrogen-enriched bottoms liquid at first pressure, and a second portion of nitrogen-enriched bottoms liquid at a second pressure that is different from the first pressure.Type: ApplicationFiled: February 11, 2016Publication date: August 17, 2017Applicant: Air Products and Chemicals, Inc.Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
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Publication number: 20170234611Abstract: Overall power consumption in a cryogenic distillation process for recovering helium from nitrogen-rich gases comprising helium may be reduced if the feed to the distillation column system is at least substantially condensed by indirect heat exchange against a first bottoms liquid at first pressure, and a second bottoms liquid at a second pressure that is different from the first pressure.Type: ApplicationFiled: February 11, 2016Publication date: August 17, 2017Applicant: Air Products and Chemicals, Inc.Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
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Publication number: 20160090910Abstract: Carbon dioxide is separated from natural gas using a single stage membrane separation system to produce a retentate gas that typically meets the specification for pipeline distribution of natural gas, and a permeate gas comprising methane that is combusted to generate power and/or heat, e.g. for use in providing the utility requirements of the process itself or for export to an integrated process. Advantages include an overall reduction in power consumption and improvement in process efficiency.Type: ApplicationFiled: September 25, 2014Publication date: March 31, 2016Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Jason Michael Ploeger, John Eugene Palamara, Jack Theodore Kindt
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Publication number: 20150184932Abstract: The power required to recover C3+ hydrocarbons from crude carbon dioxide comprising C1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce “lighter” and “heavier” hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.Type: ApplicationFiled: December 30, 2013Publication date: July 2, 2015Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Paul Higginbotham, Liu Yang, John Eugene Palamara, Vincent White
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Publication number: 20150114033Abstract: In a process for separating at least one “heavy” impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one “light” impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the “light” impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed “light” impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.Type: ApplicationFiled: October 25, 2013Publication date: April 30, 2015Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
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Publication number: 20150114032Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulfide, are removed from crude carbon dioxide by processes involving distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapor and bottoms liquid enriched with said impurities. Where such processes involve a single heat pump cycle, significant savings in power consumption are realized when the distillation column system is re-boiled by at least partially vaporizing liquid in or taken from an intermediate location in the column system.Type: ApplicationFiled: October 22, 2014Publication date: April 30, 2015Inventors: Paul Higginbotham, John Eugene Palamara, Galip Hakan Guvelioglu
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Publication number: 20150114034Abstract: In a process for separating “heavy” impurities such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of “light” impurities such as non-condensable gases, involving at least one heat pump cycle using as working fluid a fluid from the “heavy” impurity separation, the “light” impurities are removed from carbon dioxide-enriched gas generated in the “heavy” impurity separation. The carbon dioxide-enriched gas, or a compressed carbon dioxide-enriched gas produced therefrom, is at least partially condensed by indirect heat exchange against intermediate liquid also generated in the “heavy” impurity separation. Total and specific energy consumption is reduced compared to conventional processes in which “light” impurities are removed from carbon dioxide product gas.Type: ApplicationFiled: October 25, 2013Publication date: April 30, 2015Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
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Publication number: 20140033764Abstract: Systems and methods are provided for recovering helium from a feed comprising helium, carbon dioxide, and at least one intermediate component having a volatility between those of helium and carbon dioxide. In particular, processes of the present invention comprise separating the carbon dioxide and the components of intermediate volatility from the helium at a temperature greater than ?82.7° C. to form a helium-rich product stream, wherein the concentration of at least one of the intermediate components in the helium-rich product stream is lower than its concentration in the feed stream, and wherein at least part of the separation is effected by contacting a vapor with a liquid.Type: ApplicationFiled: August 2, 2012Publication date: February 6, 2014Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Paul Higginbotham, Vincent White, John Eugene Palamara
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Publication number: 20130283851Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulphide, are removed from crude carbon dioxide by processes involving sub-ambient distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapour and bottoms liquid enriched with said impurities. Where such processes involve at least one heat pump cycle, significant savings in power consumption are realised when the process uses more than one recycle pressure in the heat pump cycle(s).Type: ApplicationFiled: April 26, 2012Publication date: October 31, 2013Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Paul Higginbotham, John Eugene Palamara