Patents by Inventor John Eugene Palamara

John Eugene Palamara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220252341
    Abstract: Integration of a natural gas liquefaction system, a hydrogen production system, and power generation system to increase CO2 capture and improve overall plant efficiency. The predominantly methane endflash is sent to the hydrogen production system which produces hydrogen and CO2. The CO2 may be captured or beneficially used. At least a portion of the hydrogen produced is used to fuel gas turbines in the power generation which, in turn, provides power for the refrigeration compressor of the natural gas liquefaction system—either in the form of mechanical work or electricity.
    Type: Application
    Filed: February 5, 2021
    Publication date: August 11, 2022
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Annemarie Ott Weist, Jeremy D. Beard, David Ross Graham, John Eugene Palamara, Mark Julian Roberts, Dejan Veskovic
  • Patent number: 11353261
    Abstract: Light gases such as helium are extracted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.
    Type: Grant
    Filed: October 31, 2019
    Date of Patent: June 7, 2022
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, John Eugene Palamara, Cory E. Sanderson, John H. Petrik
  • Publication number: 20210131727
    Abstract: Light gases such as helium are extacted from a carbon dioxide-containing feed stream by distillation. Costly dehydration steps are avoided by pumping the liquid bottoms stream leaving the distillation column without vaporization so as to ensure that any water present in the feed remains in solution with the bulk stream leaving the process. This prevents any liquid phase water causing corrosion or solid ice or hydrates forming to plug the flow.
    Type: Application
    Filed: October 31, 2019
    Publication date: May 6, 2021
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, John Eugene Palamara, Cory E. Sanderson, John H. Petrik
  • Patent number: 10655912
    Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulfide, are removed from crude carbon dioxide by processes involving distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapor and bottoms liquid enriched with said impurities. Where such processes involve a single heat pump cycle, significant savings in power consumption are realized when the distillation column system is re-boiled by at least partially vaporizing liquid in or taken from an intermediate location in the column system.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: May 19, 2020
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, John Eugene Palamara, Galip Hakan Guvelioglu
  • Patent number: 10267560
    Abstract: The power required to recover C3+ hydrocarbons from crude carbon dioxide comprising C1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce “lighter” and “heavier” hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.
    Type: Grant
    Filed: December 30, 2013
    Date of Patent: April 23, 2019
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, Liu Yang, John Eugene Palamara, Vincent White
  • Patent number: 10254042
    Abstract: In a process for separating at least one “heavy” impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one “light” impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the “light” impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed “light” impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.
    Type: Grant
    Filed: October 25, 2013
    Date of Patent: April 9, 2019
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
  • Patent number: 10215488
    Abstract: Helium can be recovered from nitrogen-rich natural gas at high pressure with low helium loss by cryogenic distillation of the natural gas after pre-treatment of the gas to remove incompatible impurities and then recovery of natural gas liquid (NGL) from the pre-treated gas by distillation. Overall power consumption may be reduced, particularly if the feed to the helium recovery column system is at least substantially condensed by indirect heat exchange against a first portion of nitrogen-enriched bottoms liquid at first pressure, and a second portion of nitrogen-enriched bottoms liquid at a second pressure that is different from the first pressure.
    Type: Grant
    Filed: February 11, 2016
    Date of Patent: February 26, 2019
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
  • Publication number: 20190041128
    Abstract: Overall power consumption in a cryogenic distillation process for recovering helium from nitrogen-rich gases comprising helium may be reduced if the feed to the distillation column system is at least substantially condensed by indirect heat exchange against a first bottoms liquid at first pressure, and a second bottoms liquid at a second pressure that is different from the first pressure.
    Type: Application
    Filed: October 9, 2018
    Publication date: February 7, 2019
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
  • Patent number: 10060348
    Abstract: Carbon dioxide is separated from natural gas using a single stage membrane separation system to produce a retentate gas that typically meets the specification for pipeline distribution of natural gas, and a permeate gas comprising methane that is combusted to generate power and/or heat, e.g. for use in providing the utility requirements of the process itself or for export to an integrated process. Advantages include an overall reduction in power consumption and improvement in process efficiency.
    Type: Grant
    Filed: September 25, 2014
    Date of Patent: August 28, 2018
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Jason Michael Ploeger, John Eugene Palamara, Jack Theodore Kindt
  • Patent number: 9945608
    Abstract: The invention provides systems and methods for separating ethane and heavier hydrocarbons from a natural gas stream. In aspects of the invention, an adsorption unit is integrated with a cryogenic gas processing plant in order to overcome methane recovery limitations by sending the tail gas from the adsorption unit to the cryogenic gas processing plant to recover methane that would otherwise be lost.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: April 17, 2018
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Jason Michael Ploeger, Timothy Christopher Golden, Jeffrey Raymond Hufton, John Eugene Palamara
  • Patent number: 9791210
    Abstract: Systems and methods are provided for recovering helium from a feed comprising helium, carbon dioxide, and at least one intermediate component having a volatility between those of helium and carbon dioxide. In particular, processes of the present invention comprise separating the carbon dioxide and the components of intermediate volatility from the helium at a temperature greater than ?82.7° C. to form a helium-rich product stream, wherein the concentration of at least one of the intermediate components in the helium-rich product stream is lower than its concentration in the feed stream, and wherein at least part of the separation is effected by contacting a vapor with a liquid.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: October 17, 2017
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Paul Higginbotham, Vincent White, John Eugene Palamara
  • Publication number: 20170234611
    Abstract: Overall power consumption in a cryogenic distillation process for recovering helium from nitrogen-rich gases comprising helium may be reduced if the feed to the distillation column system is at least substantially condensed by indirect heat exchange against a first bottoms liquid at first pressure, and a second bottoms liquid at a second pressure that is different from the first pressure.
    Type: Application
    Filed: February 11, 2016
    Publication date: August 17, 2017
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
  • Publication number: 20170234612
    Abstract: Helium can be recovered from nitrogen-rich natural gas at high pressure with low helium loss by cryogenic distillation of the natural gas after pre-treatment of the gas to remove incompatible impurities and then recovery of natural gas liquid (NGL) from the pre-treated gas by distillation. Overall power consumption may be reduced, particularly if the feed to the helium recovery column system is at least substantially condensed by indirect heat exchange against a first portion of nitrogen-enriched bottoms liquid at first pressure, and a second portion of nitrogen-enriched bottoms liquid at a second pressure that is different from the first pressure.
    Type: Application
    Filed: February 11, 2016
    Publication date: August 17, 2017
    Applicant: Air Products and Chemicals, Inc.
    Inventors: Vincent White, Paul Higginbotham, John Eugene Palamara, Alan Berger
  • Publication number: 20160090910
    Abstract: Carbon dioxide is separated from natural gas using a single stage membrane separation system to produce a retentate gas that typically meets the specification for pipeline distribution of natural gas, and a permeate gas comprising methane that is combusted to generate power and/or heat, e.g. for use in providing the utility requirements of the process itself or for export to an integrated process. Advantages include an overall reduction in power consumption and improvement in process efficiency.
    Type: Application
    Filed: September 25, 2014
    Publication date: March 31, 2016
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Jason Michael Ploeger, John Eugene Palamara, Jack Theodore Kindt
  • Publication number: 20150184932
    Abstract: The power required to recover C3+ hydrocarbons from crude carbon dioxide comprising C1+ hydrocarbons and hydrogen sulfide may be reduced by distilling the crude carbon dioxide to produce carbon dioxide-enriched overhead vapor and C3+ hydrocarbon-enriched bottoms liquid such that the hydrogen sulfide is rejected with the overhead vapor. Power consumption reductions may be achieved by incorporating a heat pump cycle using carbon dioxide vapor as working fluid to provide at least a part of the refrigeration duty and using a side reboiler to reduce the bottom reboiler duty. Where the bottoms liquid is further processed to produce “lighter” and “heavier” hydrocarbon fractions, the process enables optimization of upgrading crude oil on the basis of API gravity, Reid Vapor pressure and/or viscosity.
    Type: Application
    Filed: December 30, 2013
    Publication date: July 2, 2015
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Paul Higginbotham, Liu Yang, John Eugene Palamara, Vincent White
  • Publication number: 20150114033
    Abstract: In a process for separating at least one “heavy” impurity such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of at least one “light” impurity such as non-condensable gases, involving at least one heat pump cycle using carbon dioxide-containing fluid from the process as the working fluid, the “light” impurity is removed from the crude carbon dioxide and carbon dioxide is subsequently recovered from the removed “light” impurity, thereby improving overall carbon dioxide recovery and efficiency in terms of energy consumption.
    Type: Application
    Filed: October 25, 2013
    Publication date: April 30, 2015
    Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
  • Publication number: 20150114032
    Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulfide, are removed from crude carbon dioxide by processes involving distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapor and bottoms liquid enriched with said impurities. Where such processes involve a single heat pump cycle, significant savings in power consumption are realized when the distillation column system is re-boiled by at least partially vaporizing liquid in or taken from an intermediate location in the column system.
    Type: Application
    Filed: October 22, 2014
    Publication date: April 30, 2015
    Inventors: Paul Higginbotham, John Eugene Palamara, Galip Hakan Guvelioglu
  • Publication number: 20150114034
    Abstract: In a process for separating “heavy” impurities such as hydrogen sulfide from crude carbon dioxide comprising significant quantities of “light” impurities such as non-condensable gases, involving at least one heat pump cycle using as working fluid a fluid from the “heavy” impurity separation, the “light” impurities are removed from carbon dioxide-enriched gas generated in the “heavy” impurity separation. The carbon dioxide-enriched gas, or a compressed carbon dioxide-enriched gas produced therefrom, is at least partially condensed by indirect heat exchange against intermediate liquid also generated in the “heavy” impurity separation. Total and specific energy consumption is reduced compared to conventional processes in which “light” impurities are removed from carbon dioxide product gas.
    Type: Application
    Filed: October 25, 2013
    Publication date: April 30, 2015
    Inventors: Paul Higginbotham, Galip Hakan Guvelioglu, John Eugene Palamara, Vincent White
  • Publication number: 20140033764
    Abstract: Systems and methods are provided for recovering helium from a feed comprising helium, carbon dioxide, and at least one intermediate component having a volatility between those of helium and carbon dioxide. In particular, processes of the present invention comprise separating the carbon dioxide and the components of intermediate volatility from the helium at a temperature greater than ?82.7° C. to form a helium-rich product stream, wherein the concentration of at least one of the intermediate components in the helium-rich product stream is lower than its concentration in the feed stream, and wherein at least part of the separation is effected by contacting a vapor with a liquid.
    Type: Application
    Filed: August 2, 2012
    Publication date: February 6, 2014
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Paul Higginbotham, Vincent White, John Eugene Palamara
  • Publication number: 20130283851
    Abstract: Impurities that are less volatile than carbon dioxide, e.g. hydrogen sulphide, are removed from crude carbon dioxide by processes involving sub-ambient distillation of said crude carbon dioxide in a distillation column system operating at super-atmospheric pressure(s) to produce carbon dioxide-enriched overhead vapour and bottoms liquid enriched with said impurities. Where such processes involve at least one heat pump cycle, significant savings in power consumption are realised when the process uses more than one recycle pressure in the heat pump cycle(s).
    Type: Application
    Filed: April 26, 2012
    Publication date: October 31, 2013
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventors: Paul Higginbotham, John Eugene Palamara