Patent number: 4012399
Abstract: Ultraviolet light absorbers and stabilizers, particularly for monolefin polymers, are provided from metal complexes of trivalent phosphorus compounds of the formulaeMe (L).sub.n (A).sub.m (L').sub.owhere Me is preferably nickel but can be manganese, iron, copper, molybdenum or tungsten, L is P(X)(Y)(Z) where any one or all of X, Y and Z can be O hydrocarbyl, ##STR1## where R.sub.31 and R.sub.32 are hydrocarbyl or hydrogen, S hydrocarbyl, hydrocarbyl, 2 or 3 of X, Y and Z can form one or more heterocyclic rings with P, A is an anion such as halogen, e.g. Cl, Br, I or F, NO.sub.3, C104, R.sub.33 COO- where R.sub.33 is hydrocarbyl, any hydrocarbyl group can have 1 or 2 halogen substituents, m is 0 or a small whole number, e.g. 1,2,3,4, L' is CO, NO, CN, halogen, o is zero or a small whole number, e.g. 1,2,3,4, n is 1 or another small whole number, e.g. 2,3,4, o+m+n is not greater than the highest coordination number of the metal.
Type:
Grant
Filed:
November 4, 1975
Date of Patent:
March 15, 1977
Assignee:
Cincinnati Milacron Chemicals, Inc.
Inventors:
Ingenuin Hechenbleikner, Thomas G. Kugele, John F. Hussar
Patent number: 3959220
Abstract: Ultraviolet light absorbers and stabilizers, particularly for monolefin polymers, are provided from metal complexes of trivalent phosphorus compounds of the formulaeMe (L).sub.n (A).sub.m (L').sub.owhere Me is preferably nickel but can be manganese, iron, copper, molybdenum or tungsten, L is P(X)(Y)(Z) where any one or all of X, Y and Z can be O hydrocarbyl, ##EQU1## where R.sub.31 and R.sub.32 are hydrocarbyl oro hydrogen, S hydrocarbyl, hydrocarbyl, 2 or 3 of X, Y and Z can form one or more heterocyclic rings with P, A is an anion such as halogen, e.g. Cl, Br, I or F, NO.sub.3, ClO.sub.4, R.sub.33 COO.sup.- where R.sub.33 is hydrocarbyl, any hydrocarbyl group can have 1 or 2 halogen substituents, m is 0 or a small whole number, e.g. 1,2,3,4, L' is CO, NO, CN, halogen, o is zero or a small whole number, e.g. 1,2,3,4, n is 1 or another small whole number, e.g. 2,3,4, o+m+n is not greater than the highest coordination number of the metal.
Type:
Grant
Filed:
December 16, 1971
Date of Patent:
May 25, 1976
Assignee:
Cincinnati Milacron Chemicals, Inc.
Inventors:
Ingenuin Hechenbleikner, Thomas G. Kugele, John F. Hussar