Abstract: A process is disclosed for the removal of metals contaminants, particularly calcium, from hydrocarbonaceous feedstocks. The process comprises mixing the feedstock with an aqueous solution of a metals sequestering agent, particularly amino-carboxylic acids, their salts, or mixtures thereof, more particularly EDTA, and separating the aqueous solution containing the metals from the demetalated feedstock.

Abstract: A process is disclosed for the demetalation of organically-bound compounds of Group VIII metals, particularly iron, from hydrocarbonaceous feedstock. In the process, an aqueous solution of amino-carboxylic acid, or salts, particularly EDTA, is used to form complexes with the metals and extract them from the feedstock. The aqueous phase containing the complexed metals contaminants is then separated from the hydrocarbonaceous phase.

Abstract: A process is disclosed for removing metals contaminants, particularly calcium compounds, from hydrocarbonaceous feedstocks using aqueous carbonic acids, its salts, or mixtures thereof as the metals extraction agent. The hydrocarbonaceous layer and aqueous layers are then separated and the demetalated hydrocarbonaceous feedstock is removed for further processing.

Abstract: A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and dispersed activated or presulfided red mud having demetalizing and coke-suppressing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocatalytic conditions.

Abstract: A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and metals-impregnated red mud having coke-suppressing and demetalizing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocatalytic conditions. The preferred metals for impregnation include transition metals, in particular, nickel and molybdenum.

Abstract: A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and red mud having coke-suppressing and demetalizing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocracking conditions.