Abstract: A polymeric composition including a copolymer comprising a first monomer having a high carbon to oxygen ratio of from about 3 to about 8; a second monomer comprising two or more vinyl groups, wherein the second monomer is present in the copolymer in an amount of from greater than about 8 percent by weight to about 60 percent by weight, based on the weight of the copolymer; and, optionally, a third monomer comprising an amine, wherein the third monomer, if present, is present in an amount of from about 0.5 percent by weight to about 5 percent by weight, based on the weight of the copolymer. A toner including the copolymer as a toner surface additive. An emulsion aggregation toner process including the copolymer as a toner surface additive.

Abstract: A toner having a high colorant concentration and a binder resin that includes a polyester resin having linear portions and crosslinked portions of high density crosslinked microgel particles has a melt flow index value of about 11±MFI units. The binder resin may also include a mixture of two polyester resins having different MFI values.

Abstract: A die for the preparation of a toner resin in an extruder having a housing defining a housing aperture therein and a conveyor for conveying the resin through the housing aperture to form a stream of resin is provided. The die includes a member connected to a first end of the housing. The member defines an opening therethrough. The cross sectional area of the opening is progressively reduced in the direction of the stream of resin for at least a substantial portion of the opening.

Abstract: An apparatus for the preparation of a mixture of toner resin and initiator, to form a toner resin or toner mixture including cross-linked microgel particles is provided. The apparatus includes a toner extruder having the resin being conveyed therethrough and an adder for adding the initiator to the toner resin in the toner extruder to form the toner resin or mixture. The apparatus also includes a measurer for measuring the cross-linked microgel particles in the toner mixture substantially immediately after mixing in the toner extruder and transmitting a signal indicative of the quantity of cross-linked microgel particles in the toner resin or mixture. The apparatus also includes a controller for controlling the addition rate of initiator in response to the signals from the measurer.

Abstract: A die for the preparation of a toner resin in an extruder having a housing defining a housing aperture therein and a conveyor for conveying the resin through the housing aperture to form a stream of resin is provided. The die includes a member connected to a first end of the housing. The member defines an opening therethrough. The member includes a splitter disposed adjacent the opening for splitting a stream of resin passing through the opening in a first direction into two separate streams of resin.

Abstract: An apparatus for the preparation of a mixture of toner resin and initiator, to form a toner resin or toner mixture including cross-linked microgel particles is provided. The apparatus includes a toner extruder having the resin being conveyed therethrough and an adder for adding the initiator to the toner resin in the toner extruder to form the toner resin or mixture. The apparatus also includes a measurer for measuring the cross-linked microgel particles in the toner mixture substantially immediately after mixing in the toner extruder and transmitting a signal indicative of the quantity of cross-linked microgel particles in the toner resin or mixture. The apparatus also includes a controller for controlling the addition rate of initiator in response to the signals from the measurer.

Abstract: A process for the preparation of pigmented toner compositions comprising: a) forming at a first temperature, a first melt mixture comprised of a partially crosslinked thermoplastic resin, pigment, optionally a wax, and optional additives, wherein the partially crosslinked thermoplastic resin is comprised of a mixture of crosslinked resin macrogel particles, crosslinked resin microgel particles, and uncrosslinked resin; and b) melt mixing at a second temperature, the first melt mixture to form a second mixture, wherein the macrogel particles are partially converted into microgel particles, and wherein the second temperature is less than or equal to the first temperature.