Patents by Inventor John L. Burba
John L. Burba has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20040146784Abstract: The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The freshly prepared anodes of the invention are combined with a positive electrode including an active material, a separator that a separates the positive electrode and the negative electrode, and an electrolyte in communication with the positive electrode and the negative electrode. The present invention also includes a method of preparing a freshly prepared anode and a method of operating a secondary battery including the anode of the invention.Type: ApplicationFiled: January 16, 2004Publication date: July 29, 2004Inventors: Yuan Gao, John L. Burba
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Patent number: 6706447Abstract: The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The freshly prepared anodes of the invention are combined with a positive electrode including an active material, a separator that a separates the positive electrode and the negative electrode, and an electrolyte in communication with the positive electrode and the negative electrode. The present invention also includes a method of preparing a freshly prepared anode and a method of operating a secondary battery including the anode of the invention.Type: GrantFiled: December 19, 2001Date of Patent: March 16, 2004Assignee: FMC Corporation, Lithium DivisionInventors: Yuan Gao, John L. Burba, III
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Publication number: 20040002005Abstract: The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The anodes of the invention are combined with a cathode including an active material, a separator that a separates the cathode and the anode, and an electrolyte in communication with the cathode and the anode. The present invention also includes a method of preparing an anode and a method of operating a secondary battery including the anode of the invention.Type: ApplicationFiled: December 20, 2002Publication date: January 1, 2004Inventors: Yuan Gao, John L. Burba, John F. Engel, Marina V. Yakovleva
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Publication number: 20030205700Abstract: The present invention includes lithium cobalt oxides having hexagonal layered crystal structures and methods of making same. The lithium cobalt oxides of the invention have the formula LiwCo1−xAxO2+y wherein 0.96≦w≦1.05, 0≦x≦0.Type: ApplicationFiled: April 25, 2003Publication date: November 6, 2003Inventors: Yuan Gao, Marina Yakovleva, John L. Burba, John F. Engel
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Patent number: 6579475Abstract: The present invention includes lithium cobalt oxides having hexagonal layered crystal structures and methods of making same. The lithium cobalt oxides of the invention have the formula LiwCo1−xAxO2+y wherein 0.96≦w≦1.05, 0≦x≦0.05, −0.02≦y≦0.02 and A is one or more dopants. The lithium cobalt oxides of the invention preferably have a position within the principal component space defined by the relationship axi+byi≦c, wherein xi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c1; yi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c2; the vector {right arrow over (S)}i is the x-ray spectrum for the LiwCo1−xAxO2+y compound; the vectors {right arrow over (P)}c1 and {right arrow over (P)}c2 defining the principal component space are determined by measuring the x-ray powder diffraction values {right arrow over (S)}i between 15° and 120° using a 0.Type: GrantFiled: December 7, 2000Date of Patent: June 17, 2003Assignee: FMC CorporationInventors: Yuan Gao, Marina Yakovleva, John L. Burba, III, John F. Engel
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Publication number: 20020127175Abstract: The present invention includes lithium cobalt oxides having hexagonal layered crystal structures and methods of making same. The lithium cobalt oxides of the invention have the formula LiwCo1−xAxO2+y wherein 0.96≦w≦1.05, 0≦x≦0.05, −0.02≦y≦0.02 and A is one or more dopants. The lithium cobalt oxides of the invention preferably have a position within the principal component space defined by the relationship axi+byi≦c, wherein xi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c1; yi={right arrow over (S)}i&Circlesolid;{right arrow over (P)}c2; the vector {right arrow over (S)}i is the x-ray spectrum for the LiwCo1−xAxO2+y compound; the vectors {right arrow over (P)}c1 and {right arrow over (P)}c2 defining the principal component space are determined by measuring the x-ray powder diffraction values {right arrow over (S)}i between 15° and 120° using a 0.Type: ApplicationFiled: December 7, 2000Publication date: September 12, 2002Applicant: FMC CorporationInventors: Yuan Gao, Marina Yakovleva, John L. Burba, John F. Engel
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Publication number: 20020119373Abstract: The present invention is a secondary battery having a high specific capacity and good cycleability, and that can be used safely. The secondary battery is manufactured to include an anode formed from a host material capable of absorbing and desorbing lithium in an electrochemical system such as a carbonaceous material, and lithium metal dispersed in the host material. The freshly prepared anodes of the invention are combined with a positive electrode including an active material, a separator that a separates the positive electrode and the negative electrode, and an electrolyte in communication with the positive electrode and the negative electrode. The present invention also includes a method of preparing a freshly prepared anode and a method of operating a secondary battery including the anode of the invention.Type: ApplicationFiled: December 19, 2001Publication date: August 29, 2002Applicant: FMC CorporationInventors: Yuan Gao, John L. Burba
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Patent number: 6280693Abstract: The present invention is a composition comprising pellets, each of said pellets consisting essentially of an integral mass of polycrystalline material of randomly disposed crystals of hydrated alumina infused with an amount of LiX to produce LiX/Al(OH)3 having up to a mol fraction of 0.33 of LiX in the so-produced LiX/Al(OH)3, wherein LiX is at least one compound selected from the group consisting of Li hydroxide, Li halide, Li nitrate, Li sulfate, and Li bicarbonate. The present invention further includes methods of preparing the composition and methods of recovery lithium values from brine using the composition.Type: GrantFiled: September 20, 1996Date of Patent: August 28, 2001Assignee: FMC CorporationInventors: William C. Bauman, John L. Burba, III
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Patent number: 6077914Abstract: The molecular weight of a polyolefin such as polypropylene is reduced, as evidenced by lowered viscosity and increased melt flow rate, by treatment with an inorganic peroxygen selected from metal persulfates, ammonium persulfates, and any mixtures thereof. The treatment avoids or minimizes the color or odor attendant treatment with organic peroxygens and the toxic products of organic persulfate decomposition, and avoids the special handling required with organic peroxides.Type: GrantFiled: February 19, 1998Date of Patent: June 20, 2000Assignee: FMC CorporationInventors: Nancy D. Arabinick, John L. Burba, III, William O. Dalton
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Patent number: 5721198Abstract: Elastic solids having reversible stress-induced fluidity are prepared, e.g., by combining liquid formulations with a crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.multidot.a) (A.sup.n).sub.a .multidot.xH.sub.2 Owhere m is amount of Li, d is amount of divalent metal D, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, and xH.sub.2 O represents excess waters of hydration, if any. These make useful coatings.The instantly reversible fluidization of these unique elastic solids may be expressed as:.sigma.=k.sub..alpha. .epsilon. when .epsilon.<F, for the solid phase; and.sigma.=f(d.epsilon.'/dt) when .epsilon.'>F, (this equation represents a generalized form for the usual theological equations); for a cycle of .epsilon., -xF <.epsilon.<xF, and when .epsilon.' equals 0 the liquid phase changes back to the solid phase, andwhere the symbol .sigma. represents stress; k.Type: GrantFiled: August 18, 1995Date of Patent: February 24, 1998Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Christopher P. Christenson
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Patent number: 5658653Abstract: The invention provides composites of organic polymeric compositions including a matrix of an organic polymer and a filler distributed throughout the matrix, the flier being present in the matrix substantially as separate particles, each about the fundamental particle size of the filler. The fillers are unique mixed metal hydroxide compositions that are obtainable in sub-micron size particles. These particles are layered and have a BET specific surface area in excess of about 100 m.sup.2 /g. An anion of the particulates is selected to be compatible with the organic polymer thereby providing ease of dispersion of the filler particles throughout the polymer matrix.Type: GrantFiled: November 23, 1994Date of Patent: August 19, 1997Assignee: The Dow Chemical CompanyInventors: Clive P. Bosnyak, John L. Burba, III, Malcolm F. Finlayson, Arthur E. Read, Jr., Chai-Jing Chou
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Patent number: 5658859Abstract: The present invention relates to a pseudoplastic fluid composition including water, a mixed metal layered hydroxide dispersed in the water to impart preselected rheological properties to the fluid and a fluid loss additive composition including one or more of a carboxymethyl substituted vegetable starch, a carboxymethylated cellulosic compound or mixtures thereof in an amount effective to inhibit loss of fluid and with the degree of substitution being selected so that the carboxymethyl substituted compound is soluble in the fluid at the concentration of use without materially adversely affecting the rheological properties of the fluid and so that the fluid is resistant to fermentation. The improved composition includes a crosslinked carboxymethylated vegetable starch which has a degree of substitution in the broad range from about 0.3 to about 0.8 and in a narrower range of about 0.4 to about 0.Type: GrantFiled: January 30, 1996Date of Patent: August 19, 1997Assignee: Dowell Schlumberger IncorporatedInventors: John L. Burba, III, Lindsay J. Fraser
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Patent number: 5599516Abstract: Pellets of a polycrystalline hydrated alumina, especially Gibbsite, are infused with LiOH to obtain loadings up to 0.33 mol fraction of LiOH in the LiOH/Al(OH).sub.3. The so-prepared material is useful for mixing with a LiX-containing brine solution, producing an interaction of the LiOH infused in the alumina pellets with the X ion (where X represents an acid salt moiety, especially halide) of the LiX-containing brine. The LiX interaction product is efficiently removed from the alumina pellets by water washing, leaving rejuvenated LiOH which can be used in yet another cycling of LiX formation/water removal. A plurality of loading and unloading cycles are achieved, yielding an appreciable amount of the lithium values derived from the brine.Type: GrantFiled: February 13, 1995Date of Patent: February 4, 1997Assignee: FMC CorporationInventors: William C. Bauman, John L. Burba, III
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Patent number: 5481042Abstract: Described are preferred processes which produce methyl mercaptan from methyl bromide and aqueous mediums of metal hydrosulfide. The processes can be used to simultaneously consume methyl bromide byproduct and aqueous NaSH byproduct while producing methyl mercaptan.Type: GrantFiled: April 11, 1994Date of Patent: January 2, 1996Assignee: Great Lakes Chemical Corp.Inventors: John L. Burba, III, James T. Ayres, Preston E. Spires, John E. Hill
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Patent number: 5443761Abstract: Elastic solids having reversible stress-induced fluidity are prepared, e.g., by combining liquid formulations with a crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.a) (A.sup.n).sub.a.xH.sub.2 Owhere m is amount of Li, d is amount of divalent metal D, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, and xH.sub.2 O represents excess waters of hydration, if any. These make useful coatings.The instantly reversible fluidization of these unique elastic solids may be expressed as:.tau.=ka.epsilon.,When .epsilon.<F, for the solid phase; and.epsilon.=f(d.epsilon.'/dt)when .epsilon.'<F, (this equation represents a generalized form for the usual rheological equations); for a cycle of .epsilon., -xF<.epsilon.<xF, and when .epsilon.' equals 0 the liquid phase changes back to the solid phase, andwhere the symbol .sigma. represents stress; k.sub.Type: GrantFiled: October 11, 1991Date of Patent: August 22, 1995Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Christopher P. Christenson
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Patent number: 5418271Abstract: Coating formulations which behave as elastic solids having reversible stress-induced fluidity are prepared by creating a fluid having distributed therein effective amounts of ionic charge sites and countercharge sites. For instance, elastic solids having reversible stress-induced fluidity are prepared by combining liquid formulations with a dispersion of a small, but effective, amount of at least one crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.multidot.a) (A.sup.n).sub.a .multidot.xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n and a is the amount of A, where n is 1 or more, (m+2d+3+n.multidot.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration, if any.Type: GrantFiled: October 11, 1991Date of Patent: May 23, 1995Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Peter A. Doty, Christopher P. Christenson, Susan K. Falcone, Andrea H. Hazlitt, Thomas M. Knobel, Wilfred C. Meyer, Arthur E. Read, Jr., Edgar F. Hoy, Avis L. McCrary, Ha Q. Pham, Stanley F. Simpson, Steve A. Sims, Betty J. Smith
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Patent number: 5389349Abstract: Morphologically altered pellets of a polycrystalline hydrated alumina, intercalated with LiX (where LiX is a lithium salt, preferably LiCl), is prepared by contacting the polycrystalline structure with LiX solution carried in NaCl brine, the LiX creating lithium-specific sites of intercalation in the crystalline structure, and the material is used in a LiX absorption process involving unloading LiX from the pellets, and then passing a LiX-containing brine through the pellets to capture more LiX in the Li-depleted active sites, and repeating the unloading and loading of the LiX a plurality of cycles. The unloaded LiX is collected as crude product which can be concentrated by evaporation and removing precipitated NaCl.Type: GrantFiled: May 24, 1993Date of Patent: February 14, 1995Inventors: William C. Bauman, John L. Burba, III
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Patent number: 5308547Abstract: Novel compositions useful as fluid gelling agents, especially for use in subterranean applications such as drilling fluids, are prepared by reacting an aqueous dispersion of a clay, such as bentonite, with an aqueous gel of a monodispersed mixed metal layered hydroxide of the formula Li.sub.m D.sub.d T(OH).sub.(m+2d+3+na) A.sub.a.sup.n, where D is a divalent metal, such as Mg, T is a trivalent metal, such as Al, and A represents other monovalent or polyvalent anions, the formula being described in detail in the disclosure.Type: GrantFiled: November 15, 1991Date of Patent: May 3, 1994Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Audrey L. Barnes
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Patent number: 5232627Abstract: Adducts of clay, especially of the smectite variety, most especially bentonite, are prepared with an effective amount of at least one activated mixed metal oxide or oxy-hydroxide (AHMMO) formed by dehydrating hydrotalcite or a mixture comprising magnesium oxide and aluminum oxide, or a crystalline mixed metal hydroxide conforming substantially to the formulaLi.sub.m D.sub.d T(OH).sub.(m+2d+3+n.a) (A.sup.n).sub.a. xH.sub.2 Owhere m is zero to one, D is a divalent metal, d is from zero to 4, T is a trivalent metal, A represents at least one anion or negative-valence radical of valence n, where n is 1 or more, (m+2d+3+n.a) is equal to or greater than 3, (m+d) is greater than zero, and xH.sub.2 O represents excess waters of hydration. These adducts are useful, e.g., in drilling muds and in viscosity modification of a wide variety of fluids.Type: GrantFiled: April 16, 1991Date of Patent: August 3, 1993Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Arthur E. Read, Jr., Edgar F. Hoy
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Patent number: 5196143Abstract: Novel compositions useful as fluid gelling agents, especially for use in subterranean applications such as drilling fluids, are prepared by reacting an aqueous dispersion of a clay, such as bentonite, with an aqueous gel of a monodispersed mixed metal layered hydroxide of the formula Li.sub.m D.sub.d T(OH).sub.(m+2d+3+na) A.sup.n.sub.a.H.sub.2 O, where x is zero or more representing excess water of hydration, where D is a divalent metal, such as Mg, T is a trivalent metal, such as Al, and A represents other monovalent or polyvalent anions, the formula being described in detail in the disclosure.Type: GrantFiled: May 10, 1991Date of Patent: March 23, 1993Assignee: The Dow Chemical CompanyInventors: John L. Burba, III, Audrey L. Barnes