Patents by Inventor John L. Kubis
John L. Kubis has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9315396Abstract: Synergies in recovery of reverse osmosis (RO) membrane process reject waste and forward osmosis (FO) membrane process water extraction, using such osmotic process byproducts in applications for makeup to evaporative cooling towers, concurrent with use of specific corrosion and scale inhibition methods that permit tower water discharge reduction to approach zero blowdown. Such synergies are derived from methods for application of subsequent RO feed water and reject wastewater with pre-treatment steps, and FO process optimization steps to permit water quality and economic performance efficiencies when used as makeup to evaporative cooling systems.Type: GrantFiled: March 28, 2012Date of Patent: April 19, 2016Assignee: Water Conservation Technology International, Inc.Inventors: Dan A. Duke, John L. Kubis
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Publication number: 20120255908Abstract: Synergies in recovery of reverse osmosis (RO) membrane process reject waste and forward osmosis (FO) membrane process water extraction, using such osmotic process byproducts in applications for makeup to evaporative cooling towers, concurrent with use of specific corrosion and scale inhibition methods that permit tower water discharge reduction to approach zero blowdown. Such synergies are derived from methods for application of subsequent RO feed water and reject wastewater with pre-treatment steps, and FO process optimization steps to permit water quality and economic performance efficiencies when used as makeup to evaporative cooling systems.Type: ApplicationFiled: March 28, 2012Publication date: October 11, 2012Applicant: WATER CONSERVATION TECHNOLOGY INTERNATIONAL, INC.Inventors: DAN A. DUKE, JOHN L. KUBIS
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Patent number: 8057738Abstract: Methods for inhibiting corrosion in aqueous evaporative systems where soluble silica (SiO2) is maintained at residuals between 10 Mg/L and saturation, but more preferably maintained at greater than 300 mg/L as SiO2, to provide corrosion inhibiting silica films that protect system metals. Silica is provided by evaporation of water and subsequent concentration and transformation of silica naturally contained in source water. The methods of the present invention provide highly effective inhibition of corrosion for mild steel, copper, stainless steel, aluminum, zinc, galvanized steel and various alloys of such metals. The methods of the present invention comprise pretreatment removal of polyvalent metal ions from the makeup source water, maintenance of concentration of monovalent metal ions, and controlling pH at a minimum of 7.0 in the presence of an elevated temperature aqueous environment.Type: GrantFiled: February 18, 2009Date of Patent: November 15, 2011Assignee: Water Conservation Technology International, Inc.Inventors: Dan A. Duke, John L. Kubis
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Patent number: 7955553Abstract: A method of providing corrosion inhibition to copper, nickel, aluminum, zinc, tin, lead, beryllium, carbon steel, various alloys of such metals, and galvanized coatings in evaporative cooling water applications approaching zero liquid discharge that are specifically attacked by cooling water with residuals of corrosive chemistry or ions such as ammonia/ammonium ion, chloride, high TDS, OH?, or high pH. The method includes applying azoles inhibitors (such as TTA, BTA, etc.) at residuals of 0.25 mg/L to 200 mg/L or greater (as azoles) to the cooling water application and operating with a combination of high TDS (greater than 2500 mg/L) and high pH (greater than 9.0), while maintaining low total hardness (less than 200 mg/L as CaCO3).Type: GrantFiled: March 24, 2010Date of Patent: June 7, 2011Inventors: Dan A. Duke, John L. Kubis
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Publication number: 20100173071Abstract: A method of providing corrosion inhibition to copper, nickel, aluminum, zinc, tin, lead, beryllium, carbon steel, various alloys of such metals, and galvanized coatings in evaporative cooling water applications approaching zero liquid discharge that are specifically attacked by cooling water with residuals of corrosive chemistry or ions such as ammonia/ammonium ion, chloride, high TDS, OH?, or high pH. The method includes applying azoles inhibitors (such as TTA, BTA, etc.) at residuals of 0.25 mg/L to 200 mg/L or greater (as azoles) to the cooling water application and operating with a combination of high TDS (greater than 2500 mg/L) and high pH (greater than 9.0), while maintaining low total hardness (less than 200 mg/L as CaCO3).Type: ApplicationFiled: March 24, 2010Publication date: July 8, 2010Inventors: DAN A. DUKE, JOHN L. KUBIS
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Patent number: 7708939Abstract: A method of providing corrosion inhibition to copper, nickel, aluminum, zinc, tin, lead, beryllium, carbon steel, various alloys of such metals, and galvanized coatings in evaporative cooling water applications approaching zero liquid discharge that are specifically attacked by cooling water with residuals of corrosive chemistry or ions such as ammonia/ammonium ion, chloride, high TDS, OH?, or high pH. The method includes applying azoles inhibitors (such as TTA, BTA, etc.) at residuals of 0.25 mg/L to 200 mg/L or greater (as azoles) to the cooling water application and operating with a combination of high TDS (greater than 2500 mg/L) and high pH (greater than 9.0), while maintaining low total hardness (less than 200 mg/L as CaCO3).Type: GrantFiled: April 24, 2007Date of Patent: May 4, 2010Assignee: Water Conservation Technology International, Inc.Inventors: Dan A. Duke, John L. Kubis
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Publication number: 20090159420Abstract: Methods for inhibiting corrosion in aqueous evaporative systems where soluble silica (SiO2) is maintained at residuals between 10 Mg/L and saturation, but more preferably maintained at greater than 300 mg/L as SiO2, to provide corrosion inhibiting silica films that protect system metals. Silica is provided by evaporation of water and subsequent concentration and transformation of silica naturally contained in source water. The methods of the present invention provide highly effective inhibition of corrosion for mild steel, copper, stainless steel, aluminum, zinc, galvanized steel and various alloys of such metals. The methods of the present invention comprise pretreatment removal of polyvalent metal ions from the makeup source water, maintenance of concentration of monovalent metal ions, and controlling pH at a minimum of 7.0 in the presence of an elevated temperature aqueous environment.Type: ApplicationFiled: February 18, 2009Publication date: June 25, 2009Inventors: Dan A. Duke, John L. Kubis
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Patent number: 7517493Abstract: Methods for inhibiting corrosion in aqueous evaporative systems where soluble silica (SiO2) is maintained at residuals between 10 Mg/L and saturation, but more preferably maintained at greater than 300 mg/L as SiO2, to provide corrosion inhibiting silica films that protect system metals. Silica is provided by evaporation of water and subsequent concentration and transformation of silica naturally contained in source water. The methods of the present invention provide highly effective inhibition of corrosion for mild steel, copper, stainless steel, aluminum, zinc, galvanized steel and various alloys of such metals. The methods of the present invention comprise pretreatment removal of polyvalent metal ions from the makeup source water, maintenance of concentration of monovalent metal ions, and controlling pH at a minimum of 7.0 in the presence of an elevated temperature aqueous environment.Type: GrantFiled: March 9, 2006Date of Patent: April 14, 2009Inventors: Dan A. Duke, John L. Kubis
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Publication number: 20080264870Abstract: A method of providing corrosion inhibition to copper, nickel, aluminum, zinc, tin, lead, beryllium, carbon steel, various alloys of such metals, and galvanized coatings in evaporative cooling water applications approaching zero liquid discharge that are specifically attacked by cooling water with residuals of corrosive chemistry or ions such as ammonia/ammonium ion, chloride, high TDS, OH?, or high pH. The method includes applying azoles inhibitors (such as TTA, BTA, etc.) at residuals of 0.25 mg/L to 200 mg/L or greater (as azoles) to the cooling water application and operating with a combination of high TDS (greater than 2500 mg/L) and high pH (greater than 9.0), while maintaining low total hardness (less than 200 mg/L as CaCO3).Type: ApplicationFiled: April 24, 2007Publication date: October 30, 2008Inventors: Dan A. Duke, John L. Kubis
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Patent number: 7122148Abstract: A methods of the present invention for inhibiting silica scale formation and corrosion in aqueous systems where soluble silica residuals (SiO2) are maintained in excess of 200 mg/L, and source water silica deposition is inhibited with silica accumulations as high as 4000 mg/L (cycled accumulation) from evaporation and concentration of source water. The methods of the present invention also provides inhibition of corrosion for carbon steel at corrosion rates of less than 0.3 mpy (mils per year), and less than 0.1 mpy for copper, copper alloy, and stainless steel alloys in highly concentrated (high dissolved solids) waters. The methods of the present invention comprise pretreatment removal of hardness ions from the makeup source water, maintenance of electrical conductivity, and elevating the pH level of the aqueous environment. Thereafter, specified water chemistry residual ranges are maintained in the aqueous system to achieve inhibition of scale and corrosion.Type: GrantFiled: December 21, 2004Date of Patent: October 17, 2006Assignee: Water Conservation Technologies InternationalInventors: Dan A. Duke, John L. Kubis, John P. Wetherell
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Patent number: 6998092Abstract: A methods for inhibiting silica scale formation and corrosion in aqueous systems where soluble silica (SiO2) can be maintained at residuals below 200 mg/L, but more preferably maintained at greater than 200 mg/L as SiO2, without silica scale and with control of deposition of source water silica accumulations as high as 4000 mg/L (cycled accumulation) from evaporation and concentration of source water. The methods of the present invention also provide highly effective inhibition of corrosion for carbon steel, copper, copper alloy, and stainless steel alloys. The methods of the present invention comprise pretreatment removal of hardness ions from the makeup source water, maintenance of electrical conductivity, and elevating the pH level of the aqueous environment. Thereafter, specified water chemistry residual ranges are maintained in the aqueous system to achieve inhibition of scale and corrosion.Type: GrantFiled: December 21, 2004Date of Patent: February 14, 2006Assignee: Water Conservation Technologies InternationalInventors: Dan A. Duke, John L. Kubis
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Patent number: 6949193Abstract: A methods for inhibiting silica scale formation and corrosion in aqueous systems where soluble silica (SiO2) can be maintained at residuals below 200 mg/L, but more preferably maintained at greater than 200 mg/L as SiO2, without silica scale and with control of deposition of source water silica accumulations as high as 4000 mg/L (cycled accumulation) from evaporation and concentration of source water. The methods of the present invention also provide highly effective inhibition of corrosion for carbon steel, copper, copper alloy, and stainless steel alloys. The methods of the present invention comprise pretreatment removal of hardness ions from the makeup source water, maintenance of electrical conductivity, and elevating the pH level of the aqueous environment. Thereafter, specified water chemistry residual ranges are maintained in the aqueous system to achieve inhibition of scale and corrosion.Type: GrantFiled: March 31, 2004Date of Patent: September 27, 2005Assignee: Water & Enviro Tech Company, Inc.Inventors: Dan A. Duke, John L. Kubis
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Patent number: 6929749Abstract: A methods of the present invention for inhibiting silica scale formation and corrosion in aqueous systems where soluble silica residuals (SiO2) are maintained in excess of 200 mg/L, and source water silica deposition is inhibited with silica accumulations as high as 4000 mg/L (cycled accumulation) from evaporation and concentration of source water. The methods of the present invention also provides inhibition of corrosion for carbon steel at corrosion rates of less than 0.3 mpy (mils per year), and less than 0.1 mpy for copper, copper alloy, and stainless steel alloys in highly concentrated (high dissolved solids) waters. The methods of the present invention comprise pretreatment removal of hardness ions from the makeup source water, maintenance of electrical conductivity, and elevating the pH level of the aqueous environment. Thereafter, specified water chemistry residual ranges are maintained in the aqueous system to achieve inhibition of scale and corrosion.Type: GrantFiled: January 9, 2004Date of Patent: August 16, 2005Assignee: Water & Enviro Tech Company, Inc.Inventors: Dan A. Duke, John L. Kubis, John P. Wetherell