Patents by Inventor John Loper
John Loper has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11091613Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.Type: GrantFiled: February 8, 2019Date of Patent: August 17, 2021Assignee: AFTON CHEMICAL CORPORATIONInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Patent number: 11046908Abstract: The present disclosure relates to oxazoline modified lubricant additives that have dispersant properties and lubricating oil compositions including such dispersant lubricant additives. The disclosure also relates to the use of lubricant compositions comprising the additives of the disclosure for improving the soot or sludge handling characteristics of an engine lubricant composition while providing robust and consistent frictional performance at the same time.Type: GrantFiled: January 11, 2019Date of Patent: June 29, 2021Assignee: Afton Chemical CorporationInventors: Arturo Carranza, Sheng Jiang, John Loper
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Publication number: 20210171678Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene unit content of the copolymer is less than 80 mol %. 70 mol % or greater of the copolymer has a carbon-carbon double bond in a terminal monomer unit, and at least 70 mol % of the terminal unsaturation is vinylidene, one or more tri-substituted isomers of the vinylidene or any combination thereof. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain average ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt. % of the copolymer. The copolymers may low metal (ash) and/or fluorine contents.Type: ApplicationFiled: June 12, 2018Publication date: June 10, 2021Applicant: AFTON CHEMICAL CORPORATIONInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Patent number: 11008527Abstract: Engine oil \s and methods for use in soot-producing engines. The engine oil contains a major amount of a base oil and a dispersant reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine, that is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups of C) are attached directly to an aromatic ring. A molar ratio of carboxyl groups from components A) and C) to nitrogen atoms from component B) of from 0.9 to 1.3 is used to make the dispersant which also has a molar ratio of component C) to component B) of at least 0.4 and when component B) has an average of 4-6 nitrogen atoms per molecule, a molar ratio of A) to B) is from 1.0 to 1.6.Type: GrantFiled: January 18, 2019Date of Patent: May 18, 2021Assignee: Afton Chemical CorporationInventor: John Loper
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Publication number: 20210070900Abstract: Ethylene-C3-C10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C3-C10 alpha-olefin-derived units. The C3-C10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C3-C10 alpha-olefin-derived units may be propylene-derived units. The dispersants may be made from copolymers having low metal and/or fluorine contents.Type: ApplicationFiled: June 12, 2018Publication date: March 11, 2021Applicant: AFTON CHEMICAL CORPORATIONInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Publication number: 20200231892Abstract: Engine oil \s and methods for use in soot-producing engines. The engine oil contains a major amount of a base oil and a dispersant reaction product of A) a hydrocarbyl-dicarboxylic acid or anhydride, and B) at least one polyamine, that is post-treated with C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups of C) are attached directly to an aromatic ring. A molar ratio of carboxyl groups from components A) and C) to nitrogen atoms from component B) of from 0.9 to 1.3 is used to make the dispersant which also has a molar ratio of component C) to component B) of at least 0.4 and when component B) has an average of 4-6 nitrogen atoms per molecule, a molar ratio of A) to B) is from 1.0 to 1.6.Type: ApplicationFiled: January 18, 2019Publication date: July 23, 2020Applicant: Afton Chemical CorporationInventor: John Loper
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Publication number: 20200224117Abstract: The present disclosure relates to oxazoline modified lubricant additives that have dispersant properties and lubricating oil compositions including such dispersant lubricant additives. The disclosure also relates to the use of lubricant compositions comprising the additives of the disclosure for improving the soot or sludge handling characteristics of an engine lubricant composition while providing robust and consistent frictional performance at the same time.Type: ApplicationFiled: January 11, 2019Publication date: July 16, 2020Inventors: Arturo Carranza, Sheng Jiang, John Loper
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Publication number: 20190177651Abstract: Lubricating oil compositions including olefin copolymer dispersants comprising olefin copolymers derived from ethylene and one or more C3-C10 alpha olefins in combination with various additives and related methods are generally described herein. The compositions may include one or more phosphorus-containing compound(s), detergents, friction modifiers, extreme pressure agents, and mixtures thereof.Type: ApplicationFiled: June 12, 2018Publication date: June 13, 2019Inventors: John Loper, Nathaniel Cain, Mark Devlin
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Publication number: 20190177632Abstract: A fuel composition including a fuel and a fuel additive including a fuel soluble detergent selected from succinimide compounds of the Formula (I), Mannich detergents of the formulae (IIa), and amine detergents of the formulae (IIIa) and (IIIb). The fuel soluble detergents are derived from a specific class of ethylene-alpha olefin copolymers having an Mn of less than 5,000 g/mol, an ethylene unit content of more than 40 mol % to less than 90 mol %; a terminal unsaturation of 70 mol % or greater; at least 70 mol % of the unsaturation is terminal vinylidene, one or more tri-substituted isomers of the terminal vinylidene or any combination thereof, an average ethylene run length of less than 2.6; and wherein nC2,Actual>nC2,Statistical. Methods employing the fuel compositions for operating diesel and gasoline engines to reduce injector valve deposits, valve sticking and injector nozzle fouling, and a method for stabilizing a diesel fuel composition.Type: ApplicationFiled: June 12, 2018Publication date: June 13, 2019Applicant: AFTON CHEMICAL CORPORATIONInventors: Nathaniel Cain, Michel Nuckols, John Loper, Lawrence Cunningham, William Colucci
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Publication number: 20190177518Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The copolymers have low metal (ash) and/or fluorine contents.The ethylene content of the copolymer is less than 80 mol %. 70 mol % or greater of the copolymer has a carbon-carbon double bond in a terminal monomer unit, and at least 70 mol % of the terminal monomer units that have a carbon-carbon double bond have a terminal group selected from a vinylidene group and a tri-substituted isomer of a vinylidene group. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt. % of the copolymer as well as methods of fanctionalizing the copolymer and products made with the functionalized coploymer.Type: ApplicationFiled: February 24, 2018Publication date: June 13, 2019Applicant: Afton Chemical CorporationInventors: Nathaniel Cain, John Loper
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Publication number: 20190169334Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.Type: ApplicationFiled: February 8, 2019Publication date: June 6, 2019Applicant: Afton Chemical CorporationInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Patent number: 10221267Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.Type: GrantFiled: December 13, 2016Date of Patent: March 5, 2019Assignee: AFTON CHEMICAL CORPORATIONInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Publication number: 20180162972Abstract: A copolymer including ethylene units and units of one or more C3-10 alpha-olefins. The copolymer has a number average molecular weight of less than 5,000 g/mol, as measured by GPC. The ethylene content of the copolymer is less than 80 mol %. At least 70% of molecules of the copolymer have an unsaturated group, and at least 70% of said unsaturated groups are located in a terminal vinylidene group or a tri-substituted isomer of a terminal vinylidene group. The copolymer has a crossover temperature of ?20° C. or lower and/or a certain ethylene run length. Also disclosed are a method for making the copolymer and polyolefins plasticized with 1-40 wt % of the copolymer.Type: ApplicationFiled: December 13, 2016Publication date: June 14, 2018Applicant: Afton Chemical CorporationInventors: Nathaniel Cain, John Loper, Lawrence Cunningham, Joseph W. Roos
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Publication number: 20080051520Abstract: A novel a multi-functional polymer viscosity modifier comprising an additive reaction product obtained by reacting a first monomer comprising an alkylacrylate with a second monomer comprising an olefinic carboxylic acylating agent under conditions effective for free radical polymerization of the first and second monomers to provide a base polymer comprising an acylated alkylacrylate copolymer, and wherein the base polymer optionally may be further reacted with an amine compound to provide a multi-functional polyalkylacrylate copolymer. The base polymer has good thickening efficiency. The multi-functional polyalkylacrylate copolymer dispersant viscosity modifier has good thickening efficiency. The base polymer and the multi-functional polyalkylacrylate copolymer viscosity modifier have good thickening efficiency, low temperature properties, dispersancy, and antioxidancy properties. They also have no precipitation or sedimentation, nor cause or encourage such formations in finished fluids incorporating them.Type: ApplicationFiled: September 11, 2007Publication date: February 28, 2008Applicant: AFTON CHEMICAL CORPORATIONInventors: Sanjay Srinivasan, John Loper, Naresh Mathur, Akhilesh Duggal
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Publication number: 20080026964Abstract: A novel a multi-functional polymer viscosity modifier comprising an additive reaction product obtained by reacting a first monomer comprising an alkylacrylate with a second monomer comprising an olefinic carboxylic acylating agent under conditions effective for free radical polymerization of the first and second monomers to provide a base polymer comprising an acylated alkylacrylate copolymer, and wherein the base polymer optionally may be further reacted with an amine compound to provide a multi-functional polyalkylacrylate copolymer. The base polymer has good thickening efficiency. The multi-functional polyalkylacrylate copolymer dispersant viscosity modifier has good thickening efficiency. The base polymer and the multi-functional polyalkylacrylate copolymer viscosity modifier have good thickening efficiency, low temperature properties, dispersancy, and antioxidancy properties. They also have no precipitation or sedimentation, nor cause or encourage such formations in finished fluids incorporating them.Type: ApplicationFiled: September 11, 2007Publication date: January 31, 2008Applicant: AFTON CHEMICAL CORPORATIONInventors: Sanjay SRINIVASAN, John Loper, Naresh Mathur, Akhilesh Duggal
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Publication number: 20070142249Abstract: There is disclosed herein an additive composition including a compound of formula (III): wherein R1, R2, R3, R4, R5, R6 , R7, R8, and R9are independently selected from the group consisting of hydrogen, cyano, and hydrocarbyl groups comprising from about 1 to about 30 carbon atoms.Type: ApplicationFiled: March 9, 2006Publication date: June 21, 2007Inventors: David DeGonia, Chip Hewette, Roger Sheets, Ronald Phillips, John Loper
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Publication number: 20070111908Abstract: A fully formulated lubricating oil, lubricated surface, and lubricant additive concentrates for lubricants providing reduced sludge formation. The fully formulated lubricating oil composition has therein at least one succinimide dispersant derived from a polyalkylene compound having from about 50 to about 85% vinylidene double bonds in the compound, a metal containing detergent, at least one wear reducing agent, at least one antioxidant, and a hydrocarbon soluble titanium compound as a friction modifier. The lubricating oil composition is also substantially free of molybdenum compounds.Type: ApplicationFiled: December 15, 2006Publication date: May 17, 2007Inventors: William Lam, John Loper
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Publication number: 20060168876Abstract: A fuel composition and methods for using it for controlling deposit formation in a spark-ignition internal combustion engine, such as a direct injection engine, comprising a spark-ignition fuel, a detergent, and a deposit inhibitor compound.Type: ApplicationFiled: April 3, 2006Publication date: August 3, 2006Inventors: William Colucci, John Loper, Allen Aradi
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Publication number: 20060128571Abstract: A novel crankcase dispersant reaction product having fused therein an antioxidant moiety whereby the dispersant reaction product can function as an antioxidant while retaining at least two structural domains, one being a polar domain for association with sludge and a hydrocarbyl domain for oil solubility, so that the dispersant can function as a chemical agent to suspend sludge and prevent agglomeration of sludge precursors and soot so the latter can be readily removed from the system, such as by filtering, instead of being deleteriously deposited on internal engine components, as well as lubricant compositions incorporating such novel dispersant and, for instance, engines lubricated with such lubricant compositions.Type: ApplicationFiled: December 10, 2004Publication date: June 15, 2006Inventor: John Loper
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Publication number: 20060084584Abstract: The present disclosure relates to organic molybdenum complexes prepared by reacting a Mannich base with a source of molybdenum. The complexes may be useful in lubricating oil compositions as at least one of an antioxidant, a deposit control additive, and a friction modifier. The organic molybdenum complexes may show a reduced tendency to color finished oils.Type: ApplicationFiled: October 20, 2004Publication date: April 20, 2006Inventors: Vincent Gatto, John Loper