Abstract: Provided is an improved herbicide formulation and an improved method of treating a crop. The herbicide formulation comprises a herbicide and a volatility reduction adjuvant comprising a salt of a volatile acid and a salt of a nonvolatile acid.

Abstract: A process for treating carbon-containing material contaminated with toxic elements utilises smelting of the material in a top-submerged lancing reactor. The material has its carbon content present as elemental or free carbon. Smelting is conducted so as to form, or in the presence of, a fluid slag. In the course of smelting, free-oxygen-containing gas is injected into the slag by top-submerged injection, to combust the carbon content of the material. Volatilizable toxic elements are discharged in reactor off-gas, while non-volatilizable elements are substantially fully incorporated into the slag.

Abstract: The process provides for disposal of waste materials, including municipal waste such as garbage, industrial wastes, waste materials including rubber and plastics based materials, and ash waste from municipal waste incinerators and toxic waste incinerators. The waste is charged to a reactor, of a top-submerged lancing injector reactor system, containing a molten slag bath maintained in a turbulent condition, during charging of the waste, by top-submerged injection therein of a free-oxygen containing gas, using at least one top-submerged lance of the system. The waste is taken into the molten bath and is caused to circulate therein to a combustion/oxidation zone generated by the top-submerged injection. Constituents of the waste are subjected to free-oxygen of the injected gas in that zone and to heat energy of the slag, and thereby combusted/oxidised and/or decomposed.

Abstract: A process for smelting iron-containing source material in a reactor containing a slag bath, includes generating heating and reducing conditions in at least one reducing region of the bath by injection of fuel/reductant and oxygen-containing gas by at least one top submerged lance. The source material is fed to the reactor together with additional reductant and with flux at or adjacent the at least one reducing region so as to be subjected to smelting reduction, using coal as the additional reductant. The rates of injection of oxygen and fuel/reductant are controlled to achieve required and sufficient reducing conditions by providing the injected gas with an oxygen content from about 40% to about 100% sufficient for a degree of combustion of the fuel/reductant of from about 40% to about 50%. The CO and H.sub.

Abstract: The top-submergable injection lance has an elongate conduit which extends between upper and discharge ends and defines a bore, for the supply of reactants, through the conduit and an annular, alloy steel tip at the discharge end. The conduit comprises an inner pipe defining the bore, an outer pipe, and a third pipe which divides an annular volume between the inner and an outer pipes for circulation of coolant fluid. The tip is defined by inner and outer peripheral surfaces merging at a sharp lower edge and a top surface extending between the peripheral surfaces. The top surface of the tip joins the inner and outer pipes so as to be contactable by the coolant fluid. The frusto-conical inner peripheral surface provides a continuation of the bore which increases in cross-section to an opening at the lower edge.

Abstract: A process for smelting metallurgical waste material containing at least one iron compound, at lest one heavy metal, and at least one toxic element. The waste material and a reductant are introduced into a furnace. Heat is applied to the waste material and to the reductant to form a melt under reducing conditions whereby volatilization of the heavy metal occurs and a matte or speiss is formed in which the toxic element is stabilized. Fuel and an oxidizing gas are introduced into the melt by submerged injection to create a submerged oxidizing region. The melt is circulated to the submerged oxidizing region and is oxidized causing volatilization of the toxic element stabilized in the matte or speiss.

Abstract: A lance comprising a first elongate tube extending through an elongate tubular shroud, is used for top submerged injection of a fluid into a liquid pyrometallurgical bath comprising slag or having slag on its surface. The first tube defines a duct for the flow of the fluids. The shroud defines a flow passage for a coolant such as air. The shroud terminates above the lower end portion of the first tube. In use, the coolant cools the lance and discharges into the bath when the outlet of the first tube is inserted into the bath.

Abstract: Lead is obtained from lead sulfide ores or concentrates without prior sintering or roasting by the steps of adding the lead sulfide to a molten slag, injecting sufficient oxide to below the surface of the molten slag and vigorously agitating the slag whereby substantially to oxidize the lead sulfides to lead oxides, and then reducing the lead oxides. The slag is preferably agitated by means of a lance. The reduction stage may follow the oxidation stage in the same vessel or may be conducted in another vessel.

Abstract: A method of injecting gas into a pyrometallurgical bath is disclosed, wherein the gas is injected through a lance having an interior duct for flow of gas therethrough and a discharge end at which the gas is discharged characterized by the steps of presenting the discharge end of the lance to a molten mass of slag and forcing gas through the lance to splash-coat the discharge end of the lance with molten slag and inserting the thus coated discharge end of the lance into the pyrometallurgical bath. Also disclosed is a lance for submerged injection of gas into a liquid pyrometallurgical bath comprising a duct for flow of gas longitudinally through the lance characterized in that the outer wall of the duct is defined by an elongate tube constituting an outer wall of the lance and there is gas flow swirler means within the tube to impart swirl to gas passed through the duct.