Patents by Inventor John M. Zimmerman

John M. Zimmerman has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160362579
    Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.
    Type: Application
    Filed: December 13, 2013
    Publication date: December 15, 2016
    Applicant: DSM IP ASSETS B.V.
    Inventors: Steven Robert SCHMID, Petrus Jacobus Hubertus NIELS, Paulus Antonio Maria STEEMAN, Xiaosong WU, Wendell Wayne CATTRON, Tyson Dean NORLIN, Edward Joseph MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20160326398
    Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The radiation curable coating comprises at least one (meth)acrylate functional oligomer and a photoinitiator, wherein the urethane-(meth)acrylate oligomer CA/CR comprises (meth)acrylate groups, at least one polyol backbone and urethane groups, wherein about 15% or more of the urethane groups are derived from one or both of 2,4- and 2,6-toluene diisocyanate, wherein at least 15% of the urethane groups are derived from a cyclic or branched aliphatic isocyanate, and wherein said (meth)acrylate functional oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of the radiation curable Primary Coating composition has a modulus of less than or equal to about 1.2 MPa.
    Type: Application
    Filed: May 5, 2015
    Publication date: November 10, 2016
    Inventors: Paulus Antonius Maria STEEMAN, Xiaosong WU, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20150050000
    Abstract: A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Omega Oligomer; and ?) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of ?1) a hydroxyl-containing (meth)acrylate; ?2) an isocyanate; ?3) a polyether polyol; and ?4) tripropylene glycol; in the presence of ?5) a polymerization inhibitor; and ?6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylh
    Type: Application
    Filed: December 13, 2013
    Publication date: February 19, 2015
    Inventors: Wendell Wayne CATTRON, Steven R. SCHMID, Edward J MURPHY, John M ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140226943
    Abstract: A wet-on-dry process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying radiation to effect curing of said radiation curable Primary Coating composition; (d) applying a secondary coating to the Primary Coating; and (e) applying radiation to effect curing of said secondary coating. Also, a wet-on-wet process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying a secondary coating to the Primary Coating; and (d) applying radiation to effect curing of the Primary Coating and the secondary coating.
    Type: Application
    Filed: December 12, 2013
    Publication date: August 14, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Xiaosong Dean WU, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140126866
    Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. A radiation curable Primary Coating composition comprising: an oligomer; a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said catalyst is an organo bismuth catalyst; wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of said radiation curable coating composition has a peak tan delta Tg of from about ?25° C. to about ?45° C.; and a modulus of from about 0.50 MPa to about 1.2 MPa.
    Type: Application
    Filed: December 13, 2013
    Publication date: May 8, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Xiaosong Dean WU, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140126868
    Abstract: A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Alpha Oligomer, which is non-urethane; (?) a Beta Oligomer; which is a urethane or non-urethane. ?) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.
    Type: Application
    Filed: December 13, 2013
    Publication date: May 8, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Wendell Wayne CATTRON, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140126867
    Abstract: A wet-on-dry process for coating a glass optical fiber with a Radiation Curable Secondary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable primary coating composition onto the surface of the optical fiber; (c) applying radiation to effect curing of said radiation curable primary coating composition; (d) applying a Radiation Curable Secondary Coating to the radiation curable primary coating; and (e) applying radiation to effect curing of said Radiation Curable Secondary Coating.
    Type: Application
    Filed: December 13, 2013
    Publication date: May 8, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Wendell Wayne CATTRON, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140127506
    Abstract: A wet-on-dry process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying radiation to effect curing of said radiation curable Primary Coating composition; (d) applying a secondary coating to the Primary Coating; and (e) applying radiation to effect curing of said secondary coating. Also, a wet-on-wet process for coating a glass optical fiber with a radiation curable Primary Coating, comprising (a) operating a glass drawing tower to produce a glass optical fiber; (b) applying a radiation curable Primary Coating composition onto the surface of the optical fiber; (c) applying a secondary coating to the Primary Coating; and (d) applying radiation to effect curing of the Primary Coating and the secondary coating.
    Type: Application
    Filed: December 13, 2013
    Publication date: May 8, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Tyson Dean NORLIN, Steven R SCHMID, Edward J MURPHY, John M ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140106082
    Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Wendell Wayne CATTRON, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140105555
    Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes to coat the optical fiber are described and claimed. The radiation curable coating is a radiation curable Primary Coating composition comprising: an oligomer; a first diluent monomer; a second diluent monomer, a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, and wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; wherein a cured film of said radiation curable primary coating composition has a peak tan delta Tg of from about ?25° C. to about ?45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.
    Type: Application
    Filed: December 13, 2013
    Publication date: April 17, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Xiaosong Dean WU, Steven R. SCHMID, Edward J MURPHY, John M ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20140099063
    Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The radiation curable coating comprises at least one (meth)acrylate functional oligomer and a photoinitiator, wherein the urethane-(meth)acrylate oligomer CA/CR comprises (meth)acrylate groups, at least one polyol backbone and urethane groups, wherein about 15% or more of the urethane groups are derived from one or both of 2,4- and 2,6-toluene diisocyanate, wherein at least 15% of the urethane groups are derived from a cyclic or branched aliphatic isocyanate, and wherein said (meth)acrylate functional oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of the radiation curable Primary Coating composition has a modulus of less than or equal to about 1.2 MPa.
    Type: Application
    Filed: December 12, 2013
    Publication date: April 10, 2014
    Applicant: DSM IP ASSETS B.V.
    Inventors: Paulus Antonius Maria STEEMAN, Xiaosong WU, Steven R. SCHMID, Edward J. MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Publication number: 20130236709
    Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.
    Type: Application
    Filed: April 22, 2013
    Publication date: September 12, 2013
    Applicant: DSM IP ASSETS B.V.
    Inventors: Steven Robert SCHMID, Petrus Jacobus Hubertus NIELS, Paulus Antonio Maria STEEMAN, Xiaosong WU, Wendell Wayne CATTRON, Tyson Dean NORLIN, Edward Joseph MURPHY, John M. ZIMMERMAN, Anthony Joseph TORTORELLO
  • Patent number: 8426021
    Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.
    Type: Grant
    Filed: September 15, 2011
    Date of Patent: April 23, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Wendell Wayne Cattron, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Patent number: 8426020
    Abstract: The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%; B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; and C) a Tube Tg, of from about ?25° C. to about ?55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: April 23, 2013
    Assignee: DSM IP Assets B.V.
    Inventors: Steven R. Schmid, Petrus Jacobus Hubertus Niels, Paulus Antonius Maria Steeman, Xiaosong Wu, Wendell Wayne Cattron, Tyson Dean Norlin, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Publication number: 20120003474
    Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.
    Type: Application
    Filed: September 15, 2011
    Publication date: January 5, 2012
    Inventors: Wendell Wayne Cattron, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Publication number: 20100274276
    Abstract: An occlusion system, method, and apparatus which treats an aneurysm in a primary vessel such as an intracranial vessel. Aneurysm types treatable by means of this invention include bulge (sometimes referred to as a true aneurysm), dissecting aneurysms in which the layers of vessel wall are partially delaminated, and what are referred to a “false” aneurysm defined by a relatively small opening in the parent vessel wall fluridically coupled to a bulb-shaped sac, also defined by the vessel wall. The system includes an occlusion device configured for deployment in the parent vessel that restricts fluid flow to the aneurysm. A patch on the device covers the neck of the aneurysm. The system includes a marker in a defined relationship with the patch, which allows for axial and rotational positioning of the device.
    Type: Application
    Filed: April 22, 2009
    Publication date: October 28, 2010
    Inventors: Ricky Chow, John Schreiner, William K. Durfee, John M. Zimmerman
  • Publication number: 20100228150
    Abstract: A guide wire having dual coil on core configuration. The guide wire has a core wire with distal and proximal ends or segments wherein two coils are tandomly disposed on its distal end. The more proximally-disposed of the distal coils is multifilar having from 4 to 15 filars all wound in one direction. The multifilar coil comprises a super elastic material. The more distal of the distally-disposed coils comprises a radiopaque material, the core wire terminating with an atraumatic tip. A guide wire of this invention is particularly well suited to navigation of the neuroanatomy.
    Type: Application
    Filed: March 5, 2009
    Publication date: September 9, 2010
    Applicant: LAKE REGION MEDICAL, INC.
    Inventors: John M. Zimmerman, Bradley D. Seibert
  • Publication number: 20080241535
    Abstract: The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.
    Type: Application
    Filed: December 13, 2007
    Publication date: October 2, 2008
    Inventors: Wendell Wayne CATTRON, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Publication number: 20080233397
    Abstract: A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Alpha Oligomer, which is non-urethane; ?) a Beta Oligomer; which is a urethane or non-urethane. ?) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.
    Type: Application
    Filed: December 13, 2007
    Publication date: September 25, 2008
    Inventors: Wendell Wayne Cattron, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
  • Publication number: 20080226913
    Abstract: A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Omega Oligomer; and ?) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of ?1) a hydroxyl-containing (meth)acrylate; ?2) an isocyanate; ?3) a polyether polyol; and ?4) tripropylene glycol; in the presence of ?5) a polymerization inhibitor; and ?6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylh
    Type: Application
    Filed: December 13, 2007
    Publication date: September 18, 2008
    Inventors: Wendell Wayne Cattron, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello