Abstract: A nanocomposite comprising at least one elastomer and at least one nanofiller. The elastomer comprises units derived from isoolefins having from 4 to 7 carbon atoms and at least one multiolefin. The nanofiller comprise a layered filler and an amine modifier wherein the nanofiller is substantially free of any unassociated amines. By eliminating unassociated amines in the nanofiller, prior to contact with the elastomer, the nanocomposite has improved processability characteristics while maintaining desired impermeability characteristics.

Abstract: A nanocomposite comprising at least one elastomer and at least one nanofiller. The elastomer comprises units derived from isoolefins having from 4 to 7 carbon atoms and at least one multiolefin. The nanofiller comprise a layered filler and an amine modifier wherein the nanofiller is substantially free of any unassociated amines. By eliminating unassociated amines in the nanofiller, prior to contact with the elastomer, the nanocomposite has improved processability characteristics while maintaining desired impermeability characteristics.

Abstract: A copolymer is formed from an isoolefin having from 4 to 7 carbon atoms and an alkylstyrene. The copolymer has a substantially homogeneous compositional distribution. The copolymer has from about 8 to about 12 wt % of alkylstyrene and at least 85 wt % of isoolefin. The copolymer is preferably halogenated with about 1.1 to about 1.5 wt % of a halogen. The copolymer may in elastomeric nanocomposites. To obtain a good dispersion of the nanoclay in a formulated compound, at least one cure accelerator is selected from the group consisting of mercaptobenzothiazole disulfide, mercaptobenzothiazole, cyclohexyl benzothiazole disulfide, dibutyl thiourea, tetramethylthiuram disulfide, 4-4-dithiodimropholine, zinc dimethyldithiocarbamate, and zinc dibutylphosphorodithiate.

Abstract: The invention relates to a new catalyst system that improves the heat transfer capability of a butyl reactor slurry process system in the production of isobutylene-based polymers in continuous slurry polymerization processes. The process is carried out in an anhydrous polymerization system containing a mixture of the monomers in a polar diluent along with a Lewis acid and a C5 or greater initiator having a tertiary halide.

Abstract: The invention relates to a new catalyst system that improves the heat transfer capability of a butyl reactor slurry process system in the production of isobutylene-based polymers in continuous slurry polymerization processes. The process is carried out in an anhydrous polymerization system containing a mixture of the monomers in a polar diluent along with a Lewis acid and a C5 or greater initiator having a tertiary halide.