Abstract: A method for making an improved pressure sensitive adhesive coated laminate is disclosed. The method involves coating a sheet having a release surface thereon with a pressure sensitive adhesive to form a laminate, drying or curing the pressure sensitive adhesive and marrying the laminate to the inner surface of a facing layer. A material comprising a mixture of substantially water-insoluble and adhesive incompatible polysiloxane (i) and water soluble and adhesive compatible polysiloxane (ii) is included so as to produce a low zero-minute peel value in the pressure sensitive adhesive layer and is intimately mixed with the pressure sensitive adhesive prior to the adhesive being coated on the release surface of the sheet. The resulting laminate can be easily applied to a substrate and removed and repositioned or straightened, if necessary, and provides a superior increase in peel value over a period of time to produce a more permanent installation.

Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.

Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.

Abstract: An improved self-wound roll of a pressure sensitive adhesive coated laminate comprising a substrate which becomes dimensionally-unstable under normal processing conditions, e.g., printing, at least one layer comprising a continuous film of a normally dimensionally stable polymer adhesively fixed to one or both sides of the substrate thereby stabilizing it during processing, a transparent flexible release layer of a resin on the outwardly facing surface of the laminate, and a layer of a modified pressure sensitive adhesive on the inwardly facing surface of the substrate. The laminate can be processed without distortion, wound into rolls, unwound and applied to a surface to be decorated without delamination or shrinkage and without distortion of printed indicia, and it ultimately can be stripped without damage to the surface.

Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.

Abstract: This invention provides graffiti removers for removing permanent ink stains from painted surfaces. This graffiti removers include an active solvent for dissolving the stains, which are organic in nature, an optional secondary solvent for concentrated attack on the stain without being adversely affected by dilution with water, an emollient for maintaining a uniform dispersion of particulates in the remover and on the graffiti-stained painted surfaces, and an amorphous, particulate, mildly abrasive filler for imbiding the solvents, the filler being selected to permit the slow release of the active solvent.

Abstract: A transfer composite for in-mold decoration of molded plastic or rubber articles complexing a casting substrate having a controlled release surface, and a thin discontinuously printed pressure sensitive adhesive tape-strippable pattern deposited on the casting substrate, whereby the transfer composite is suitable for inserting into a mold and adapted to resist print-distorting movement during flow of plastics or rubbers in the mold, yet capable of permanently bonding to the molded article without the use of adhesives. After removal from the mold the casting substrate and the controlled release surface are stripped from the decorated article.

Abstract: This invention provides graffiti removers for removing permanent ink stains from painted surfaces. The graffiti removers include an active solvent for dissolving the stains, which are organic in nature, an optional secondary solvent for concentrated attack on the stain without being adversely affected by dilution with water, an emollient for maintaining a uniform dispersion of particulates in the remover and on the graffiti-stained painted surfaces, and an amorphous, particulate, mildly abrasive filler for imbibing the solvents, the filler being selected to permit the slow release of the active solvent.

Abstract: A modified coating composition including a water based coating and a silicone component comprising 2 to 12 weight percent of the composition. The water based coating is preferably an acrylic latex paint. Preferably a filler is also included in the composition. The coating provides a sacrificial characteristic wherein layers may be removed with a stain or mark, leaving the coated surface looking new, using no more than soap and water.

Abstract: A pressure sensitive dry transfer article comprising a backing film, a release coating applied to a first face of the backing film, a continuous film of brittle polymeric compound applied to the release coating, and a pigmented pressure sensitive adhesive coating applied in imagewise fashion to said polymeric film to form a graphic pattern. On application of the article to the bonding substrate by pressure applied to the areas defined by the graphic pattern, the pigmented pressure sensitive adhesive is transferred to the bonding substrate and, after peeling the article away from the bonding substrate, the polymeric film fractures along the borders defining the graphic pattern such that the polymeric film in union with the graphic pattern is transferred with the pressure sensitive adhesive to the bonding substrate and the polymeric film not in union with the graphic pattern remains with the release coating.

Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.

Abstract: A transfer composite for in-mold decoration of molded plastic or rubber articles comprising a casting substrate having a controlled release surface, and a thin discontinuously printed pressure sensitive adhesive tape-strippable pattern deposited on the casting substrate, whereby the transfer composite is suitable for inserting into a mold and adapted to resist print-distorting movement during flow of plastics or rubbers in the mold, yet capable of permanently bonding to the molded article without the use of adhesives. After removal from the mold the casting substrate and the controlled release surface are stripped from the decorated article.