Abstract: A method of preparing an organosilicon compound having at least one silicon-bonded carbinol group and/or at least one silanol group with a cytochrome P450 variant that facilitates the oxidization of a silicon-bonded hydrocarbyl group in the presence of an oxidant. The method includes combining the cytochrome P450 variant, an initial organosilicon compound having at least one silicon-bonded hydrocarbyl group, and a cofactor to give a reaction mixture, and exposing the reaction mixture to an oxidant to oxidize the silicon-bonded hydrocarbyl group of the initial organosilicon compound, thereby preparing the organosilicon compound having at least one silicon-bonded carbinol group and/or at least one silanol group. Cytochrome P450 variants suitable for use in the method are also disclosed, along with methods for engineering and optimizing the same. Nucleic acids encoding the cytochrome P450 variants and compositions, expression vectors, and host cells including the same are also disclosed.

Abstract: This relates to a process for the preparation of siloxane polymers and copolymers, made by acid (cationic) catalysed ring-opening polymerisation of macrocyclic cyclosiloxane oligomers having from seven to ten siloxane units per macrocyclic cyclosiloxane oligomers. It also relates to the siloxane polymers and copolymers, made by the process and their uses.

Abstract: This relates to a process for the polymerisation of siloxane polymers and copolymers, made by base catalysed ring-opening polymerisation of cyclosiloxane oligomers having six siloxane units per ring, using a sodium silanolate catalyst. It also relates to the siloxane polymers and copolymers, made by the process and their uses.

Abstract: This relates to a process for the polymerisation of siloxane polymers and copolymers, made by base catalysed ring-opening polymerisation of macrocyclic cyclosiloxane oligomers having from seven to ten siloxane units per macrocyclic cyclosiloxane oligomer. It also relates to the siloxane polymers and copolymers, made by the process and their uses.

Abstract: A method of preparing a multifunctional organosilicon compound is provided. The method comprises reacting (A) an organosilanol compound comprising a functional moiety selected from alkoxysilyl moieties and acryloxy moieties and (B) a hydridosilane compound having at least two hydrolysable groups in the presence of (C) an acetate salt. A multifunctional organosilicon compound prepared according to the method is also provided.

Abstract: Embodiments of the present disclosure are directed towards a method of preparing a silanol-functional polyolefin that includes combining, under thermal conditions to effect synthesis of a silanol moiety, starting materials comprising A) a silyl hydride-functionalized polyolefin, optionally B) a solvent, C) a peroxy acid, optionally D) a neutralizing agent thereby forming a reaction mixture that under the thermal conditions produces the silanol-functional polyolefin having the silanol moiety.

Abstract: A method for preparing a silanol-functional organosilicon compound from a silyl hydride and an oxidant is provided. The oxidant includes peroxyacetic acid.

Abstract: Disclosed herein are system, apparatus, article of manufacture, method and/or computer program product embodiments, and/or combinations and sub-combinations thereof, for an application pre-launch system. An example embodiment operates by detecting a user interaction associated with launching an app configured to operate on a computing device. A first launch command is provided to a server associated with the app. The first launch command is configured to instruct the server to begin loading application data for the app into a cache. Application code of the app is executed, wherein the application code is configured to provide a second launch command to the server. The application data is received from the cache responsive to the second launch command. The app is launched on the computing device using the application data received from the cache. After the launching, the app is configured to receive a user command.

Abstract: Computer implemented systems and methods for providing dynamic lighting through lighting fixtures are provided herein. In one aspect, one or more characteristics of light provided from a lighting fixture or a plurality of lighting fixtures changes over time to shape the environment of an indoor space according to simulated environment illumination parameters and general illumination parameters. Dynamic lighting may improve the health or wellbeing of individuals in an indoor space, for example, by simulating an outdoor environment to reduce stress, by providing circadian entrainment to improve sleep and wakefulness, or the like. Other aspects of the present disclosure enable lighting fixtures to provide light that is synchronized with one or more other devices that simulate an environment and shape the environment of an indoor space.

Abstract: A method for performing magnetic resonance-guided thermal therapy includes selecting a first set of sampling characteristics for acquiring a first set of slabs covering a first anatomical region of interest. Additionally, a second set of sampling characteristics is selected for acquiring a second set of slabs covering a second anatomical region of interest. This second set of sampling characteristics is distinct from the first set of sampling characteristics. An interleaved acquisition of the first set of slabs and the second set of slabs may then be performed using the first set of sampling characteristics and the second set of sampling characteristics.

Abstract: A method that can be used for preparing a poly(dimethyl/methylvinyl) siloxane copolymer is provided. The method includes use of Raman spectroscopy.

Abstract: A multifunctional organosilicon compound is provided which has the general formula XSi([OSiR2]p-0-SiR2Y)a(R1)3-a— ln the formula, X is selected from H and ethylenically un saturated moieties; each Y independently comprises a functional moiety selected from alkoxysilyl moieties, acryloxy moieties, and epoxide moieties; each R is an independently selected hydrocarbyl group; each R1 is an independently selected hydrocarbyl group; subscript a is 1, 2, or 3; and each subscript b is independently 0, 1, or 2. A method of preparing the multifunctional organosilicon compound is also provided. The method comprises reacting (A) an organosilanol compound and (B) a silane compound having at least two hydrolysable groups. A functionalized siloxane compound prepared from the multifunctional organosilicon compound, a method of preparing the functionalized siloxane compound, and an adhesive comprising the functionalized siloxane compound are also provided.

Abstract: A branched organosilanol compound and method for its preparation are provided. The branched organosilanol compound may be used as a starting material in a method for preparing a functionalized polymer.

Abstract: A method of preparing an organosilanol compound is disclosed. The method comprises reacting (A) an initial organosilicon compound and (B) water in the presence of (C) a catalyst. The catalyst (C) is selected from: (C1) [(C8H12irCl]2[(p-cymene)RuCl2]2; and (C3) Pd/C. The initial organosilicon compound (A) has the general formula HO—Si(R)2—[Si(R)2O]a—OSi(R)2—Y and the organosilanol compound has the general formula HO—Si(R)2-[Si(R)2O]a—OSi(R)2—Y, where each R is an independently selected hydrocarbyl group; Y comprises a functional moiety selected from alkoxysilyl moieties, epoxide moieties, and acryloxy moieties, with the proviso that Y is other than the acryloxy moieties when the catalyst (C) is (C3) Pd/C; and subscript a is 0 or 1. The organosilanol compound prepared by the method is also provided.

Abstract: This disclosure provides a method of preparing a silanol-functional organosilicon compound with a cytochrome P450 variant that facilitates the oxidization of a silyl hydride group to a silanol group in the presence of oxygen. The method includes combining the cytochrome P450 variant and an organosilicon compound having at least one silicon-bonded hydrogen atom to give a reaction mixture and exposing the reaction mixture to oxygen to oxidize the organosilicon compound, thereby preparing the silanol-functional organosilicon compound. Cytochrome P450 variants suitable for use in the method are also disclosed, along with methods for engineering and optimizing the same. Nucleic acids encoding the cytochrome P450 variants and compositions, expression vectors, and host cells including the same are also disclosed.

Abstract: Disclosed herein are system, apparatus, article of manufacture, method and/or computer program product embodiments, and/or combinations and sub-combinations thereof, for display dynamic splash screens using a media device during a launch sequence of an application without interrupting or delaying processing of the launch sequence. A launch sequence may be considered to include operations for compiling code associated with the application and operations for displaying splash screens. An example embodiment operates by the media device launching the application responsive to receiving a request and while code for the application is being compiled, selecting and displaying a dynamic splash screen. Operations of compiling code and displaying the splash screen may be performed under the control of the media device operating system and control is passed from the operating system to the application after launch sequence is completed.

Abstract: Disclosed herein are system, apparatus, article of manufacture, method and/or computer program product embodiments, and/or combinations and sub-combinations thereof, for operating a user application including a user rendered context operating on a user device and maintaining a current render tree, and a user programmer context operating on a cloud computing system. The user rendered context of the user application can receive an input; and send, responsive to receiving the input, an event notification to the user programmer context of the user application. The user rendered context can further receive, from the user programmer context, a difference tree to update the current render tree, and update the current render tree based on the difference tree.

Abstract: Disclosed herein are system, apparatus, article of manufacture, method and/or computer program product embodiments, and/or combinations and sub-combinations thereof, for display dynamic splash screens using a media device during a launch sequence of an application without interrupting or delaying processing of the launch sequence. A launch sequence may be considered to include operations for compiling code associated with the application and operations for displaying splash screens. An example embodiment operates by the media device launching the application responsive to receiving a request and while code for the application is being compiled, selecting and displaying a dynamic splash screen. Operations of compiling code and displaying the splash screen may be performed under the control of the media device operating system and control is passed from the operating system to the application after launch sequence is completed.

Abstract: Disclosed herein are system, apparatus, article of manufacture, method and/or computer program product embodiments, and/or combinations and sub-combinations thereof, for operating a user application including a user rendered context operating on a user device and maintaining a current render tree, and a user programmer context operating on a cloud computing system. The user rendered context of the user application can receive an input; and send, responsive to receiving the input, an event notification to the user programmer context of the user application. The user rendered context can further receive, from the user programmer context, a difference tree to update the current render tree, and update the current render tree based on the difference tree.

Abstract: A cooling assembly includes an evaporator containing a primary cooling medium, a passive condenser, and a heat exchanger. When a secondary cooling medium is provided to the heat exchanger, the primary cooling medium in the gas phase switches from being received by the passive condenser to the heat exchanger without operating any valves located between the evaporator and the passive condenser and between the evaporator and the heat exchanger. The primary cooling medium circulates between the evaporator and the passive condenser and between the evaporator and the heat exchanger by natural circulation and gravity without a pump in the flow path of the primary cooling medium between the heat exchanger and the evaporator and between the passive condenser and the evaporator to circulate the primary cooling medium.