Abstract: An electrochemical cell is formed. The cell includes a non-lithium negative electrode in contact with a lithium ion permeable negative electrode current collector, and a positive electrode disposed in contact with a lithium ion permeable positive electrode current collector. The non-lithium negative electrode and the positive electrode are lithium ion permeable. The cell also has a lithium source electrode including lithium ions. A respective microporous polymer separator is disposed between the lithium source electrode and each of the negative and positive electrodes; or a first separator is disposed between the lithium source electrode and one of the negative and positive electrodes, and a second separator is disposed between the negative and positive electrodes. An electrolyte is introduced into the electrochemical cell.

Abstract: Methods, systems, and apparatuses, including electrical circuitry, are described for auto-negotiation. Active cables, active backplanes, and line cards may include one or more instances of electrical circuitry and/or integrated circuits that intercept advertisements of standard auto-negotiation protocol signaling from an initiating device for establishment of communication links with a receiving device. Auto negotiation information in the intercepted signaling may be translated and encoded into signaling in accordance with the capabilities of the receiving device. Active cables and active backplanes may also include one or more connection components between instances of electrical circuitry and/or integrated circuits to provide high-speed transmission of data packets encapsulating the auto-negotiation information in a format that differs from the standard auto-negotiation protocol.

Abstract: Methods, systems, and apparatuses, including electrical circuitry, are described for auto-negotiation. Active cables, active backplanes, and line cards may include one or more instances of electrical circuitry and/or integrated circuits that intercept advertisements of standard auto-negotiation protocol signaling from an initiating device for establishment of communication links with a receiving device. Auto negotiation information in the intercepted signaling may be translated and encoded into signaling in accordance with the capabilities of the receiving device. Active cables and active backplanes may also include one or more connection components between instances of electrical circuitry and/or integrated circuits to provide high-speed transmission of data packets encapsulating the auto-negotiation information in a format that differs from the standard auto-negotiation protocol.

Abstract: An electroactive material for use in an electrochemical cell, like a lithium ion battery, is provided. The electroactive material comprises a multifunctional hybrid protective coating system formed over an electroactive material. The coating system includes a first oxide-based coating disposed on one or more surfaces of the electroactive material, followed by a second coating deposited via a non-aqueous process. The second coating may be a fluoride-based, nitride-based, or carbide-based coating. The first and second coatings may be applied by atomic layer deposition (ALD) to form conformal ultrathin layers over the electroactive materials. Such a multifunctional hybrid protective coating system can suppress formation of gases within the electrochemical cell and also minimize formation of solid electrolyte interface (SEI) layers on the electrode to improve battery performance. Methods for making such materials and using such materials in electrochemical cells are likewise provided.

Abstract: Methods and apparatuses are described for timing skew mitigation in time-interleaved ADCs (TI-ADCs) that may be performed for any receive signal without any special signals during blind initialization, which may be followed by background calibration. The same gain/skew calibration metrics may be applied to baud sampled and oversampled systems, including wideband receivers and regardless of any modulation, by applying a timing or frequency offset to non-stationary sampled signals during initial training. Skew mitigation is low latency, low power, low area, noise tolerant and scalable. Digital estimation may be implemented with accumulators and multipliers while analog calibration may be implemented with adjustable delays. DC and gain offsets may be calibrated before skew calibration. The slope of the correlation function between adjacent samples may be used to move a timing skew estimate stochastically at a low adaptive rate until the skew algorithm converges.

Abstract: A composite of silicon and tin is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery. This electrode material is formed such that the silicon is present as a distinct amorphous phase in a matrix phase of crystalline tin. While the tin phase provides electron conductivity, both phases accommodate the insertion and extraction of lithium in the operation of the cell and both phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. In general, roughly equal atomic proportions of the tin and silicon are used in forming the phase separated composite electrode material.

Abstract: An electrochemical cell is formed. The cell includes a non-lithium negative electrode in contact with a lithium ion permeable negative electrode current collector, and a positive electrode disposed in contact with a lithium ion permeable positive electrode current collector. The non-lithium negative electrode and the positive electrode are lithium ion permeable. The cell also has a lithium source electrode including lithium ions. A respective microporous polymer separator is disposed between the lithium source electrode and each of the negative and positive electrodes; or a first separator is disposed between the lithium source electrode and one of the negative and positive electrodes, and a second separator is disposed between the negative and positive electrodes. An electrolyte is introduced into the electrochemical cell.

Abstract: A method of determining and predicting a state of a rechargeable battery device in real time involves measuring a current and a voltage of the rechargeable battery in real time, inputting the measured current and voltage into an algorithm, and applying the algorithm to determine the state of the rechargeable battery. The algorithm includes a first mathematical model based on a direct solution of at least one differential equation characterizing an equivalent RC circuit of the battery as a function of time. The first model generates a plurality of parameters that are usable to determine the state of the battery. The algorithm further includes a second mathematical model configured to regress the parameters over time, and a third mathematical model configured to estimate the state of the battery.

Abstract: An electroactive material for use in an electrochemical cell, like a lithium ion battery, is provided. The electroactive material comprises a multifunctional hybrid protective coating system formed over an electroactive material. The coating system includes a first oxide-based coating disposed on one or more surfaces of the electroactive material, followed by a second coating deposited via a non-aqueous process. The second coating may be a fluoride-based, nitride-based, or carbide-based coating. The first and second coatings may be applied by atomic layer deposition (ALD) to form conformal ultrathin layers over the electroactive materials. Such a multifunctional hybrid protective coating system can suppress formation of gases within the electrochemical cell and also minimize formation of solid electrolyte interface (SEI) layers on the electrode to improve battery performance. Methods for making such materials and using such materials in electrochemical cells are likewise provided.

Abstract: An electroactive material for use in an electrochemical cell, like a lithium-ion battery, is provided. The electroactive material comprises lithium titanate oxide (LTO) and has a surface coating with a thickness of less than or equal to about 30 nm that suppresses formation of gases within the electrochemical cell. Methods for making such materials and using such materials to suppress gas formation in electrochemical cells are likewise provided.

Abstract: A composite of silicon and tin is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery or a lithium-sulfur battery. This negative electrode material is formed such that the silicon is present as a distinct amorphous phase in a matrix phase of crystalline tin. While the tin phase provides electron conductivity, both phases accommodate the insertion and extraction of lithium in the operation of the cell and both phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. In general, roughly equal atomic proportions of the tin and silicon are used in forming the phase separated composite electrode material.

Abstract: Methods, apparatuses, and systems are presented for performing adaptive equalization involving receiving a signal originating from a channel associated with inter-symbol interference, filtering the signal using a filter having a plurality of adjustable tap weights to produce a filtered signal, and adaptively updating each of the plurality of adjustable tap weights to a new value to reduce effects of inter-symbol interference, wherein each of the plurality of adjustable tap weights is adaptively updated to take into account a constraint relating to a measure of error in the filtered signal and a constraint relating to group delay associated with the filter. Each of the plurality of adjustable tap weights may be adaptively updated to drive group delay associated with the filter toward a target group delay.

Abstract: An electroactive material for use in an electrochemical cell, like a lithium-ion battery, is provided. The electroactive material comprises lithium titanate oxide (LTO) and has a surface coating with a thickness of less than or equal to about 30 nm that suppresses formation of gases within the electrochemical cell. Methods for making such materials and using such materials to suppress gas formation in electrochemical cells are likewise provided.

Abstract: A composite of silicon and tin is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery or a lithium-sulfur battery. This negative electrode material is formed such that the silicon is present as a distinct amorphous phase in a matrix phase of crystalline tin. While the tin phase provides electron conductivity, both phases accommodate the insertion and extraction of lithium in the operation of the cell and both phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. In general, roughly equal atomic proportions of the tin and silicon are used in forming the phase separated composite electrode material.

Abstract: A method for monitoring a lithium-ion battery cell includes monitoring a battery cell voltage and a corresponding charge capacity of the battery cell during an electric power event which may include either an electric power charge event or an electric power discharge event. A measured charge-capacity-derivative is determined by differentiating the charge capacity in relation to the corresponding battery cell voltage during the electric power event. The measured charge-capacity-derivative is compared with a preferred anode charge-capacity-derivative of an anode charge curve (for electric power discharge events) or an anode discharge curve (for electric power charge events), and with a preferred cathode charge-capacity-derivative of a cathode charge curve (for electric power charge events) or a cathode discharge charge curve (for electric power discharge events).

Abstract: A method for monitoring a lithium-ion battery cell includes monitoring a battery cell voltage and a corresponding state of charge of the battery cell during an electric power event which may include either an electric power charge event or an electric power discharge event. A measured potential-derivative is determined by differentiating the battery cell voltage in relation to the corresponding state of charge of the battery during the electric power event. The measured potential-derivative is compared with a preferred anode potential-derivative of an anode charge curve (for electric power discharge events) or an anode discharge curve (for electric power charge events), and with a preferred cathode potential-derivative of a cathode charge curve (for electric power charge events) or a cathode discharge charge curve (for electric power discharge events).

Abstract: A composite of silicon and tin is prepared as a negative electrode composition with increased lithium insertion capacity and durability for use with a metal current collector in cells of a lithium-ion battery. This electrode material is formed such that the silicon is present as a distinct amorphous phase in a matrix phase of crystalline tin. While the tin phase provides electron conductivity, both phases accommodate the insertion and extraction of lithium in the operation of the cell and both phases interact in minimizing mechanical damage to the material as the cell experiences repeated charge and discharge cycles. In general, roughly equal atomic proportions of the tin and silicon are used in forming the phase separated composite electrode material.

Abstract: Methods, apparatuses, and systems are presented for performing adaptive equalization involving receiving a signal originating from a channel associated with inter-symbol interference, filtering the signal using a filter having a plurality of adjustable tap weights to produce a filtered signal, and adaptively updating each of the plurality of adjustable tap weights to a new value to reduce effects of inter-symbol interference, wherein each of the plurality of adjustable tap weights is adaptively updated to take into account a constraint relating to a measure of error in the filtered signal and a constraint relating to group delay associated with the filter. Each of the plurality of adjustable tap weights may be adaptively updated to drive group delay associated with the filter toward a target group delay.

Abstract: A method for monitoring a lithium-ion battery cell includes monitoring a battery cell voltage and a corresponding charge capacity of the battery cell during an electric power event which may include either an electric power charge event or an electric power discharge event. A measured charge-capacity-derivative is determined by differentiating the charge capacity in relation to the corresponding battery cell voltage during the electric power event. The measured charge-capacity-derivative is compared with a preferred anode charge-capacity-derivative of an anode charge curve (for electric power discharge events) or an anode discharge curve (for electric power charge events), and with a preferred cathode charge-capacity-derivative of a cathode charge curve (for electric power charge events) or a cathode discharge charge curve (for electric power discharge events).

Abstract: A method for monitoring a lithium-ion battery cell includes monitoring a battery cell voltage and a corresponding state of charge of the battery cell during an electric power event which may include either an electric power charge event or an electric power discharge event. A measured potential-derivative is determined by differentiating the battery cell voltage in relation to the corresponding state of charge of the battery during the electric power event. The measured potential-derivative is compared with a preferred anode potential-derivative of an anode charge curve (for electric power discharge events) or an anode discharge curve (for electric power charge events), and with a preferred cathode potential-derivative of a cathode charge curve (for electric power charge events) or a cathode discharge charge curve (for electric power discharge events).