Patents by Inventor John S. Waterhouse

John S. Waterhouse has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4392930
    Abstract: Diacrylates or dimethacrylates, which are compatible with water before exposure to actinic radiation but after such exposure form hard, insoluble, coatings which are resistant to organic solvents and to water, are made by reaction with (meth)acrylic acid, or with a dicarboxylic acid and a hydroxy group-containing (meth)acrylate, of epoxide groups in an advanced diepoxide resin containing groups of formula ##STR1## where R.sup.4 denotes a divalent (cyclo)aliphatic or araliphatic radical,each R.sup.15 denotes an alkyl group or each pair of R.sup.15 denotes a group of formula --CH.sub.2).sub.2 --, --C(R.sup.16 R.sup.17)CO--, --CH.sub.2 CH(CH.sub.3)--, --CH.sub.2 --.sub.3, or --CO--.sub.2, wherein R.sup.16 and R.sup.17 each represent a hydrogen atom, an alkyl group, or, conjointly, a cycloaliphatic ring, andc is zero or 1.
    Type: Grant
    Filed: June 30, 1982
    Date of Patent: July 12, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Roderick D. Hathaway, Edward Irving, John S. Waterhouse
  • Patent number: 4368253
    Abstract: A method for forming an image by a positive resist process comprises:(1) exposing imagewise to actinic radiation a photoresist composition comprising:(a) a film-forming organic material having at least one substituted benzoin group of formula: ##STR1## where R.sup.1 denotes a hydrogen atom, an alkyl, cycloalkyl, cycloalkylalkyl, or aralkyl group or a group --(CH.sub.2).sub.b X; R.sup.2 denotes a hydrogen atom or an alkyl, cycloalkyl, cycloalkylalkyl, aryl or aralkyl group; R.sup.3 denotes a halogen atom or an alkyl, alkoxy, cycloalkyl, cycloalkylalkyl or phenyl group; X denotes a halogen atom, an alkoxy group, a phenoxy group, a group --COOR.sup.4 or a group --OOCR.sup.4, where R.sup.
    Type: Grant
    Filed: January 19, 1982
    Date of Patent: January 11, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: George E. Green, John S. Waterhouse
  • Patent number: 4193927
    Abstract: The imidyl compounds, according to the invention, of the formula I are suitable for the manufacture of polymers which can be crosslinked by light, which polymers can be, for example, polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyester-amide-imides, polyethers, polyamines, polysaccharides and polysiloxanes. Polymers of this type are suitable for carrying out photochemical processes. Compared with known polymers, the polymers based on the imidyl compounds according to the invention have the advantage that they are photochemically substantially more sensitive. In addition, this sensitivity can also be further increased effectively by a combination with sensitizers.
    Type: Grant
    Filed: April 21, 1978
    Date of Patent: March 18, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Marcus Baumann, Vratislav Kvita, Martin Roth, John S. Waterhouse
  • Patent number: 4174326
    Abstract: The imidyl compounds, according to the invention, of the formula I are suitable for the manufacture of polymers which can be crosslinked by light, which polymers can be, for example, polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyester-amide-imides, polyethers, polyamines, polysaccharides and polysiloxanes. Polymers of this type are suitable for carrying out photochemical processes. Compared with known polymers, the polymers based on the imidyl compounds according to the invention have the advantage that they are photochemically substantially more sensitive. In addition, this sensitivity can also be further increased effectively by a combination with sensitizers.
    Type: Grant
    Filed: April 21, 1978
    Date of Patent: November 13, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Marcus Baumann, Vratislav Kvita, Martin Roth, John S. Waterhouse
  • Patent number: 4172836
    Abstract: The imidyl compounds, according to the invention, of the formula I are suitable for the manufacture of polymers which can be crosslinked by light, which polymers can be, for example, polyesters, polyamides, polyamide-imides, polyimides, polyester-polyamides, polyester-amide-imides, polyethers, polyamines, polysaccharides and polysiloxanes. Polymers of this type are suitable for carrying out photochemical processes. Compared with known polymers, the polymers based on the imidyl compounds according to the invention have the advantage that they are photochemically substantially more sensitive. In addition, this sensitivity can also be further increased effectively by a combination with sensitisers.
    Type: Grant
    Filed: April 21, 1978
    Date of Patent: October 30, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Marcus Baumann, Vratislav Kvita, Martin Roth, John S. Waterhouse
  • Patent number: 4163097
    Abstract: The invention relates to organic polymers which can be crosslinked under the action of light and which are suitable for carrying out photomechanical processes. These polymers are photochemically considerably more sensitive than known comparable polymers and their sensitivity can additionally also be further increased by means of a combination with sensitizers. The molecular weight is at least 1,000. The polymers contain, as light-sensitive groups, groups of the formula I ##STR1## wherein R and R.sub.1 independently of one another denote alkyl groups with at most 4 C atoms, or R and R.sub.1 conjointly denote the remaining part of a 5-membered to 6-membered carbocyclic ring.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: July 31, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Niklaus Baumann, Hans Zweifel, Marcus Bauman, John S. Waterhouse
  • Patent number: 4158730
    Abstract: The invention relates to organic polymers which can be crosslinked under the action of light and which are suitable for carrying out photomechanical processes. These polymers are photochemically considerably more sensitive than known comparable polymers and their sensitivity can additionally also be further increased by means of a combination with sensitisers. The molecular weight is at least 1,000. The polymers contain, as light-sensitive groups, groups of the formula I ##STR1## wherein R and R.sub.1 independently of one another denote alkyl groups with at most 4 C atoms, or R and R.sub.1 conjointly denote the remaining part of a 5-membered to 6-membered carbocyclic ring.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: June 19, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Niklaus Baumann, Hans Zweifel, Marcus Baumann, John S. Waterhouse
  • Patent number: 4158731
    Abstract: The invention relates to organic polymers which can be crosslinked under the action of light and which are suitable for carrying out photomechanical processes. These polymers are photochemically considerably more sensitive than known comparable polymers and their sensitivity can additionally also be further increased by means of a combination with sensitizers. The molecular weight is at least 1,000. The polymers contain, as light-sensitive groups, groups of the formula I ##STR1## wherein R and R.sub.1 independently of one another denote alkyl groups with at most 4 C atoms, or R and R.sub.1 conjointly denote the remaining part of a 5-membered to 6-membered carbocyclic ring.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: June 19, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Niklaus Baumann, Hans Zweifel, Marcus Baumann, John S. Waterhouse
  • Patent number: 4124760
    Abstract: Diepoxides which may be photopolymerized in the presence or absence of a photosensitizer contain a group having conjugated unsaturation attached to a nitrogen heterocycle, such as a hydantoin or barbituric acid residue, forming part of an advanced diepoxide. The resultant photopolymer may be crosslinked by heating in the presence of a curing agent for epoxide resins.The diepoxides are of use in the production of printing plates and printed circuits, especially multilayer printed circuits.
    Type: Grant
    Filed: July 13, 1977
    Date of Patent: November 7, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: George E. Green, Bernard P. Stark, John S. Waterhouse