Patents by Inventor John W. Rehfuss
John W. Rehfuss has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6147163Abstract: A durability enhancing agent comprising the reaction product of an acrylic oligomer or acrylic polymer and an ultraviolet light absorbing compound, a hindered amine light stabilizer or mixture thereof, said durability enhancing agent further comprising more than one carbamate functional group, or group convertible to a carbamate group, and optionally, including other reactive functionality capable of undergoing a crosslinking reaction. Also included is a curable coating composition comprising the durability enhancing agent, a method for obtaining a coated substrate and the coated article obtained thereby.Type: GrantFiled: December 18, 1996Date of Patent: November 14, 2000Assignee: BASF CorporationInventors: John E. Boisseau, Donald L. St. Aubin, Patricia K. Oberg, John W. Rehfuss
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Patent number: 6117931Abstract: There is described a curable coating composition having at least one effect pigment which, upon cure, exhibits substantially improved orientation of the effect pigment and a corresponding improvement in appearance. The composition comprises:(A) a carbamate-functional component having a hydrophobicity equivalent to or greater than that of a carbamate-functional compound (A') which is the reaction product of:(1) a compound comprising a plurality of hydroxyl groups, at least one of which is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a compound comprising a carbamate group, and(B) a component comprising a plurality of groups that are reactive with the carbamate functional groups on component (A), and(C) at least one effect pigment,the curable coating composition when cured having a substantially improved effect pigment orientation. Preferably, the composition further comprises particular rheology control agents.Type: GrantFiled: December 1, 1997Date of Patent: September 12, 2000Assignee: BASF CorporationInventors: John W. Rehfuss, Marvin L. Green, Bertrum Miller
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Patent number: 6114444Abstract: Coating compositions are described comprising:(A) a polyurea reaction product of a mixture comprising:(1) a polyisocyanate, and(2) ammonia, ammonium hydroxide, an aliphatic or cycloaliphatic primary amine, a hydrazide, aziridine, or water, and(B) a compound having a plurality of functional groups that are reactive with urea groups on said polyurea.Type: GrantFiled: August 8, 1994Date of Patent: September 5, 2000Assignee: BASF CorporationInventors: John W. Rehfuss, Walter H. Ohrbom, Robert J. Taylor
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Patent number: 6106951Abstract: The invention provides a process that includes a first step of reacting the hydroxyl groups of a acrylic resin having hydroxyl groups and carbamate groups with a compound that converts the hydroxyl groups to new groups unreactive with an aminoplast crosslinker; a second step of combining the acrylic resin reaction product with at least an aminoplast crosslinker to form a coating composition; and a third step of applying the coating composition to a substrate and curing the applied coating layer, in which substantially no ether linkages are formed. Aminoplast crosslinkers are desirable for other reasons such as providing high solids coatings having excellent appearance that cure under moderate conditions. Avoiding the ether linkages that could be formed by reaction of aminoplast crosslinkers with hydroxyl groups improves the resistance of the cured coating to environmental etch.Type: GrantFiled: November 24, 1998Date of Patent: August 22, 2000Assignee: BASF CorporationInventors: Walter H Ohrbom, Donald L. St. Aubin, John W. Rehfuss
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Patent number: 6084038Abstract: The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) having at least one carbamate group or urea group and having a lactone or hydroxy carboxylic acid moiety. The second component (b) of the coating composition is one or more of three materials. First, the second component can be a polymer resin (b)(1) comprising active hydrogen-containing functional groups reactive with the third component(c). Secondly, the second component can be a compound (b)(2) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea. Finally, the second component can be a compound (b)(3) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups.Type: GrantFiled: November 2, 1998Date of Patent: July 4, 2000Assignee: BASF CorporationInventors: Walter H Ohrbom, Gregory G. Menovcik, Donald L. St. Aubin, John E. Boisseau, John W. Rehfuss, John D. McGee, Brian D. Bammel, Danielle Regulski, Christopher Bradford
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Patent number: 6080825Abstract: The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes a polymer resin comprising active hydrogen-containing functional groups reactive with the third component (c). The resins is selected from polyester, polyurethane, or polyester-polyurethane copolymers Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.Type: GrantFiled: November 2, 1998Date of Patent: June 27, 2000Assignee: BASF CorporationInventors: Walter H Ohrbom, Gregory G. Menovcik, Donald L. St. Aubin, John E. Boisseau, John W. Rehfuss, John D. McGee, Brian D. Bammel, Danielle Regulski, Christopher Bradford
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Patent number: 6040062Abstract: Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.Type: GrantFiled: June 2, 1997Date of Patent: March 21, 2000Assignee: BASF CorporationInventors: John D. McGee, Donald H. Campbell, John W. Rehfuss
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Patent number: 6037441Abstract: A durability enhancing agent which comprises an ultraviolet light absorbing compound or hindered amine light stabilizer, or mixture thereof, bonded to a non-acrylic monomeric, oligomeric, or polymeric component, said agent comprising more than one carbamate functional group, group convertible to a carbamate group, or a group that crosslinks with a carbamate functional group. Also included is a coating composition including the durability enhancing agent for improved resistance to environmental etch.Type: GrantFiled: December 18, 1996Date of Patent: March 14, 2000Assignee: BASF CorporationInventors: Walter H. Ohrbom, John E. Boisseau, Donald L. St. Aubin, John W. Rehfuss
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Patent number: 5872195Abstract: Curable coating compositions are described comprising(a) a polymer resin comprising active hydrogen-containing functional groups,(b) a curing agent having groups that are reactive with said functional groups on (a), and(c) a compound comprising at least one carbamate group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a compound comprising a carbamate group.Type: GrantFiled: July 1, 1997Date of Patent: February 16, 1999Assignee: BASF CorporationInventors: Marvin L. Green, John W. Rehfuss
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Patent number: 5854385Abstract: A coating composition is disclosed that includes:(A) a multi-functional compound having(1) at least one carbamate or urea functional group,(2) at least one other functional group which may or may not be carbamate or urea, and(3) at least one hydrogen bond acceptor group that is not also a hydrogen bond donor group, with the proviso that said multi-functional compound is other than an acrylic polymer or oligomer having carbamate functional or urea groups appended to the acrylic backbone through acrylic ester side chains, a polyester polymer or oligomer that is the polycondensation reaction product of a polyol and a polyacid component, or a polyurethane that is the reaction product of a polyisocyanate component and a polyester polyol component, and(B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).Type: GrantFiled: August 15, 1996Date of Patent: December 29, 1998Assignee: BASF CorporationInventors: John D. McGee, Brian D. Bammel, Todd A. Seaver, Walter H. Ohrbom, John W. Rehfuss, Gregory G. Menovcik, Paul J. Harris
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Patent number: 5827930Abstract: A curable coating composition is described comprising(A) a carbamate- or urea-functional compound that is the reaction product of(1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of(a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone or a hydroxy carboxylic acid, and(b) a lactone or hydroxy carboxylic acid, and(2) a component that is reactive with compound (A)(1) to convert a hydroxyl group on compound (A)(1) to a carbamate group, or a component comprising a group that is reactive with a hydroxyl group on compound (A)(1) and a carbamate or urea group or group that can be converted to carbamate or urea,(B) a compound comprising a plurality of groups that are reactive with carbamate or urea.Type: GrantFiled: August 15, 1996Date of Patent: October 27, 1998Assignee: BASF CorporationInventors: Walter H. Ohrbom, Brian D. Bammel, John D. McGee, Todd A. Seaver, Gregory G. Menovcik, Paul J. Harris, John W. Rehfuss
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Patent number: 5792810Abstract: A curable coating composition is described comprising(A) a compound comprising carbamate or urea and hydroxyl functional groups that is the reaction product of(1) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone or a hydroxy carboxylic acid, and(2) a lactone or a hydroxy carboxylic acid,(B) a compound comprising at least one group that is reactive with carbamate and at least one group that is reactive with hydroxyl, or a plurality of groups that are reactive with both carbamate and hydroxyl.Type: GrantFiled: August 15, 1996Date of Patent: August 11, 1998Assignee: BASF CorporationInventors: Gregory G. Menovcik, John D. McGee, Walter H. Ohrbom, Brian D. Bammel, Todd A. Seaver, John W. Rehfuss
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Patent number: 5770650Abstract: A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one ester or amide group derived from a reaction of an active hydrogen group with a lactone ring or a hydroxy carboxylic acid, and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).Type: GrantFiled: August 15, 1996Date of Patent: June 23, 1998Assignee: BASF CorporationInventors: John D. McGee, Brian D. Bammel, Walter H. Ohrbom, Todd A. Seaver, Gregory G. Menovcik, Paul J. Harris, John W. Rehfuss
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Patent number: 5766769Abstract: A curable coating composition is described comprising(A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising(1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group(2) a compound comprising inorganic functional groups that are reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that are not reactive with the carbamate or urea groups on compound (A)(1),(B) a compound comprising a plurality of groups that are reactive with carbamate or urea.Type: GrantFiled: August 15, 1996Date of Patent: June 16, 1998Assignee: BASF CorporationInventors: Walter H. Ohrbom, Brian D. Bammel, John D. McGee, Todd A. Seaver, Gregory G. Menovcik, Paul J. Harris, John W. Rehfuss
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Patent number: 5760127Abstract: A curable coating composition is described comprising(A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising(1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of(a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and(b) a lactone or a hydroxy carboxylic acid, and(2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1),(B) a compound comprising a plurality of groups that are reactive with carbamate or urea.Type: GrantFiled: August 15, 1996Date of Patent: June 2, 1998Assignee: BASF CorporationInventors: Brian D. Bammel, John D. McGee, Walter H. Ohrbom, Todd A. Seaver, Gregory G. Menovcik, Paul J. Harris, John W. Rehfuss
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Patent number: 5756213Abstract: A curable coating composition is described comprising(A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).Type: GrantFiled: August 15, 1996Date of Patent: May 26, 1998Assignee: BASF CorporationInventors: Walter H. Ohrbom, John W. Rehfuss, John D. McGee, Gregory G. Menovcik, Paul J. Harris
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Patent number: 5744550Abstract: Curable coating compositions are described comprising(a) a polymer resin comprising active hydrogen-containing functional groups other than carbamate,(b) a curing agent having groups that are reactive with said functional groups on (a), and(c) a compound having a molecular weight of from 75 to 2000 comprising at least one group of the formula: ##STR1## wherein X is O or NH and either (a), (b), or both (a) and (b) comprise groups that are reactive with said group on (c).Type: GrantFiled: November 3, 1994Date of Patent: April 28, 1998Assignee: BASF CorporationInventors: Gregory G. Menovcik, Walter H. Ohrbom, John W. Rehfuss
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Patent number: 5726244Abstract: Environmental etch resistant coatings are described. The coatings are derived from aqueous, curable coating compositions comprising:(a) a carbamate-functional grafted acrylic polymer that comprises the reaction product of a first acrylic polymer and a second acrylic polymer, with at least one of the first and second acrylic polymers having groups that impart water dispersibility to the grafted acrylic polymer, and at least one of the first and second acrylic polymers having carbamate functionality; and(b) a second component comprising a compound having a plurality of functional groups that are reactive with the carbamate functionality.Type: GrantFiled: August 10, 1995Date of Patent: March 10, 1998Assignee: BASF CorporationInventors: John D. McGee, Donald H. Campbell, John W. Rehfuss
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Method for improving etch resistance in a coating utilizing carbamate-functional polymer composition
Patent number: 5726246Abstract: A method for improving etch resistance in a coating comprising applying to a substrate a curable coating composition comprising:(a) a first component comprising a polymer backbone having appended thereto at least one carbamate functional group, and(b) a second component comprising a compound having a plurality of functional groups that are reactive with said carbamate group, andcuring the coating composition.Type: GrantFiled: February 20, 1997Date of Patent: March 10, 1998Assignee: BASF CorporationInventors: John W. Rehfuss, Donald L. St. Aubin -
Patent number: 5719237Abstract: Coatings are described derived from a curable coating composition comprising:(a) a non-polymeric organic compound having a molecular weight of from 75 to 2000 comprising a plurality of carbamate active hydrogens, and(b) a second component comprising a compound having a plurality of functional groups that are reactive with said carbamate active hydrogens.Type: GrantFiled: November 3, 1994Date of Patent: February 17, 1998Assignee: BASF CorporationInventors: John W. Rehfuss, Walter H. Ohrbom, Donald L. St. Aubin, Robert J. Taylor