Abstract: Wurster's crown ligands comprise a macrocyclic ligand such as a crown ether in which a hetero atom is substituted with a 1,4-phenylenediamine group. The phenylenediamine group is covalently bound to the macrocyclic ligand by one or both of the amine nitrogens, the amine nitrogen thereby substituting for the hetero atom of the macrocyclic ligand. The resulting compounds are redox active. Methods of making and using the compounds are also disclosed.

Abstract: Wurster's crown ligands comprise a macrocyclic ligand such as a crown ether in which a hetero atom is substituted with a 1,4-phenylenediamine group. The phenylenediamine group is covalently bound to the macrocyclic ligand by one or both of the amine nitrogens, the amine nitrogen thereby substituting for the hetero atom of the macrocyclic ligand. The resulting compounds are redox active. Methods of making and using the compounds are also disclosed.

Abstract: Wurster's crown ligands comprise a macrocyclic ligand such as a crown ether in which a hetero atom is substituted with a 1,4-phenylenediamine group. The phenylenediamine group is covalently bound to the macrocyclic ligand by one or both of the amine nitrogens, the amine nitrogen thereby substituting for the hetero atom of the macrocyclic ligand. The resulting compounds are redox active. Methods of making and using the compounds are also disclosed.

Abstract: A process for reducing the sulfur content of coal containing pyritic and organic sulfur comprising: contacting the coal with less than the molar stoichiometric amount of at least one +5 vanadium component and at least one reducible manganese component at selected conditions effective to oxidize at least a portion of the sulfur in the coal; reducing the sulfur content of the oxidized sulfur-containing coal; and recovering a coal product having a reduced sulfur content.In another embodiment, the process involves the use of certain plant derived ortho-quinone containing components, in particular, certain lignin and/or tannin derived components containing ortho-quinone functionality, to oxidize at least a portion of at least one of the pyritic and organic sulfur materials in the coal.Preferred compositions comprise at least one ligno sulfonate component containing ortho-quinone functionality.

Abstract: A process for chemically modifying at least one component of a hydrocarbon-based material comprising: contacting the hydrocarbon-based material with at least one metal component selected from the group consisting of vanadium components in which vanadium is present in the 5+ oxidation state in an amount effective to promote the chemical modification of at least one component of the hydrocarbon-based material, iron components in which iron is present in the 3+ oxidation state in an amount effective to promote the chemical modification of at least one component of the hydrocarbon-based material, managanese components in which manganese is present in the 3+ oxidation state in an amount effective to promote the chemical modification of at least one component of the hydrocarbon-based material and mixtures thereof, and at least one oxygen transfer agent in an amount effective to do at least one of the following: maintain at least partially the promoting activity of the metal component; produce at least a portion of

Abstract: A process for recovering a first metal, e.g., gold, from a carbonaceous ore comprising contacting the ore with an added metal component other than an alkali metal or alkaline earth metal component in an amount effective to at least promote the oxidation of carbonaceous material in the ore, the contacting occurring at conditions effective to (1) chemically oxidize at least a portion of the carbonaceous material, and (2) at least partially liberate the first metal from the ore; and recovering the first metal from the ore.

Abstract: A process for at least one of (1) recovering at least one first metal other than manganese from a first ore containing reducible manganese, and (2) recovering at least one second metal from a second ore containing the second metal and at least one metal sulfide of a metal other than the second metal and manganese; the process comprising at least one of: (A) contacting the first ore with an aqueous composition and a material containing at least one metal sulfide in the presence of a metal redox couple more positive than about +0.1 versus the standard hydrogen electrode, W. M.

Abstract: A photoconductive device of decreased resistivity is provided by using at least one zinc oxide transparent conductive layer in conjunction with a thin film amorphous silicon photoconductor. The zinc oxide layer can be used as the front contact, the back contact or both the front and back contacts of the photoconductive device.

Abstract: The unitary electrode (10) comprises a porous sheet (12) of fiberglass the strands (14) of which contain a coating (16) of conductive tin oxide. The lower portion of the sheet contains a layer (18) of resin and the upper layer (20) contains lead dioxide forming a positive active electrode on an electrolyte-impervious layer. The strands (14) form a continuous conduction path through both layers (16, 18). Tin oxide is prevented from reduction by coating the surface of the plate facing the negative electrode with a conductive, impervious layer resistant to reduction such as a thin film (130) of lead or graphite filled resin adhered to the plate with a layer (31) of conductive adhesive. The plate (10) can be formed by casting a molten resin from kettle (60) onto a sheet of glass wool (56) overlying a sheet of lead foil and then applying positive active paste from hopper (64) into the upper layer (68).

Abstract: In the subsurface solution mining of mineral values, especially uranium, in situ, magnesium bicarbonate leaching solution is used instead of sodium, potassium and ammonium carbonate and bicarbonates. The magnesium bicarbonate solution is formed by combining carbon dioxide with magnesium oxide and water. The magnesium bicarbonate lixivant has four major advantages over prior art sodium, potassium and ammonium bicarbonates.