Abstract: This invention provides a multistage emulsion polymer including, as copolymerized units: from 0.5% to 5%, by weight P-acid monomer, based on the weight of the emulsion polymer; from 0% to 0.05% by weight multiethylenically unsaturated monomer, based on the weight of the emulsion polymer; and at least one second monoethylenically unsaturated monomer; the emulsion polymer having a calculated Tg of from ?20° C. to 50° C.; the emulsion polymer is formed by the “pulsed” addition of 75% to 100% of the P-acid monomer during a stage including from 10% to 50% of the total monomer weight, preferably added during the relatively early stages of the polymerization. A multistage polymer/TiO2 composite particle and an aqueous coating composition including the composite particle are also provided.

Abstract: This invention provides a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at or below the critical composite ratio to an equilibrated viscosity range of from 200 cps to 4000 cps. Also provided is a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at a mixing intensity of greater than 2 hp/kgal. A method for providing a coating including composite particles is also included.

Abstract: The present invention relates to a latex composition comprising a) an opaque polymer having a pigment volume concentration of from 18 to 28; b) fully or partially polymer encapsulated TiO2 particles having a pigment volume concentration of from 8 to 18; c) an extender having a pigment volume concentration of from 0 to 10; d) a binder; e) a thickener; and f) water. Notwithstanding the surprisingly high pigment volume concentration of opaque polymer, the composition—upon application to a substrate—gives a coating with a gloss or semi-gloss finish, excellent hiding, and acceptable burnish resistance.

Abstract: Disclosed herein is a method that includes mixing opacifying agent particles with a thickening agent to form a first mixture; the mixing being conducted at a shear rate of about 10 to about 2,000 sec?1; the first mixture having a viscosity of greater than or equal to about 70 Krebs units; and mixing a polymer latex binder with the first mixture to form a coating composition; the polymer latex binder including a copolymer that comprises phosphorus containing repeat units and an acrylate polymer.

Abstract: This invention provides a multistage emulsion polymer including, as copolymerized units: from 0.5% to 5%, by weight P-acid monomer, based on the weight of the emulsion polymer; from 0% to 0.05% by weight multiethylenically unsaturated monomer, based on the weight of the emulsion polymer; and at least one second monoethylenically unsaturated monomer; the emulsion polymer having a calculated Tg of from ?20° C. to 50° C.; the emulsion polymer is formed by the “pulsed” addition of 75% to 100% of the P-acid monomer during a stage including from 10% to 50% of the total monomer weight, preferably added during the relatively early stages of the polymerization. A multistage polymer/TiO2 composite particle and an aqueous coating composition including the composite particle are also provided.

Abstract: This invention provides a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at or below the critical composite ratio to an equilibrated viscosity range of from 200 cps to 4000 cps. Also provided is a method for forming a stable aqueous composition including composite particles by admixing TiO2 particles and adsorbing emulsion polymer particles at a mixing intensity of greater than 2 hp/kgal. A method for providing a coating including composite particles is also included.

Abstract: Disclosed herein is a method that includes mixing opacifying agent particles with a thickening agent to form a first mixture; the mixing being conducted at a shear rate of about 10 to about 2,000 sec?1; the first mixture having a viscosity of greater than or equal to about 70 Krebs units; and mixing a polymer latex binder with the first mixture to form a coating composition; the polymer latex binder including a copolymer that comprises phosphorus containing repeat units and an acrylate polymer.

Abstract: A paint manufacturing method includes receiving each of a group of fluid prepaints at different inputs of a fluid component mixing system, determining at a computer system a first fluid prepaint ratio, and mixing the fluid prepaints in accordance with the first ratio to form a base paint at an output of the mixing system. A paint manufacturing system includes a computer-controlled prepaint mixing system. The prepaint mixing system includes multiple fluid inputs providing for computer-controllable flow of prepaints into the mixing system. The computer system includes a memory storing software instructions that configured the computer system to receive user input selecting a base paint to be produced, determine a ratio of fluid prepaints needed to produce the base paint, and regulate each fluid flow control to establish, in the determined ratio, a flow of fluid prepaints entering the fluid mixing system.

Abstract: A paint manufacturing method includes receiving each of a group of fluid prepaints at different inputs of a fluid component mixing system, determining at a computer system a first fluid prepaint ratio, and mixing the fluid prepaints in accordance with the first ratio to form a base paint at an output of the mixing system. A paint manufacturing system includes a computer-controlled prepaint mixing system. The prepaint mixing system includes multiple fluid inputs providing for computer-controllable flow of prepaints into the mixing system. The computer system includes a memory storing software instructions that configured the computer system to receive user input selecting a base paint to be produced, determine a ratio of fluid prepaints needed to produce the base paint, and regulate each fluid flow control to establish, in the determined ratio, a flow of fluid prepaints entering the fluid mixing system.

Abstract: Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.

Abstract: Sets of prepaints useful for forming a road-marking paint line are provided. Also provided are methods which permit the person applying the road-marking paint to vary the properties of the road-marking paint at the application point to suit the ambient conditions, including temperature, humidity, traffic flow and the like.

Abstract: Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.

Abstract: A paint manufacturing method includes receiving each of a group of fluid prepaints at different inputs of a fluid component mixing system, determining at a computer system a first fluid prepaint ratio, and mixing the fluid prepaints in accordance with the first ratio to form a base paint at an output of the mixing system. A paint manufacturing system includes a computer-controlled prepaint mixing system. The prepaint mixing system includes multiple fluid inputs providing for computer-controllable flow of prepaints into the mixing system. The computer system includes a memory storing software instructions that configured the computer system to receive user input selecting a base paint to be produced, determine a ratio of fluid prepaints needed to produce the base paint, and regulate each fluid flow control to establish, in the determined ratio, a flow of fluid prepaints entering the fluid mixing system.

Abstract: Methods of providing a paint line containing a latex polymeric binder are described. A range of paints can be formulated using sets of prepaints, at least one of which contains a latex polymeric binder. The paints may be applied as architectural coatings, industrial coatings, graphic arts coating, elastomeric coatings, and non-cementitious, aggregate finish coatings suitable for application on a wall directly or as a topcoat in exterior insulation finishing systems.

Abstract: The preparation of a paint line using sets of prepaints containing a latex polymer binder. At least one of which contains a latex polymeric binder, is also is described. The paints may be applied to architectural coatings, and non-cementitious, aggregate finish coating suitable for application on a wall directly or as a topcoat.

Abstract: Methods of providing a paint line containing a latex polymeric binder are described. A range of paints can be formulated using sets of prepaints, at least one of which contains a latex polymeric binder. The paints may be applied as architectural coatings, industrial coatings, graphic arts coating, elastomeric coatings, and non-cementitious, aggregate finish coatings suitable for application on a wall directly or as a topcoat in exterior insulation finishing systems.

Abstract: Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.

Abstract: Sets of prepaints useful for forming a road-marking paint line are provided. Also provided are methods which permit the person applying the road-marking paint to vary the properties of the road-marking paint at the application point to suit the ambient conditions, including temperature, humidity, traffic flow and the like.