Abstract: Processes for treating effluent streams in alkylation processes are described. One or more process streams rom HF alkylation processes, H2SO4 alkylation processes, or ionic liquid alkylation processes can be thermally oxidized in a thermal oxidation system. The thermal oxidation system can replace at least one of the caustic wash unit, the neutralization unit, and the acid gas treatment unit.

Abstract: Processes for treating effluent streams in alkylation processes are described. One or more process streams rom HF alkylation processes, H2SO4 alkylation processes, or ionic liquid alkylation processes can be thermally oxidized in a thermal oxidation system. The thermal oxidation system can replace at least one of the caustic wash unit, the neutralization unit, and the acid gas treatment unit.

Abstract: The present invention relates to a combined reactor settler with the reactor. More specifically, the present invention relates to a combined reactor settler and reactor in a caustic free kerosene sweetening reactor which reduces equipment costs, operating costs, and plot space requirements.

Abstract: A process and apparatus for sweetening a hydrocarbon stream. The apparatus includes two vessels. In a first extraction vessel, caustic removes mercaptans from the hydrocarbon stream. In a second oxidation vessel, the mercaptans in the rich caustic are converted in disulfides. The lean caustic and disulfides are passed back to the first extraction vessel in which the disulfides are separated into the sweetened hydrocarbon phase. The second vessel may receive a wash oil, such as the sweetened hydrocarbon phase, to remove disulfides from a vented gas stream.

Abstract: The present invention relates to a combined reactor settler with the reactor. More specifically, the present invention relates to a combined reactor settler and reactor in a caustic free kerosene sweetening reactor which reduces equipment costs, operating costs, and plot space requirements.

Abstract: One exemplary embodiment can be a process for oxidizing one or more thiol compounds from an alkaline stream. The process may include passing a mixed stream having the alkaline stream to a vessel having an oxidation section, a separation section and a vent gas section. Often, the oxidation section includes a body containing one or more packing elements. The process can further include passing an oxidized alkaline stream to the separation section containing a first chamber and a second chamber. Usually, the first chamber contains a coated mesh and packing. The two sections further form a neck contains a packing, a distributor, and a mesh.

Abstract: A process and apparatus for oxidizing thiol compounds from an alkaline stream. The process includes passing a thiol rich alkaline stream and an oxygen containing gas to a low pressure oxidizing zone to oxidize at least a portion of the thiol compounds to disulfide compounds. A liquid stream comprising the alkali containing the disulfide compounds is passed through a pump to increase the pressure and form a pressurized alkaline stream. The pressurized alkaline stream and a sulfur lean liquid light hydrocarbon stream are introduced to a high pressure disulfide separation vessel to form a sulfur lean alkaline stream and a sulfur rich liquid light hydrocarbon stream.

Abstract: The present invention relates to a system to detect mercaptides or sulfides in a caustic stream. More particularly, this invention relates to an on-line analyzer for measuring mercaptides using a color changing reagent to quantify mercaptide or sulfide concentration in a caustic stream. The on-line analyzer which includes a liquid sensor which can provide valuable feedback to an operator for controlling a processing unit for the catalytic oxidation of mercaptides to disulfides in an alkaline environment.

Abstract: A process and apparatus for oxidizing thiol compounds from an alkaline stream. The process includes passing a thiol rich alkaline stream and an oxygen containing gas to a low pressure oxidizing zone to oxidize at least a portion of the thiol compounds to disulfide compounds. A liquid stream comprising the alkali containing the disulfide compounds is passed through a pump to increase the pressure and form a pressurized alkaline stream. The pressurized alkaline stream and a sulfur lean liquid light hydrocarbon stream are introduced to a high pressure disulfide separation vessel to form a sulfur lean alkaline stream and a sulfur rich liquid light hydrocarbon stream.

Abstract: One exemplary embodiment can be a process for oxidizing one or more thiol compounds from an alkaline stream. The process may include passing a mixed stream having the alkaline stream to a vessel having an oxidation section, a separation section and a vent gas section. Often, the oxidation section includes a body containing one or more packing elements. The process can further include passing an oxidized alkaline stream to the separation section containing a first chamber and a second chamber. Usually, the first chamber contains a coated mesh and packing. The two sections further form a neck contains a packing, a distributor, and a mesh.

Abstract: One exemplary embodiment can be a process for oxidizing one or more thiol compounds from an alkaline stream. The process may include passing a mixed stream having the alkaline stream to a vessel having an oxidation section, a separation section and a vent gas section. Often, the oxidation section includes a body containing one or more packing elements. The process can further include passing an oxidized alkaline stream to the separation section containing a first chamber and a second chamber. Usually, the first chamber contains a coated mesh and packing. The two sections further form a neck contains a packing, a distributor, and a mesh.

Abstract: Clay treatment apparatuses and methods for processing hydrocarbon products using clay treatment apparatuses are disclosed. In one exemplary embodiment, a clay treatment apparatus includes a vessel enclosing an interior space, an active clay material disposed within the interior space of the vessel, and a clay retention structure positioned above a bottom head portion of the vessel. The clay retention structure includes a wire mesh coupled with a perforated plate. In another exemplary embodiment, a method for processing a hydrocarbon product includes the steps of contacting the hydrocarbon product with an active clay material within an interior space of a vessel and passing the hydrocarbon product through a clay retention structure that includes a wire mesh and a perforated plate.

Abstract: A process and apparatus for sweetening a hydrocarbon stream. The apparatus includes two vessels. In a first extraction vessel, caustic removes mercaptans from the hydrocarbon stream. In a second oxidation vessel, the mercaptans in the rich caustic are converted in disulfides. The lean caustic and disulfides are passed back to the first extraction vessel in which the disulfides are separated into the sweetened hydrocarbon phase. The second vessel may receive a wash oil, such as the sweetened hydrocarbon phase, to remove disulfides from a vented gas stream.

Abstract: A method and apparatus for removing carbonyl sulfide (COS) from a hydrocarbon stream have been developed. The design allows removal of COS in the regeneration stream to less than 10 wppm, even at high concentrations of COS. The spent bed is regenerated using a portion of the treated product stream. The COS regeneration column provides increased contact and residence time.

Abstract: Clay treatment apparatuses and methods for processing hydrocarbon products using clay treatment apparatuses are disclosed. In one exemplary embodiment, a clay treatment apparatus includes a vessel enclosing an interior space, an active clay material disposed within the interior space of the vessel, and a clay retention structure positioned above a bottom head portion of the vessel. The clay retention structure includes a wire mesh coupled with a perforated plate. In another exemplary embodiment, a method for processing a hydrocarbon product includes the steps of contacting the hydrocarbon product with an active clay material within an interior space of a vessel and passing the hydrocarbon product through a clay retention structure that includes a wire mesh and a perforated plate.

Abstract: A method and apparatus for removing carbonyl sulfide (COS) from a hydrocarbon stream have been developed. The design allows removal of COS in the regeneration stream to less than 10 wppm, even at high concentrations of COS. The spent bed is regenerated using a portion of the treated product stream. The COS regeneration column provides increased contact and residence time.

Abstract: Processes and apparatuses for removing mercaptans from feed streams are provided. In one embodiment, a process for removing mercaptans from a feed stream includes extracting mercaptans and a polymeric precursor from the feed stream with a caustic solvent to form a polymeric precursor rich spent caustic solvent. The polymeric precursor rich spent caustic solvent is contacted with a polymeric precursor-deficient hydrocarbon stream in a multistage vessel and the polymeric precursor is extracted from the polymeric precursor rich spent caustic solvent to form a treated spent caustic solvent. The process contacts the treated spent caustic solvent with oxygen and oxidizes the mercaptans to disulfides to form an oxidized caustic solvent stream. The process includes separating the oxidized caustic solvent stream into an offgas stream, a disulfide stream, and a caustic solvent stream.

Abstract: Disclosed is a liquid-liquid contacting tray, including: (i) a liquid-liquid contacting deck having a first side and a opposite second side, the deck comprising a perforated tray material; (ii) an outlet weir extending vertically from the first side of the contacting deck, the outlet weir defining an interior space of the outlet weir; (iii) an inlet weir extending vertically from the first side of the contacting deck, the inlet weir surrounding the outlet weir; and (iv) a tubular downcomer having a first end and a second end, the first end being in fluid communication with the interior space of the outlet weir, the downcomer extending away from the second side of the liquid-liquid contacting deck.

Abstract: One exemplary embodiment can be a stack for a separation vessel adapted to receive a fluid having one or more phases. The stack may include one or more walls surrounding a void, a packed bed positioned within the void, and a distributor positioned above the packed bed. Generally, the stack has a height greater than its width. Usually, the separation vessel further includes a base having a length greater than its height, and the height of the stack is orientated substantially perpendicular to the length of the base.

Abstract: The invention covers a method for treating spent regeneration gas from one or more molecular sieve treaters, first in an amine solvent unit and then in a caustic unit. The amine solvent unit removes hydrogen sulfide and carbonyl sulfide and the caustic unit removes mercaptans. Optionally, there are additional treatments before the treated gas has met specifications for burning as a fuel or used for other purposes.