Abstract: Method and apparatus for monitoring amounts of submerged solid consumable. A GWR (Guided Wave Radar) component can provide a measurement of a reflection at a fixed position in a particle bed. The reflection represents aggregate dielectric properties in a vessel. The measurement includes hydrocarbon and solid consumable properties of a mixture in the vessel, wherein a measurement value is indicative of a greater amount of the solid consumable in the mixture in the vessel. If data is measured by the GWR component indicating that the measurement value is approaching the measurement value of the hydrocarbon, this data is indicative that the material (e.g., solid consumable such as salt) in the vessel should be replenished.

Abstract: Method and apparatus for monitoring amounts of submerged solid consumable. A GWR (Guided Wave Radar) component can provide a measurement of a reflection at a fixed position in a particle bed. The reflection represents aggregate dielectric properties in a vessel. The measurement includes hydrocarbon and solid consumable properties of a mixture in the vessel, wherein a measurement value is indicative of a greater amount of the solid consumable in the mixture in the vessel. If data is measured by the GWR component indicating that the measurement value is approaching the measurement value of the hydrocarbon, this data is indicative that the material (e.g., solid consumable such as salt) in the vessel should be replenished.

Abstract: One exemplary embodiment can be a process for removing gases from a sweetened hydrocarbon stream. The process can include passing the sweetened hydrocarbon stream to a gas removal zone, contacting the sweetened hydrocarbon stream with an aqueous stream, passing the aqueous stream to the degassing drum, and removing gases including at least one of oxygen and nitrogen from the aqueous stream. Often, the gas removal zone includes a degassing drum.

Abstract: Embodiments of apparatuses and methods for conversion of mercaptans are provided. In one example, an apparatus comprises a vessel that is capable to receive a feed stream that comprises liquid hydrocarbons and the mercaptans. The vessel comprises a catalyst bed section that is capable of contacting the feed stream with a catalyst in the presence of oxygen (O2) and caustic at reaction conditions effective to oxidize the mercaptans and form a caustic-containing, sweetened liquid hydrocarbon-containing stream. A coalescing bed section is capable to coalesce and separate at least a portion of the caustic from the caustic-containing, sweetened liquid hydrocarbon-containing stream for forming a caustic-depleted, sweetened liquid hydrocarbon-containing product stream.

Abstract: A unit for processing a liquid/gas phase mixture, a mercaptan oxidation apparatus, and a method of processing a liquid/gas phase mixture are provided. In an embodiment, a unit for processing a liquid/gas phase mixture includes a vessel that is adapted to receive the liquid/gas phase mixture and a distributor that is disposed in the vessel. The distributor is adapted for flow of the liquid/gas phase mixture into the vessel, and the distributor includes a first outlet pipe that is horizontally disposed within the vessel. The first outlet pipe includes top orifices and bottom orifices that are spaced along the first outlet pipe, and the first outlet pipe is in fluid communication with the vessel through the top orifices and the bottom orifices. The top orifices have a smaller cross-sectional area than the bottom orifices.

Abstract: Embodiments of apparatuses and methods for treating mercaptans are provided. In one example, an apparatus comprises a vessel capable of receiving a feed stream that comprises liquid hydrocarbons and the mercaptans. The vessel comprises an extraction section that is capable of extracting a portion of the mercaptans from the feed stream to form a mercaptan-reduced, liquid hydrocarbon-containing stream. A catalyst bed section is capable of contacting the mercaptan-reduced, liquid hydrocarbon-containing stream with a catalyst in the presence of oxygen (O2) and caustic at reaction conditions effective to oxidize a remaining portion of the mercaptans and form a sweetened liquid hydrocarbon-containing stream.

Abstract: Methods and apparatuses are provided for producing low sulfur propane and butane. The method includes reacting a mercaptan in a washed feed stream with a caustic stream to produce a mercaptan salt in a rich caustic stream and a hydrocarbon treated stream. The mercaptan salt in the rich caustic stream is reacted with oxygen and water to produce a mixed caustic/disulfide stream, and the caustic and disulfides in the mixed caustic/disulfide stream are separated to produce a disulfide stream and the caustic stream. The hydrocarbon treated stream is fractionated to produce a propane stream, a butane stream, and a C5+ stream.

Abstract: One exemplary embodiment can be a process for removing one or more sulfur compounds from a first liquid. The process can include passing the first liquid through a first inlet and a second liquid through a second inlet of a vessel, passing the first and second liquids through the passageway for facilitating contacting of the first and second liquids to extract the one or more sulfur compounds from the first liquid to the second liquid, and passing the first liquid through the first outlet and the second liquid through the second outlet. Often, the vessel has a plurality of vortex contactors, and a first outlet and a second outlet. The plurality of vortex contactors can include a first vortex contactor, in turn having at least one wall forming a perimeter about an interior region and including a first side and a second side forming a passageway communicating the first liquid from an exterior to the interior region, and a frustum positioned proximate to the passageway and abutting the at least one wall.

Abstract: Disclosed is a method for treating hydrocarbon streams containing mercaptan compounds including contacting a first, relatively light hydrocarbon stream including mercaptan compounds with a first alkaline caustic solution to remove the mercaptan compounds from the first hydrocarbon stream and generate a second alkaline caustic solution including mercaptan compounds and oxidizing the mercaptan compounds in the second alkaline caustic solution to generate a third alkaline solution including a first concentration of disulfide compounds. The method further includes separating a portion of the disulfide compounds in the third alkaline solution to form a fourth alkaline solution including a second concentration of disulfide compounds.

Abstract: An exemplary embodiment can be a process for removing one or more sulfur compounds in a gas hydrocarbon stream. The process may include feeding the gas hydrocarbon stream to a prewash zone containing an alkali stream and passing the gas hydrocarbon stream from the prewash zone to an extraction zone. Usually, the gas hydrocarbon stream includes one or more sulfur compounds and the prewash zone includes a hollow fiber membrane.

Abstract: One exemplary embodiment can be a process for extracting sulfur compounds in a hydrocarbon stream. The process can include feeding a hydrocarbon stream containing sulfur compounds to a prewash zone containing an alkali, withdrawing a prewashed hydrocarbon stream from the prewash zone, and feeding the prewashed hydrocarbon stream to a mass transfer zone for extracting one or more thiol compounds from the prewashed hydrocarbon stream. Often, the mass transfer zone includes a hollow fiber membrane contactor.

Abstract: Processes and apparatus are provided for treating gasoline range hydrocarbons containing mercaptans to convert the mercaptans to organic disufides. The process involves contacting treated gasoline range hydrocarbons comprising organic disulfides with a coalescing material and separating refined gasoline range hydrocarbons and organic disulfides from spent alkali using a separation device. The apparatus comprises a treatment vessel suitable for housing a catalyst therein for producing treated gasoline range hydrocarbons comprising organic disulfides, as well as a separation device and coalescing material therein for separating gasoline range hydrocarbons and organic disulfides from spent alkali.

Abstract: One exemplary embodiment can be a process for removing one or more sulfur-containing hydrocarbons. The process can include sending a stream including one or more alkaline compounds, one or more hydrocarbons, and one or more sulfur compounds to a stack of a disulfide separator, and sending a fluid downstream of a distributor to a vortex contacting device for providing a gas having no more than about 100 ppm, by weight, sulfur. Often, the stack includes one or more walls surrounding a void and the distributor positioned within the void, and is adapted to receive the stream having one or more phases.

Abstract: Methods and apparatuses for processing hydrocarbons are provided. In one embodiment, a method for processing a hydrocarbon stream includes feeding a hydrocarbon stream including amine and mercaptan to an extraction zone. The method includes contacting the hydrocarbon stream with an alkaline stream in the extraction zone to convert the mercaptan to a mercaptide. Further, the method includes contacting the hydrocarbon stream with water in the extraction zone to remove the amine from the hydrocarbon stream.

Abstract: Embodiments of apparatuses and methods for treating mercaptans are provided. In one example, an apparatus comprises a vessel capable of receiving a feed stream that comprises liquid hydrocarbons and the mercaptans. The vessel comprises an extraction section that is capable of extracting a portion of the mercaptans from the feed stream to form a mercaptan-reduced, liquid hydrocarbon-containing stream. A catalyst bed section is capable of contacting the mercaptan-reduced, liquid hydrocarbon-containing stream with a catalyst in the presence of oxygen (O2) and caustic at reaction conditions effective to oxidize a remaining portion of the mercaptans and form a sweetened liquid hydrocarbon-containing stream.

Abstract: Embodiments of apparatuses and methods for conversion of mercaptans are provided. In one example, an apparatus comprises a vessel that is capable to receive a feed stream that comprises liquid hydrocarbons and the mercaptans. The vessel comprises a catalyst bed section that is capable of contacting the feed stream with a catalyst in the presence of oxygen (O2) and caustic at reaction conditions effective to oxidize the mercaptans and form a caustic-containing, sweetened liquid hydrocarbon-containing stream. A coalescing bed section is capable to coalesce and separate at least a portion of the caustic from the caustic-containing, sweetened liquid hydrocarbon-containing stream for forming a caustic-depleted, sweetened liquid hydrocarbon-containing product stream.

Abstract: A process for removing sulfur compounds from a liquid hydrocarbon stream includes the steps of feeding the hydrocarbon stream to a recirculation section of an extraction vessel wherein the recirculation section contains a first alkaline solution; passing the hydrocarbon stream through the recirculation section; recirculating at least a part of a first alkaline stream to a top deck of one or more liquid-liquid contacting decks of the recirculation section; passing the hydrocarbon stream from the recirculation section to an extraction section of the extraction vessel wherein the extraction section includes one or more liquid-liquid contacting decks; feeding a second alkaline stream to an upper deck of the one or more liquid-liquid contacting decks of the extraction section wherein the second alkaline stream includes a second alkaline solution; and withdrawing a hydrocarbon product stream from the extraction vessel. An apparatus for removing sulfur compounds from the hydrocarbon stream is also disclosed.

Abstract: One exemplary embodiment can be a process for oxidizing one or more thiol compounds from an alkaline stream. The process may include passing a mixed stream having the alkaline stream to an oxidation vessel having a body and a neck. Often, the body contains one or more packing elements and the neck contains a packing, a distributor, and a mesh. The process can further include passing an oxidized alkaline stream to a separation vessel containing a first chamber and a second chamber. Usually, the first chamber contains a coated mesh.

Abstract: One exemplary embodiment can be a process for removing gases from a sweetened hydrocarbon stream. The process can include passing the sweetened hydrocarbon stream to a gas removal zone, contacting the sweetened hydrocarbon stream with an aqueous stream, passing the aqueous stream to the degassing drum, and removing gases including at least one of oxygen and nitrogen from the aqueous stream. Often, the gas removal zone includes a degassing drum.

Abstract: A unit for processing a liquid/gas phase mixture, a mercaptan oxidation apparatus, and a method of processing a liquid/gas phase mixture are provided. In an embodiment, a unit for processing a liquid/gas phase mixture includes a vessel that is adapted to receive the liquid/gas phase mixture and a distributor that is disposed in the vessel. The distributor is adapted for flow of the liquid/gas phase mixture into the vessel, and the distributor includes a first outlet pipe that is horizontally disposed within the vessel. The first outlet pipe includes top orifices and bottom orifices that are spaced along the first outlet pipe, and the first outlet pipe is in fluid communication with the vessel through the top orifices and the bottom orifices. The top orifices have a smaller cross-sectional area than the bottom orifices.