Abstract: Corrosion-resistant oxide films for use with proton exchange membrane fuel cells are described. Bipolar plates of proton exchange membrane fuel cells are subject to highly-acidic environments that can degrade the bulk material and associated properties of the bipolar plate leading to reduced proton exchange membrane fuel cell lifetimes. Materials, structures, and techniques for increasing the corrosion resistance of bipolar plates are disclosed. Such materials include substrates having a surface portion, which includes an Fe2O3 oxide layer having (110), (012), or (100) Fe2O3 surface facets configured to impart corrosion-resistance properties to the substrate.

Abstract: Provided are chemosensor compounds of formula (I) useful for detecting an ion, such as Pb2+ in an aqueous sample. Also provided are a chemosensor device including such compounds and methods of use thereof.

Abstract: A fuel cell electrolyte includes a nitrogen-doped phosphate tetrahedral network having a plurality of linked tetrahedra, each of the plurality of the linked tetrahedra having a phosphorus cation center and four anions including oxygen or nitrogen, the network having at least one compound of formula (I): H3+xPO4?xNx where x is any number between 0.001 and 3.

Abstract: A fuel cell stack includes a first end region, a second end region, and a middle region. At least one of a first number of fuel cell units in the first end region is a first fuel cell unit including a membrane electrode assembly (MEA) with a first catalyst material on either or both an anode and a cathode of the first fuel cell unit. At least one of a second number of fuel cell units in the second end region is a second fuel cell unit including an MEA with a second catalyst material on either or both an anode and a cathode of the first fuel cell unit. The middle region is situated between the first and the second end region. At least one of a third number of fuel cell units in the middle region is a third fuel cell unit including an MEA with a third catalyst material on either or both an anode and a cathode of the first fuel cell unit. At least one of the first, the second, and the third catalyst material are different.

Abstract: A simulation includes converting a molecular dynamics snapshot of elements within a multi-element system into a graph with atoms as nodes of the graph; defining a matrix such that each column of the matrix represents a node in the graph; defining a distance matrix according to a set of relative positions of each of the atoms; iterating through the GTFF using an attention mechanism, operating on the matrix and augmented by incorporating the distance matrix, to pass hidden state from a current layer of the GTFF to a next layer of the GTFF; performing a combination over the columns of the matrix to produce a scalar molecular energy; making a backward pass through the GTFF, iteratively calculating derivatives at each of the layers of the GTFF to compute a prediction of force acting on each atom; and returning the prediction of the force acting on each atom.

Abstract: Battery systems and methods for accelerating ion diffusion in polymer electrolyte materials. The application of oscillating electric fields is used to improve the ionic transport properties of polymer electrolytes by reducing the apparent hopping barrier of the lithium ions within the electrolyte material. Polymer-electrolyte-based battery cells exhibiting enhanced ion mobility due to the application of such oscillating electric fields.

Abstract: A composite fuel cell polymer electrolyte membrane. The composite membrane includes a polymer electrolyte membrane base material including first and second inorganic particles. The first and second inorganic particles are interspersed within the polymer electrolyte membrane base material and each other. The first and second inorganic particles have first and second surface properties and the first surface property is different than the second surface property.

Abstract: In some aspects, graphic layers for depicting a visible representation of an image along a surface of a photovoltaic module can include a plurality of substantially opaque isolated regions; and at least one substantially transparent contiguous region surrounding the substantially opaque isolated regions, wherein an outer surface of the at least one substantially transparent contiguous region comprises a matte surface finish.

Abstract: An intermediate temperature solid oxide fuel cell (IT-SOFC) includes an anode layer, an electrolyte adjacent to the anode layer, and a cathode layer adjacent to the electrolyte and including a material of formula (I) or (II): Sr2OsO4 (I) or Ba2MO4 (II), where M is a transition metal or post-transition metal.

Abstract: A fuel cell first and second electrode catalyst layers and a polymer electrolyte membrane (PEM) situated therebetween. A graphene-based material coated onto a first and/or second surface of the first and/or second electrode catalyst layers. The graphene-based material has a number of defects including a number of quad-vacancy (QV) defects formed by a vacancy of four adjacent carbon atoms in the graphene-based material. The number of QV defects are configured to mitigate dissolution of the first and/or second catalyst materials through the first and/or second surface of the first and/or second electrode catalyst layers.

Abstract: A fuel cell catalyst material includes metal catalyst particles formed of a metal material and a carbon-based coating composition at least partially coating at least some of the metal catalyst particles. The carbon-based coating composition includes a carbon network. The carbon-based coating composition is doped with a dopant. The carbon-based coating composition includes a number of defects formed by one or more vacated carbon atoms in the carbon network.

Abstract: A polyelemental catalyst structure. The structure includes a region formed of a first metal material, a first core region formed of a second metal material, and a second core region formed of a third metal material. The first core region has interfacial contact with the region. The second core region has interfacial contact with the first core region. The polyelemental catalyst structure includes platinum (Pt), a first metal MI, a second metal MII and a third metal MIII. The first metal MI is configured to enhance catalytic activity of Pt. The second metal MII is configured to enhance stability of the polyelemental catalyst structure. The third metal MIII is configured to enhance covalent bonding between Pt, the first metal MI, the second metal MII and/or the third metal MIII.

Abstract: A sensor system includes a sensor and an optical source. The sensor has a receptor configured to bind to a chemical species. A spacer is bound to the receptor, and a fluorophore is bound to the spacer. The optical source is configured to irradiate the sensor to dissociate the chemical species from the receptor. The optical source can be infrared light, microwave or radio wave. The sensor system optionally includes a photodetector configured to determine an amount of the chemical species by measuring fluorescence when the optical source irradiates the sensor.

Abstract: Provided are chemosensor compounds of formula (I) useful for detecting an ion, such as Pb2+ in an aqueous sample. Also provided are chemosensor device including such compounds, and methods of use thereof.

Abstract: Fuel cell alloy bipolar plates. The alloys may be used as a coating or bulk material. The alloys and metallic glasses may be particularly suitable for proton-exchange membrane fuel cells because of they may exhibit reduced weights and/or better corrosion resistance. The alloys may include any of the following AlxCuyTiz, AlxFeyNiz, AlxMnyNiz, AlxNiyTiz, CuxFeyTiz, CuxNiyTiz, AlxFeySiz, AlxMnySiz, AlxNiySiz, NixSiyTiz, and CxFeySiz. The alloys or metallic glass may be doped with various dopants to improve glass forming ability, mechanical strength, ductility, electrical or thermal conductivities, hydrophobicity, and/or corrosion resistance.

Abstract: A fuel cell membrane electrode assembly including a polymer electrolyte membrane (PEM) and first and second electrodes. The PEM is situated between the first and second electrodes. The first electrode includes a first catalyst material layer including a first catalyst material and having first and second surfaces. The first electrode includes first and second material layers adjacent to the first and second surfaces, respectively, of the first catalyst material. The first material layer faces away from the PEM and the second material layer faces the PEM. The first material layer comprises a graphene-based material layer having a number of defects configured to mitigate dissolution of the first catalyst material through the first material layer.

Abstract: A hydrogen gas storage tank includes a body including a steel bulk region and a passivating metal oxide layer adjacent to the steel bulk region, the oxide layer comprising a number of metal oxide molecules, all having a morphology, wherein at least about 51 wt. % of the number of metal oxide molecules are Fe2O3 molecules having morphologies of (012), (001), and/or (110) surface facets such that the oxide layer is configured to lower hydrogen adsorption into the steel bulk region by at least 25% compared to a steel bulk region free from the passivating metal oxide layer.

Abstract: A fuel cell bipolar plate (BPP) includes a metal substrate having a bulk portion and a surface portion comprising an anticorrosive, conductive material having oxygen vacancies and a formula (I): MgTi2O5-???(I), where ? is any number between 0 and 3 optionally including a fractional part denoting the oxygen vacancies, the material having an electronic conductivity of about 2-10 S/m at room temperature in an ambient environment.

Abstract: An anticorrosive, conductive material includes a first oxide having oxygen vacancies and a formula (I): MgTi2O5-? (I), where ? is any number between 0 and 3 optionally including a fractional part denoting the oxygen vacancies; and a second oxide having a formula (II): TiaOb (II), where 1<=a<=20 and 1<=b<=30, optionally including a fractional part, the first and second oxides of formulas (I) and (II) forming a polycrystalline matrix.

Abstract: A method of forming a fuel cell catalyst system, the method includes providing an anticorrosive, conductive catalyst support material having oxygen vacancies and a formula (I): MgTi2O5-???(I), where ? is any number between 0 and 3 optionally including a fractional part denoting the oxygen vacancies, coating the catalyst support material with a polymeric film, attaching a catalyst material onto the polymeric film, removing the polymeric film, and providing additional material onto the support material to increase physical, electrical, and/or mechanical contact between the catalyst material and the catalyst support material.