Abstract: The present invention provides an oxygen selective adsorbent containing oxides of BaxSr(1?x)Mgy(CO3)(1+y) or BaxSr(1?x)CO3 particles, increasing transition oxygen partial pressure, and representing high thermal stability and excellent oxygen sorption cavity, by adding another metal such as Sr to Ba which is active element for oxygen adsorption, so as to be capable of desorbing oxygen under lower vacuum even at the same operating temperature than the existing oxygen selective adsorbent; and a preparation method thereof.

Abstract: The present invention provides an oxygen selective adsorbent containing oxides of BaxSr(1?x)Mgy(CO3)(1+y) or BaxSr(1?x)CO3 particles, increasing transition oxygen partial pressure, and representing high thermal stability and excellent oxygen sorption cavity, by adding another metal such as Sr to Ba which is active element for oxygen adsorption, so as to be capable of desorbing oxygen under lower vacuum even at the same operating temperature than the existing oxygen selective adsorbent; and a preparation method thereof.

Abstract: Provided is a system for liquefying natural gas including: a pre-cooling means; a gas-liquid separating means; a first heat exchanging means; a second heat exchanging means; a first expanding means; a second expanding means; a first mixed refrigerant converting means; a pre-cooled refrigerant supplying means; a natural gas supplying means; and a mixer. Provided is also a method for liquefying natural gas including: a first pre-cooling operation (S01); a first mixed refrigerant separating operation (S02); a first introducing operation (S03); a first expanded refrigerant forming operation (S04); a second introducing operation (S05); a second expanded refrigerant forming operation (S06); and a second cooling operation (S07).

Abstract: Provided is a preparation method of an oxygen-selective adsorbent selectively adsorbing oxygen in the air and an oxygen-selective adsorbent prepared thereby. The preparation method includes: preparing BaMg(CO3)2 particles or particles in which MgCO3 or Mg(OH)2 are attached to the outside of BaMg(CO3)2; and sintering the particles at a high temperature. The oxygen-selective adsorbent according to the present invention may adsorb oxygen in the air at a fast rate as compared with an existing oxygen-selective adsorbent and have high thermal stability and excellent oxygen adsorptivity.

Abstract: Provided are a continuous oxygen adsorption and desorption device and an continuous oxygen adsorption and desorption method using the device, and more particularly, an continuous oxygen adsorption and desorption device for producing high-purity oxygen products by using a plurality of adsorption and desorption towers filled with an oxygen-selecting adsorption and desorption agent selected from BaMg(CO3)2 particles or particles in which either MgCO3 or Mg(OH)2 has been attached to the outside of BaMg(CO3)2, and also a continuous oxygen adsorption and desorption method using the device.

Abstract: Provided are a continuous oxygen adsorption and desorption device and an continuous oxygen adsorption and desorption method using the device, and more particularly, an continuous oxygen adsorption and desorption device for producing high-purity oxygen products by using a plurality of adsorption and desorption towers filled with an oxygen-selecting adsorption and desorption agent selected from BaMg(CO3)2 particles or particles in which either MgCO3 or Mg(OH)2 has been attached to the outside of BaMg(CO3)2, and also a continuous oxygen adsorption and desorption method using the device.

Abstract: The present invention provides an oxygen selective adsorbent containing BaxSr(1?x)Mgy(CO3)(1+y) or BaxSr(1?x)CO3 particles, increasing transition oxygen partial pressure, and representing high thermal stability and excellent oxygen sorption cavity, by adding another metal such as Sr to Ba which is active element for oxygen adsorption, so as to be capable of desorbing oxygen under lower vacuum even at the same operating temperature as existing oxygen selective adsorbents, and a preparation method thereof.

Abstract: Provided is a preparation method of an oxygen-selective adsorbent selectively adsorbing oxygen in the air and an oxygen-selective adsorbent prepared thereby. The preparation method includes: preparing BaMg(CO3)2 particles or particles in which MgCO3 or Mg(OH)2 are attached to the outside of BaMg(CO3)2; and sintering the particles at a high temperature. The oxygen-selective adsorbent according to the present invention may adsorb oxygen in the air at a fast rate as compared with an existing oxygen-selective adsorbent and have high thermal stability and excellent oxygen adsorptivity.

Abstract: Disclosed is an adsorptive ethanol drying apparatus in which microwaves are applied during the regeneration of an absorbent conducted in a continuous adsorption process for drying ethanol, so that the absorbent regeneration can be rapidly achieved at a temperature lower than that used in a conventional heating type regeneration method and within a reduced processing time, thereby being capable of allowing an efficient use of energy while improving the productivity per adsorbent mass. A method for operating the adsorptive ethanol drying apparatus is also disclosed. At an adsorption step, a vaporized ethanol azeotropic mixture is forced to pass through adsorption towers to adsorb water contained in the vaporized ethanol azeotropic mixture to an adsorbent charged in each of the adsorption towers while condensing ethanol in a storage tank.

Abstract: Disclosed is an adsorptive ethanol drying apparatus in which microwaves are applied during the regeneration of an absorbent conducted in a continuous adsorption process for drying ethanol, so that the absorbent regeneration can be rapidly achieved at a temperature lower than that used in a conventional heating type regeneration method and within a reduced processing time, thereby being capable of allowing an efficient use of energy while improving the productivity per adsorbent mass. A method for operating the adsorptive ethanol drying apparatus is also disclosed. At an adsorption step, a vaporized ethanol azeotropic mixture is forced to pass through adsorption towers to adsorb water contained in the vaporized ethanol azeotropic mixture to an adsorbent charged in each of the adsorption towers while condensing ethanol in a storage tank.

Abstract: Disclosed is a process for effecting liquid-phase hydrogenation of MAN to GBL in high conversion and high selectivity. The present invention provides an improved process of catalytic hydrogenation for converting MAN or SA to GBL in the liquid phase in the presence of a noble metal (palladium-molybdenum-nickel) catalyst supported on silica having a large surface area. The catalytic hydrogenation is conducted at a temperature of 150 to 250° C. and under a pressure of 50 to 150 kg/cm2.

Abstract: Disclosed is a process for effecting liquid-phase hydrogenation of MAN to GBL in high conversion and high selectivity. The present invention provides an improved process of catalytic hydrogenation for converting MAN or SA to GBL in the liquid phase in the presence of a noble metal (palladium-molybdenum-nickel) catalyst supported on silica having a large surface area. The catalytic hydrogenation is conducted at a temperature of 150 to 250° C. and under a pressure of 50 to 150 kg/cm2.