Abstract: The present disclosure relates to a method of preparing a heat-resistant SAN resin. More particularly, the present disclosure provides a method of preparing a heat-resistant SAN resin enabling provision of superior productivity and improved heat resistance and fluidity without generation of odor during processing, and a heat-resistant SAN resin composition prepared by the method.

Abstract: Disclosed are a rubber polymer, a graft copolymer, methods of preparing the same, and an impact and heat resistant resin composition. According to the present invention, provided are rubber latex and a graft copolymer which may realize a product having superior impact resistance, heat resistance and chemical resistance by adding a specific crosslinking regulator to the rubber polymer, methods of preparing the same, and an impact and heat resistant resin composition.

Abstract: The present invention relates to a thermoplastic resin, a method of preparing the thermoplastic resin, and a thermoplastic resin composition including the thermoplastic resin. More particularly, the present invention relates to a thermoplastic resin characterized by maximizing a ratio of monomers grafted to rubber particles and a graft rate so as to maintain a rubber particle shape in a high shear environment and varying the composition of each of monomers grafted to the inside and outside of rubber particles, a method of preparing the thermoplastic resin, and a thermoplastic resin composition having superior impact strength, falling dart impact strength, heat deflection temperature, chemical resistance, and plating adhesion strength due to inclusion of the thermoplastic resin.

Abstract: The present invention relates to a method of preparing a heat-resistant resin, a heat-resistant resin, and a heat-resistant ABS resin. According to the preparation method of the present invention, the heat-resistant resin can be prepared at a high polymerization conversion rate within a shortened polymerization time, and the amount of polymerized coagulum and the content of fine particles upon coagulation are decreased. Accordingly, a heat-resistant resin and a heat-resistant ABS resin composition with enhanced heat deflection temperature and processability are provided.

Abstract: Disclosed are a rubber polymer, a graft copolymer, methods of preparing the same, and an impact and heat resistant resin composition. According to the present invention, provided are rubber latex and a graft copolymer which may realize a product having superior impact resistance, heat resistance and chemical resistance by adding a specific crosslinking regulator to the rubber polymer, methods of preparing the same, and an impact and heat resistant resin composition.

Abstract: Disclosed is a method of preparing a rubber-reinforced graft copolymer and a rubber-reinforced graft copolymer prepared using the method. According to the present disclosure, provided is a method of preparing an ?-methylstyrene-based rubber-reinforced graft copolymer which may enhance polymerization productivity and heat resistance, and a rubber-reinforced graft copolymer prepared using the method.

Abstract: The present invention relates to a heat-resistant resin and a method of preparing the same. More particularly, the present invention relates to a heat-resistant resin including 100 parts by weight of a styrene based resin and 0.5 to 5 parts by weight of silica having a contact angle of 10 to 60° and an average particle diameter of 0.1 nm or more and 100 nm or less, a method of preparing the same and a heat-resistant resin composition including the same. In accordance with the present invention, provided are a heat-resistant resin having a low moisture content and a small content of fine particles while having heat resistance equal to or higher than conventional resins and, accordingly superior cohesion, a method of preparing the same, and a heat-resistant resin composition including the same.

Abstract: The present invention relates to a method of preparing a heat-resistant resin, a heat-resistant resin, and a heat-resistant ABS resin. According to the preparation method of the present invention, the heat-resistant resin can be prepared at a high polymerization conversion rate within a shortened polymerization time, and the amount of polymerized coagulum and the content of fine particles upon coagulation are decreased. Accordingly, a heat-resistant resin and a heat-resistant ABS resin composition with enhanced heat deflection temperature and processability are provided.

Abstract: Disclosed are a method of preparing a rubber-reinforced graft copolymer and a rubber-reinforced graft copolymer prepared using the method. According to the present disclosure, provided are a method of preparing an ?-methylstyrene-based rubber-reinforced graft copolymer which may enhance polymerization productivity and heat resistance, and a rubber-reinforced graft copolymer prepared using the method.

Abstract: The disclosed is a rubber polymer latex with a multi-layer core-shell structure that includes a diene-based rubber core of a conjugated diene-based monomer; a bridge shell formed on the rubber core of a vinyl-based monomer; and an outermost shell formed on the bridge shell of an acryl-based monomer.

Abstract: Disclosed are a thermal stabilizer-free thermoplastic resin composition and a method of preparing the same. The thermal stabilizer-free thermoplastic resin composition has superior impact resistance, falling ball impact resistance and gloss without using a separate thermal stabilizer. Particularly, the thermal stabilizer-free thermoplastic resin composition improves production efficiency when applied to a squeezing dehydrator because the thermoplastic resin composition is prepared without using a drying process.

Abstract: The present invention relates to rubber polymer latex with a multi-layer core-shell structure, a method of preparing thereof, an acrylonitrile-butadiene-styrene graft copolymer comprising the same, and a thermoplastic resin composition using the same. The rubber polymer latex with a multi-layer core-shell structure has improved weather resistance while maintaining the properties of a diene-based rubber component. The impact resistance, the coloring properties and the weather resistance of the acrylonitrile-butadiene-styrene graft copolymer including the same may be improved. Thus, the impact strength, the coloring properties and the weather resistance of the thermoplastic resin including the acrylonitrile-butadiene-styrene graft copolymer may be improved, and the graft copolymer may be easily applied in industries using thereof.

Abstract: Disclosed is a method for preparing a rubber latex which includes adding a basic solution to an initial reaction hydrophilic monomer and a small amount of fat-soluble monomer when a polymerization conversion ratio is 90% or more to form particles having a small diameter and superior stability, ionizing an end of the particles to secure stability of the particles and growing the formed particles, and thereby obtains a stable latex with a large particle diameter using a minimal amount of emulsifying agent and minimizes gas generation and heat discoloration derived from the emulsifying agent.

Abstract: Disclosed are a thermal stabilizer-free thermoplastic resin composition and a method of preparing the same. The thermal stabilizer-free thermoplastic resin composition has superior impact resistance, falling ball impact resistance and gloss without using a separate thermal stabilizer. Particularly, the thermal stabilizer-free thermoplastic resin composition improves production efficiency when applied to a squeezing dehydrator because the thermoplastic resin composition is prepared without using a drying process.

Abstract: Disclosed is a method for preparing a rubber latex which includes adding a basic solution to an initial reaction hydrophilic monomer and a small amount of fat-soluble monomer when a polymerization conversion ratio is 90% or more to form particles having a small diameter and superior stability, ionizing an end of the particles to secure stability of the particles and growing the formed particles, and thereby obtains a stable latex with a large particle diameter using a minimal amount of emulsifying agent and minimizes gas generation and heat discoloration derived from the emulsifying agent.

Abstract: Disclosed is a method for preparing a thermoplastic resin with superior impact resistance, chemical resistance and processability as well as excellent gloss and whiteness. The method includes emulsion-polymerizing a conjugated diene compound monomer to prepare a rubber latex having an average particle diameter of 1,800 ? to 5,000 ?, a polymerization conversion ratio of at least 90% and a swelling index of 12 to 40, an average gel content of 70 to 95%, emulsion-polymerizing 45 to 75 parts by weight of the rubber latex with 17 to 40 parts by weight of an aromatic vinyl compound and 4 to 20 parts by weight of a vinyl cyanide compound to prepare a graft copolymer latex, and coagulating the graft copolymer latex with a coagulant at 60 to 80° C., and aging the graft copolymer latex at 80 to 99° C. to obtain a graft copolymer powder.

Abstract: The present invention relates to a method for preparing a graft rubber latex having a low residual monomer content, and more precisely, a method for preparing a graft rubber latex having a high rubber content, which is characterized by graft-copolymerization of a mixture of a rubber latex having a gel content of at least 95% and an average particle diameter of 2,500˜5000 ?, a monomer mixture comprising one or more compounds selected from a group consisting of aromatic vinyl compound, vinyl cyan compound and acrylate compound, and small particle size latex produced by emulsion polymerization. The method of the present invention has the advantages of speedy processes with excellent latex stability and at the same time reducing residual monomer content in the latex upon completion of the polymerization, improving perceived quality of the product and increasing yield.

Abstract: Disclosed is a method for preparing a thermoplastic resin with superior impact resistance, chemical resistance and processability as well as excellent gloss and whiteness. The method includes emulsion-polymerizing a conjugated diene compound monomer to prepare a rubber latex having an average particle diameter of 1,800 ? to 5,000 ?, a polymerization conversion ratio of at least 90% and a swelling index of 12 to 40, an average gel content of 70 to 95%, emulsion-polymerizing 45 to 75 parts by weight of the rubber latex with 17 to 40 parts by weight of an aromatic vinyl compound and 4 to 20 parts by weight of a vinyl cyanide compound to prepare a graft copolymer latex, and coagulating the graft copolymer latex with a coagulant at 60 to 80° C., and aging the graft copolymer latex at 80 to 99° C. to obtain a graft copolymer powder.

Abstract: The present invention relates to a method for preparing a graft rubber latex having a low residual monomer content, and more precisely, a method for preparing a graft rubber latex having a high rubber content, which is characterized by graft-copolymerization of a mixture of a rubber latex having a gel content of at least 95% and an average particle diameter of 2,500˜5000 ?, a monomer mixture comprising one or more compounds selected from a group consisting of aromatic vinyl compound, vinyl cyan compound and acrylate compound, and small particle size latex produced by emulsion polymerization. The method of the present invention has the advantages of speedy processes with excellent latex stability and at the same time reducing residual monomer content in the latex upon completion of the polymerization, improving perceived quality of the product and increasing yield.

Abstract: The present invention relates to ABS thermoplastic resin and preparation thereof, and particularly to a process for preparing an ABS graft copolymer comprising the step of introducing to a) 40 to 80 weight parts of rubber latex comprising i) 10 to 50 weight parts of large diameter polybutadiene rubber latex having a particle diameter of 2500 to 3500 ?, gel contents of 60 to 80%, and a swelling index to 12 to 30, and ii) 50 to 90 weight parts of large diameter rubber latex having a particle diameter of 2500 to 3500 ?, gel contents of 81 to 97%, and a swelling index of 18 to 40, b) 20 to 60 weight parts of a monomer mixture of two or more kinds selected from a group consisting of aromatic vinyl compounds and vinyl cyanide compounds to prepare a graft copolymer, wherein 5 to 30 wt % of the monomer mixture is introduced as a batch and simultaneously 70 to 95 wt % of the monomer mixture is started to be continuously introduced in an emulsified state, and a thermoplastic resin composition using the same.