Patents by Inventor Jorg Hofmann
Jorg Hofmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11345775Abstract: The present invention relates to a method for producing polyurethane foams by reacting an isocyanate component with an isocyanate-reactive component comprising at least one polyethercarbonate polyol, the reaction taking place in the presence of a component K selected from one or more compounds from the group consisting of K1 esters of mono- or polybasic carboxylic acids whose (first) dissociation has a pKa of 0.5 to 4.0, K2 mono-, di- and polysulfonates of mono- and polyfunctional alcohols, and K3 one or more compounds from the group consisting of K 3.1 esters of phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid, phosphonous acid and phosphinous acid, these esters each containing no P—OH group, K3.Type: GrantFiled: December 6, 2016Date of Patent: May 31, 2022Assignee: Covestro Deutschland AGInventors: Bert Klesczewski, Jörg Hofmann, Karsten Malsch, Nicole Welsch, Klaus Lorenz, Hartmut Nefzger, Kai Laemmerhold
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Patent number: 11130842Abstract: The invention relates to a method for producing polyether carbonate polyols, wherein (i) in a first step a polyether carbonate polyol is produced from one or more H-functional starter substances, one or more alkylene oxides, and carbon dioxide in the presence of at least one DMC catalyst, and (ii) in a second step the polyether carbonate polyol is chain-extended with a mixture of at least two different alkylene oxides in the presence of at least one DMC catalyst. The invention further relates to polyether carbonate polyols that contain a terminal mixed block of at least two alkylene oxides and to a method for producing soft polyurethane foams, wherein a polyol component containing a polyether carbonate polyol according to the invention is used.Type: GrantFiled: August 27, 2018Date of Patent: September 28, 2021Assignee: Covestro Deutschland AGInventors: Jörg Hofmann, Bert Klesczewski, Michael Schneider
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Publication number: 20200407500Abstract: The present invention concerns a method for producing poly(oxyalkylene) polyols started with phosphorus-containing compounds, which have an inner block containing high amounts of EO, as well as the poly(oxyalkylene) polyols obtainable in this manner. Furthermore, the present invention comprises a method for producing polyurethane foams, preferably flexible polyurethane foams, by reacting an isocyanate component with a component reactive to isocyanates, which comprises at least one poly(oxyalkylene) polyol started with phosphorus-containing compounds with an inner block containing high amounts of EO, the polyurethane foams produced by the inventive method and their application.Type: ApplicationFiled: March 16, 2017Publication date: December 31, 2020Inventors: Bert Klesczewski, Jörg Hofmann, Hartmut Nefzger
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Patent number: 10836858Abstract: The invention relates to a method for producing polyether carbonate polyols by adding alkylene oxides and carbon dioxide to an H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein (?) alkylene oxide and carbon dioxide are added to an H-functional starter substance in a reactor with a total pressure (absolute) of 5 to 120 bar in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, and a reaction mixture containing the polyether carbonate polyol is obtained, (?) the reaction mixture obtained in step (?) remains in the reactor or is optionally continuously transferred to a downstream reactor at a starting total pressure (absolute) of 5 to 120 bar, the content of free alkylene oxide in the reaction mixture being reduced in the course of a downstream reaction in each case, and the total pressure (absolute)Type: GrantFiled: June 20, 2017Date of Patent: November 17, 2020Assignee: Covestro Deutschland AGInventors: Jörg Hofmann, Urs Rauwald, Stefanie Braun, Matthias Wohak, Hartmut Nefzger, Nicole Welsch, Aurel Wolf, Michael Traving, Lars Krueger
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Patent number: 10759902Abstract: The invention relates to a process for producing polyoxymethylene block copolymers, comprising the step of activating the DMC catalyst in the presence of an OH-terminated polymeric formaldehyde starter compound by means of a defined amount of alkylene oxide, optionally followed by polymerization with alkylene oxides, if necessary in the presence of other comonomers. The invention further relates to polyoxymethylene block copolymers that can be obtained by means of such a process and to the use of these for producing polyurethane polymers.Type: GrantFiled: September 4, 2018Date of Patent: September 1, 2020Assignee: Covestro Deutschland AGInventors: Ilja Peckermann, Aurel Wolf, Jens Langanke, Christoph Gürtler, Jörg Hofmann
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Publication number: 20200190261Abstract: The invention relates to a method for adding a compound (A) to an H-functional starting compound (BH) in the presence of a catalyst, wherein the at least one compound (A) is selected from at least one group consisting of alkylene oxide (A-1), lactone (A-2), lactide (A-3), cyclic acetal (A-4), lactam (A-5), cyclic anhydride (A-6) and oxygen-containing heterocyclic compound (A-7) different from (A-1), (A-2), (A-3), (A-4) and (A-6), wherein the catalyst comprises an organic, n-protic Brønsted acid (C), wherein n?2 and is an element of the natural numbers and the degree of protolysis D is 0<D<n, with n as the maximum number of transferable protons and D as the calculated proton fraction of the organic, n-protic Brønsted acid (C). The invention further relates to an n-protic Brønsted acid (C) having a degree of protolysis D of 0<D<n, wherein n is the maximum number of transferable protons, with n=2, 3 or 4, and D is the calculated proton fraction of the organic, n-protic Brønsted acid (C).Type: ApplicationFiled: August 9, 2017Publication date: June 18, 2020Inventors: Christoph GÜRTLER, Thomas Ernst MÜLLER, Jörg HOFMANN, Jens LANGANKE, Matthias LEVEN, Walter LEITNER
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Patent number: 10662314Abstract: The invention relates to a method for producing polyether carbonate polyols, (i) one or more alkylene oxide(s) and carbon dioxide being added to one or more H-functional starter substance(s) in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, a reaction mixture containing the polyether carbonate polyol being obtained, characterized in that (ii) at least one component K is added to the obtained reaction mixture containing the polyether carbonate polyol, wherein component K is selected from at least one compound that contains a phosphorus-oxygen bond or a compound of phosphorus that can form one or more P—O bonds by reaction with OH-functional compounds.Type: GrantFiled: October 2, 2017Date of Patent: May 26, 2020Assignee: Covestro Deutschland AGInventors: Kai Laemmerhold, Jorg Hofmann, Hartmut Nefzger
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Use of alcohols which contain at least two urethane groups for producing polyether carbonate polyols
Patent number: 10519276Abstract: The present invention relates to a method for producing polyether carbonate polyols by attaching alkyloxides and carbon dioxide to H-functional starter compounds, characterized in that at least one alcohol containing at least two urethane groups is used as the H-functional starter compound.Type: GrantFiled: May 24, 2016Date of Patent: December 31, 2019Assignee: Covestro Deutschland AGInventors: Urs Rauwald, Jörg Hofmann, Bert Klesczewski, Hartmut Nefzger, Aurel Wolf, Jens Langanke -
Patent number: 10487175Abstract: The present invention relates to a process for preparing polyether polyols by adding alkylene oxides onto H-functional starter compounds, characterized in that at least one alcohol containing at least two urethane groups is used as H-functional starter compound.Type: GrantFiled: May 19, 2016Date of Patent: November 26, 2019Assignee: Covestro Deutschland AGInventors: Jörg Hofmann, Urs Rauwald, Bert Klesczewski, Hartmut Nefzger
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Publication number: 20190322801Abstract: The invention relates to a method for producing polyether carbonate polyols by adding alkylene oxides and carbon dioxide to an H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein (?) alkylene oxide and carbon dioxide are added to an H-functional starter substance in a reactor with a total pressure (absolute) of 5 to 120 bar in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, and a reaction mixture containing the polyether carbonate polyol is obtained, (?) the reaction mixture obtained in step (?) remains in the reactor or is optionally continuously transferred to a downstream reactor at a starting total pressure (absolute) of 5 to 120 bar, the content of free alkylene oxide in the reaction mixture being reduced in the course of a downstream reaction in each case, and the total pressure (absolute)Type: ApplicationFiled: June 20, 2017Publication date: October 24, 2019Inventors: Jörg HOFMANN, Urs RAUWALD, Stefanie BRAUN, Matthias WOHAK, Hartmut NEFZGER, Nicole WELSCH, Aurel WOLF, Michael TRAVING, Lars KRUEGER
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Patent number: 10421836Abstract: The present invention relates to a purifying apparatus for polycarbonate polyols, especially for removal of cyclic alkylene carbonates, comprising an evaporation unit (1) provided with a heater (10) and having an inlet (6) disposed at the top end thereof and a bottoms vessel (11), and a stripping column (2) connected downstream of the evaporation unit (1) and having a top (21) and a bottom (23), wherein a feed (5) for the polycarbonate polyol to be purified opens into the inlet (6) to the evaporation unit (1) and a gas outlet line (12) and a connecting line which opens into the top (21) of the stripping column (2) and is equipped with a pump (18) depart from the evaporation unit (1), and wherein a gas inlet line (24) for an inert gas opens into the bottom (23) of the stripping column (2) and a product line (27) for the purified polycarbonate polyol departs from the bottom (23) of the stripping column (2) and a gas outlet line (25) departs from the top (21) of the stripping column (2).Type: GrantFiled: June 29, 2015Date of Patent: September 24, 2019Assignee: COVESTRO DEUTSCHLAND AGInventors: Jörg Hofmann, Stefanie Braun, Kai Laemmerhold, Matthias Wohak, Cyrus Ahmadzade-Youssefi, Jürgen Bausa
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Publication number: 20190284322Abstract: This invention relates to polymer polyols comprising the free-radical polymerization product of a base polyol, at least one ethylenically unsaturated monomer, and, optionally, a preformed stabilizer, in the presence of at least one free-radical polymerization initiator and at least one chain transfer agent, in which the base polyol is a polyether carbonate polyol. A process for preparing these polymer polyols is also described. This invention also relates to a polyurethane foam prepared from these polymer polyols and to a process for the preparation of these polyurethane foams.Type: ApplicationFiled: May 28, 2019Publication date: September 19, 2019Inventors: Jorg Hofmann, Norbert Hahn, Mandy Von Chamier, Edward Browne
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Patent number: 10239995Abstract: The invention provides a process for preparing polyether carbonate polyols by addition of alkylene oxides and carbon dioxide onto H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein (?) alkylene oxide and carbon dioxide are added onto H-functional starter substance in a reactor in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein a reaction mixture comprising the polyether carbonate polyol is obtained, and wherein (?) the reaction mixture obtained in step (?) remains in the reactor or is transferred continuously into a postreactor, wherein the content of free alkylene oxide in the reaction mixture is reduced in each case in the manner of a postreaction, characterized in that a component K is added during the postreaction, component K being selected from at least one compound containing a pType: GrantFiled: January 27, 2016Date of Patent: March 26, 2019Assignee: COVESTRO DEUTSCHLAND AGInventors: Jörg Hofmann, Thomas Ernst Müller, Michael Pohl, Walter Leitner
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Publication number: 20190085121Abstract: The present invention provides a process for preparing polyether carbonate polyols from H-functional starter substance, alkylene oxide and carbon dioxide in the presence of a DMC catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein the carbon dioxide used has a purity of 99.5000% to 99.9449% by volume.Type: ApplicationFiled: March 16, 2017Publication date: March 21, 2019Applicant: COVESTRO DEUTSCHLAND AGInventors: Jörg HOFMANN, Stefanie BRAUN, Aurel WOLF
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Patent number: 10233298Abstract: The present invention concerns a method for producing polyurethane foams by reacting an isocyanate component with a component that is reactive to isocyanates and that comprises at least one polyether carbonate polyol, the reaction taking place in the presence of a non-amine antioxidant and an amine antioxidant. The invention also concerns polyurethane foams produced using the claimed method and the use of said foams.Type: GrantFiled: April 21, 2015Date of Patent: March 19, 2019Assignee: Covestro Deutschland AGInventors: Bert Klesczewski, Kai Laemmerhold, Jörg Hofmann
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Patent number: 10208162Abstract: The present invention relates to a method for producing polyether carbonate polyols by addition of one or more alkylene oxides and carbon dioxide to one or more H-functional starter substances in the presence of at least one DMC catalyst, in which the reaction is conducted in a main reactor (8) and a tubular reactor (11, 17) connected as a post reactor downstream thereof, wherein the method is characterized in that at the outlet (13) of the tubular reactor (11, 17) a temperature is set that is at least 10° C. above the temperature in the inside of the main reactor (8). The invention further relates to a device for carrying out said method.Type: GrantFiled: June 30, 2015Date of Patent: February 19, 2019Assignee: COVESTRO DEUTSCHLAND AGInventors: Stefanie Braun, Horst Zwick, Matthias Wohak, Jörg Hofmann, Aurel Wolf, Michael Traving, Rolf Bachmann
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Publication number: 20190002634Abstract: The invention relates to a method for producing polyether carbonate polyols, wherein (i) in a first step a polyether carbonate polyol is produced from one or more H-functional starter substances, one or more alkylene oxides, and carbon dioxide in the presence of at least one DMC catalyst, and (ii) in a second step the polyether carbonate polyol is chain-extended with a mixture of at least two different alkylene oxides in the presence of at least one DMC catalyst. The invention further relates to polyether carbonate polyols that contain a terminal mixed block of at least two alkylene oxides and to a method for producing soft polyurethane foams, wherein a polyol component containing a polyether carbonate polyol according to the invention is used.Type: ApplicationFiled: August 27, 2018Publication date: January 3, 2019Inventors: Jörg Hofmann, Bert Klesczewski, Michael Schneider
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Publication number: 20180371159Abstract: The invention relates to a process for producing polyoxymethylene block copolymers, comprising the step of activating the DMC catalyst in the presence of an OH-terminated polymeric formaldehyde starter compound by means of a defined amount of alkylene oxide, optionally followed by polymerization with alkylene oxides, if necessary in the presence of other comonomers. The invention further relates to polyoxymethylene block copolymers that can be obtained by means of such a process and to the use of these for producing polyurethane polymers.Type: ApplicationFiled: September 4, 2018Publication date: December 27, 2018Inventors: Ilja Peckermann, Aurel Wolf, Jens Langanke, Christoph Gürtler, Jörg Hofmann
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Patent number: 10138328Abstract: The invention relates to a method for producing polyether carbonate polyols, comprising the step of reacting alkylene oxide with carbon dioxide in the presence of an h-functional starter compound and double metal cyanide catalyst. The invention is characterized in that the method comprises the following steps: (?) optionally, pre-treating the double metal cyanide catalyst (DMC catalyst) at a temperature of 50 to 200° C.Type: GrantFiled: November 16, 2015Date of Patent: November 27, 2018Assignee: Covestro Deutschland AGInventors: Thomas Ernst Müller, Christoph Gürtler, Matthias Wohak, Jörg Hofmann, Carlson Torren
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Patent number: 10125217Abstract: The invention relates to a process for producing polyether carbonate polyols through an addition reaction of alkylene oxides and carbon dioxide onto one or more H-functional starter substances in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, characterized in that one or more H-functional starter substances containing at least 1000 ppm of component (K) is/are continuously metered into the reactor during the reaction, where component (K) is selected from at least one compound containing a phosphorus-oxygen bond and a phosphorus compound that can form one or more P—O bonds through reaction with OH-functional compounds.Type: GrantFiled: October 20, 2014Date of Patent: November 13, 2018Assignee: COVESTRO DEUTSCHLAND AGInventors: Jörg Hofmann, Hans-Georg Pirkl, Kai Laemmerhold, Hartmut Nefzger, Matthias Wohak, Stefanie Braun, Christoph Gürtler, Aurel Wolf, Jens Langanke