Abstract: The present invention relates to a process for preparing unsaturated aldehydes or unsaturated carboxylic acids by heterogeneous catalytic gas phase oxidation of unsaturated or saturated hydrocarbons, comprising the process steps of: i) providing a gas mixture comprising a saturated hydrocarbon and catalytically dehydrogenating the saturated hydrocarbon in the gas phase to obtain a gas mixture comprising an unsaturated hydrocarbon in a dehydrogenation reactor having a dehydrogenation catalyst material; or ii) providing a gas mixture comprising oxygen and an unsaturated hydrocarbon; iii) catalytically oxidizing the unsaturated hydrocarbon obtained in process step i) or provided in process step ii) in the gas phase to obtain a gas mixture comprising an unsaturated aldehyde in a first oxidation reactor having a first oxidation catalyst material; wherein at least one of the reactors selected from the dehydrogenation reactor, the first oxidation reactor and the second oxidation reactor comprises at least one foam b

Abstract: The present invention relates to a process for preparing unsaturated aldehydes or unsaturated carboxylic acids by heterogeneous catalytic gas phase oxidation of unsaturated or saturated hydrocarbons, comprising the process steps of: i) providing a gas mixture comprising a saturated hydrocarbon and catalytically dehydrogenating the saturated hydrocarbon in the gas phase to obtain a gas mixture comprising an unsaturated hydrocarbon in a dehydrogenation reactor having a dehydrogenation catalyst material; or ii) providing a gas mixture comprising oxygen and an unsaturated hydrocarbon; iii) catalytically oxidizing the unsaturated hydrocarbon obtained in process step i) or provided in process step ii) in the gas phase to obtain a gas mixture comprising an unsaturated aldehyde in a first oxidation reactor having a first oxidation catalyst material; wherein at least one of the reactors selected from the dehydrogenation reactor, the first oxidation reactor and the second oxidation reactor comprises at least one foam b

Abstract: The present invention relates to a process for production of acrylic acid, comprising at least the following steps: a. dehydrating glycerine to a dehydration product comprising acrolein; b. gas phase oxidation of the dehydration product comprising acrolein to obtain a monomer gas comprising an acrylic acid; c. bringing into contact the monomer gas with a quench means to obtain a quench phase comprising acrylic acid; and d. processing the quench phase comprising acrylic acid to obtain a monomer phase comprising acrylic acid. The present invention may also relate to a process for preparation of polymers by radical polymerization of acrylic acid, the water-absorbing polymers obtainable by this process, water-absorbing polymers based to at least 25 wt % upon partially neutralized acrylic acid, a composite, a device for preparation of acrylic acid, a process for preparation of acrylic acid, and the acrylic acid obtainable by this process.

Abstract: The present invention relates to a process for the production of acrolein, comprising the following steps: (a) bringing into contact of an aqueous glycerine phase in an acrolein reaction area to obtain an aqueous acrolein reaction phase; (b) depleting the acrolein from the acrolein reaction phase to obtain an acrolein phase and a depleted acrolein reaction phase; (c) conducting back at least a part of the depleted acrolein reaction phase into the acrolein reaction area. The invention further relates to a process for production of acrylic acid as well as of water-absorbing polymer structures, composites, in particular hygiene articles, comprising these water-absorbing polymer structures, a process for production of the composites and further chemical products based on the acrylic acid obtained by the inventive process and also the use of this acrylic acid in chemical products.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: The invention relates to a process for the parameterization of a software-implemented working model of a simulation environment, which comprises a multitude of simulation model components and is loaded onto simulation hardware, particularly in order to simulate a test environment of at least one motor vehicle control system interfaced with the simulation hardware or the simulation of a motor vehicle control system running on the simulation hardware, whereby the working model is analyzed in relation to the simulation model components contained therein and for each detected simulation model component there is generated and displayed a user interface by the automatic selection out of a mask databank of at least one input/output mask allocated to the simulation model component and by the automatic selection out of a parameter-mask allocation databank of the parameters allocated to an input/output mask.

Abstract: The present invention relates to a process for preparing tert-butanol (TBA) by reacting an isobutene-containing hydrocarbon mixture with water over a solid acid catalyst in a reactor cascade, wherein at least one reactor is supplied alternately with two different isobutene-containing hydrocarbon mixtures, of which one has both a higher tert-butanol content and a higher water content than the other mixture.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: A shaped metal fixed-bed catalyst is disclosed which is made from at least one catalyst alloy formed of a catalyst metal and an extractable alloying component. The catalyst is activated in an outer layer with a thickness of 0.1 to 2.0 mm, starting from the surface, by complete or partial extraction of the extractable alloying component. The catalyst may also contain promoters. The catalyst is distinguished from known catalysts in that it is formed exclusively of the catalyst alloy and is free of alpha-aluminum oxide, and has a total pore volume of 0.1 to 0.6 ml/g and a bulk density lower than 2.2 kg/l. The catalyst is used for hydrogenation, dehydrogenation and hydrogenolysis reactions.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: A process for the catalytic epoxidation of olefins with hydrogen peroxide in a continuous flow reaction system, wherein the reaction mixture is passed through a fixed catalyst bed in down-flow operation mode and the reaction heat is at least partially removed during the course of the reaction.

Abstract: A process for the catalytic epoxidation of olefins with hydrogen peroxide in a continuous flow reaction system, wherein the reaction mixture is passed through a fixed catalyst bed within a reactor equipped with cooling means while maintaining a temperature profile within the reactor such that the cooling medium temperature of the cooling means is at least 40° C. and the maximum temperature within the catalyst bed is 60° C. at most.

Abstract: Process for the preparation of isophorone diamine from isophorone nitrile, isophorone nitrilimine or mixtures containing isophorone nitrile and/or isophorone nitrilimine by hydrogenation through to amine in the presence of at least ammonia, hydrogen and a formed Raney hydrogenation catalyst based on cobalt, nickel, copper and/or iron, wherein the Raney catalyst is present in the form of hollow bodies.

Abstract: Process for the preparation of isophorone diamine from isophorone nitrile, isophorone nitrilimine or mixtures containing isophorone nitrile and/or isophorone nitrilimine by hydrogenation through to amine in the presence of at least ammonia, hydrogen and a formed Raney hydrogenation catalyst based on cobalt, nickel, copper and/or iron, wherein the Raney catalyst is present in the form of hollow bodies.

Abstract: A process for the catalytic epoxidation of olefins by means of hydrogen peroxide and a titanium zeolite catalyst, wherein the epoxidation reaction is carried out in a reaction system through which the reaction mixture flows continuously and the regeneration of deactivated catalyst is carried out by means of hydrogen peroxide in the presence of the olefin while continuing the epoxidation reaction.

Abstract: A process for the catalytic hydrogenation of an organic compound, in particular a labile organic compound, in the presence of a support catalyst with a coating containing ruthenium as active metal and a total of 1.01 to 30 wt. % of active metals. Higher stereoselectivity and a greater catalyst shelf life may be obtained by using a support catalyst of which the oxide, carbide, nitride or siliceous support material has a BET (N2) surface area smaller than 10 m2/g, particularly preferably 0.1 to 5 m2/g, prior to loading with at least one active metal diatomaceous earth with a BET (N2) surface area greater than 2 m2/g is excluded and the ruthenium content thereof makes up at least 50 wt. %, preferably at least 99 wt. % of the active metals. The process and the catalysts are particularly suitable for the hydrogenation of polyfunctional compounds such as hydroxycarbonyl compounds and aromatic amines.

Abstract: Raney copper which is doped with at least one metal from the group comprising iron and/or noble metals is used as a catalyst in the dehydrogenation of alcohols.

Abstract: A process for the production of 1,3-propanediol by heterogeneously catalyzed hydrogenation of 3-hydroxypropionaldehyde in an aqueous solution at 30 to 180° C., at a hydrogenation pressure of 5 to 300 bar and a pH value of 2.5 to 7.0, wherein ruthenium on an oxide support is used as the catalyst.